催化氨硼烷水解制氢研究进展

doi:10.19894/j.issn.1000-0518.200229

摘要/Abstract

摘要： 当前,世界范围内的能源利用面临着巨大的挑战,开发绿色洁净能源十分重要。通过水解氨硼烷制备清洁可再生的氢气是解决能源问题的有效途径之一。选择合适的催化剂有效提高制氢效率是氨硼烷水解制氢的关键,开发高效安全的催化剂一直是该领域研究的重点和热点。本文从影响氨硼烷水解制氢反应中催化剂催化性能的因素出发,综述了活性金属组分和载体在催化剂制备过程中以及催化氨硼烷制氢反应中的作用。最后,对催化氨硼烷水解制氢过程所存在的问题以及今后的发展进行了总结和展望。

关键词: 制氢, 氨硼烷, 催化剂, 活性组分, 载体

Abstract: Energy utilization in the world is facing great challenges and it is very important to develop green and clean energy. Hydrolysis of ammonia borane is one of the effective routes to produce clean and renewable hydrogen and suitable catalysts can improve the efficiency of hydrogen production in the hydrolysis reaction. The development of efficient and safe catalysts has been the focus and hotspot in this field. This paper reviews the role of active metal components and supports in the preparation of catalysts and the catalytic hydrolysis of ammonia borane based on the key factors that affect the catalytic performance. Finally, the current problems are summarized and the future development of this field is pointed out.

Key words: Hydrogen generation, Ammonia borane, Catalyst, Active component, Support

中图分类号:

O643.3

刘军辉, 郭旭明, 宋亚坤, 郭新闻. 催化氨硼烷水解制氢研究进展[J]. 应用化学, 2021, 38(2): 157-169.

LIU Jun-Hui, GUO Xu-Ming, SONG Ya-Kun, GUO Xin-Wen. Recent Advances in Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane[J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 157-169.

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