Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (7): 1017-1023.DOI: 10.19894/j.issn.1000-0518.220386
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Pan YU, Guang-Hui WANG, Jian-Hua GUO, Qiao-Zhi GUO, Chuan DONG()
Received:
2022-11-29
Accepted:
2023-05-05
Published:
2023-07-01
Online:
2023-07-19
Contact:
Chuan DONG
About author:
dc@sxu.edu.cnSupported by:
CLC Number:
Pan YU, Guang-Hui WANG, Jian-Hua GUO, Qiao-Zhi GUO, Chuan DONG. Yellow Fluorescent Carbon Dots for Sensitive Detection of Chlortetracycline Hydrochloride[J]. Chinese Journal of Applied Chemistry, 2023, 40(7): 1017-1023.
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URL: http://yyhx.ciac.jl.cn/EN/10.19894/j.issn.1000-0518.220386
Fig.2 (A) TEM image of the Y-CDs, the upper right illustration shows the distribution of particle size; (B) FT-IR spectrum of Y-CDs; (C) XPS spectrum of Y-CDs;(D) C1s; (E) N1s; (F) O1s, high resolution XPS patterns of Y-CDs
Fig. 3 (A) UV-Vis absorption, fluorescence spectra of Y-CDs in aqueous solution; (B) Fluorescence emission spectra of the Y-CDs under different excitation wavelengths
Fig.4 (A) Fluorescence intensity of Y-CDs at different concentration of NaCl; (B) Fluorescence intensity of Y-CDs under continuous irradiation by xenon lamp; (C) Fluorescence intensity of 0.1 mg/mL Y-CDs under different pH; (D) The zeta potential of Y-CDs
Fig.5 (A) Fluorescence responses of the Y-CDs in the presence of small biomolecules; (B) Fluorescence responses of the Y-CDs toward different concentrations of CTC; (C) Linear relationship between F0/F and CTC concentration
Fig. 6 (A) The mechanisms of CTC detection by the Y-CDs. UV spectrum of CTC, and the maximum excitation and emission fluorescence spectra of Y-CDs; (B) UV-Vis absorption spectrum of CTC, Y-CDs, Y-CDs + CTC aqueous solution; (C) PL decay curves of Y-CDs aqueous solution and Y-CDs+CTC compound aqueous solution; (D) The linear relation between (F0-F)/F and CTC concentration
Spiked/(μmol·L-1) | Found/(μmol·L-1) | Recovery/%(n=6) | RSD/%(n=6) | |
---|---|---|---|---|
Milk | 10 | 10.43 | 104.30 | 3.68 |
55 | 54.65 | 99.34 | 4.01 | |
70 | 70.27 | 100.39 | 3.13 | |
Tap water | 10 | 9.74 | 97.49 | 1.36 |
55 | 58.03 | 105.52 | 3.24 | |
70 | 74.83 | 106.90 | 1.96 |
Table 1 Determination of CTC in milk and tap water
Spiked/(μmol·L-1) | Found/(μmol·L-1) | Recovery/%(n=6) | RSD/%(n=6) | |
---|---|---|---|---|
Milk | 10 | 10.43 | 104.30 | 3.68 |
55 | 54.65 | 99.34 | 4.01 | |
70 | 70.27 | 100.39 | 3.13 | |
Tap water | 10 | 9.74 | 97.49 | 1.36 |
55 | 58.03 | 105.52 | 3.24 | |
70 | 74.83 | 106.90 | 1.96 |
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