Chinese Journal of Applied Chemistry

• Full Papers • Previous Articles     Next Articles

Synthesis and Properties of a New D-π-A Type Isophorone Derivative

REN Jun, YANG Peng, DING Aixiang, WANG Shaomin, YANG Jiaxiang*   

  1. (College of Chemistry and Chemical Engineering,Anhui University,Hefei 230039,China)
  • Received:2012-09-03 Revised:2012-11-14 Published:2013-07-10 Online:2013-07-10
  • Contact: xiang jiayang

Abstract: A new isophorone derivative(2-(3-(4-(bis(2-(2-nitrophenoxy)ethyl)amino)styryl)-5,5-dimethylcyclohex-2-en-1-ylidene)malononitrile) of donor-π-acceptor(D-π-A) type which yield was 80.7% was synthesized by Knoevenagel reaction and characterized by FT-IR and 1H NMR. Its UV-Vis absorption spectrum and fluorescent properties, thermal stability and electrochemical properties were preliminarily investigated. The results showed that the target compound had good fluorescence properties and thermal stability and demonstrated instructive explorations for pursuing new luminescent materials.

Key words: D-&, pi, -A molecule, red fluorescent material, optical properties, Knovengel reaction

CLC Number: