应用化学 ›› 2020, Vol. 37 ›› Issue (9): 1056-1061.DOI: 10.11944/j.issn.1000-0518.2020.09.200066

• 研究论文 • 上一篇    下一篇

红磷/石墨复合材料的制备及电化学性能

陶承业a, 杨占旭a*, 李玥b   

  1. 辽宁石油化工大学 a化学化工与环境学部; b外国语学院 辽宁 抚顺 113001
  • 收稿日期:2020-03-12 出版日期:2020-09-01 发布日期:2020-09-09
  • 通讯作者: 杨占旭,教授; Tel/Fax:024-56860958; E-mail:zhanxuy@126.com; 研究方向:新型储能材料、新型催化材料
  • 基金资助:
    国家自然科学基金(21671092)和辽宁省“兴辽英才”科技创新领军人才项目(XLYC1802057)资助

Preparation and Electrochemical Properties of Red Phosphorus/Graphite Composite

TAO Chengyea, YANG Zhanxua*, LI Yueb   

  1. aCollege of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,Fushun,Liaoning 113001,China;
    bSchool of Foreign Languages,Liaoning Shihua University,Fushun,Liaoning 113001,China
  • Received:2020-03-12 Published:2020-09-01 Online:2020-09-09
  • Contact: YANG Zhanxu, professor; Tel:; Fax:024-56860958; E-mail:zhanxuy@126.com; Research interests:new energy storage materials, new catalytic materials
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.21671092), and Liaoning Provincial Science and Technology Innovation Leading Talent Project(No.XLYC1802057)

摘要: 研究了一种先通过机械球磨和水热法制得的亚微米红磷,再通过球磨亚微米红磷与石墨得到的块状亚微米红磷/石墨复合材料(smRP/G),并利用扫描电子显微镜(SEM)、X射线衍射(XRD)、X射线光电子能谱分析(XPS)、循环伏安法(CV)等手段其进行了表征。 相对比普通红磷,亚微米红磷更容易通过球磨与石墨复合,能有效提升石墨材料的储锂容量。 为红磷在锂离子电池负极材料上的应用提供了一种思路。 在少量添加红磷的条件下,当红磷质量分数为3%时smRP/G表现最佳(3%smRP/G)。 在100 mA/g电流密度下展示出了1417 mA·h/g的首次放电容量,首次库伦效率67.4%。 并在循环200圈后依然保持着700 mA·h/g的可逆循环容量。

关键词: 红磷, 石墨, 球磨, 锂离子电池

Abstract: In this paper, a kind of bulk submicron red phosphorus/graphite composite (smRP/G) was studied, which was prepared by mechanical ball milling submicron red phosphorus and graphite. Its characteristics were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), cyclic voltammogram (CV) and etc. Compared with common red new energystorage materials, new catalytic materials, submicron red phosphorus is easier to form composites with graphite by ball milling, which can effectively improve the lithium storage capacity of graphite materials. It provides an idea for the application of red phosphorus in the negative electrode materials of lithium-ion batteries. In this work, under the condition of adding a mass percent of 3% red phosphorus, smRP/G shows the best performance. At the current density of 100 mA/g, the first discharge capacity of 1417 mA穐/g is displayed, and the first coulomb efficiency is 67.4%. The reversible capacity of 700 mA穐/g is maintained after 200 cycles.

Key words: red phosphorus, graphite, ball milling, lithium-ion batteries