Influence of Reaction Temperature on the Amount of Silver Loaded on Montmorillonite and Its Sustained Release Performance

doi:10.11944/j.issn.1000-0518.2015.04.140260

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (4): 453-457.DOI: 10.11944/j.issn.1000-0518.2015.04.140260

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Influence of Reaction Temperature on the Amount of Silver Loaded on Montmorillonite and Its Sustained Release Performance

XU Guangnian^{a, *}, QIAO Xueliang^b, ZHANG Wenhai^a, JIN Juncheng^a, CHANG Wengui^a

^aThe Promotion Center for Preparation and Application Technology of Nano-functional Composite Materials, West Anhui University,Liuan,Anhui 237012,China
^b State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology,Wuhan 430074,China

Received:2014-07-24 Published:2015-04-10 Online:2015-04-10
Contact: Corresponding author:XU Guangnian, associate professor; Tel/Fax:0564-3305690; E-mail:xuguangnian@126.com; Research interests:preparation and properties of nano- and nano-composite materials
Supported by:
Supported by the Natural Science Foundation of Anhui Province(No.1308085ME57), State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology(No.P2014-17), the National Natural Science Fundation of China(No.21271141)

Abstract

Abstract:

Silver loaded montmorillonite(Ag-MMT) was prepared by ion-exchange and triethanolamine reduction two-step approach using [Ag(NH₃)₂OH] as the precursor for silver oxide and ammonia. The silver content in Ag-MMT was determined by the Volhard method. The effects of reaction temperature on silver loading, its release properties, and the structures of Na-MMT and Ag-MMT were characterized by FI-IR and XRD, respectively. The results show that the amount of silver loaded on the montmorillonite is maximum, the utilization rate of silver reaches up to 86.9% and the layered structure of MMT is remained under the optimized conditions:the mass ratio of montmorillonite to Ag⁺ is 20:1, the ion exchange time is 1 h, and the reaction temperature is 50 ℃, then triethanolamine and polyvinylpyrrolidone are added and react for 2 h at temperature of 50 ℃.

Key words: silver loaded montmorillonite, preparation, temperature, sustained release

CLC Number:

O614

XU Guangniana, , QIAO Xueliangb, ZHANG Wenhaia, JIN Junchenga, CHANG Wenguia. Influence of Reaction Temperature on the Amount of Silver Loaded on Montmorillonite and Its Sustained Release Performance[J]. Chinese Journal of Applied Chemistry, 2015, 32(4): 453-457.

References

[1] Pal A,Shah S,Devi S. Preparation of Silver, Gold and Silver-gold Bimetallic Nanoparticles in W/O Microemulsion Containing TritonX-100[J]. Colloids Surf A ,2007,302(1/3):483-487.
[2] Magana S M,Quintana P,Aguilar D H, et al . Antibacterial Activity of Montmorillonites Modified with Silver[J]. J Mol Catal A : Chem ,2008,281:192-199.
[3] Filho N L D,Carmo D R D. Study of an Organically Modified Clay:Selective Adsorption of Heavy Metal Ions and Voltammetric Determination of Mercury(Ⅱ)[J]. Talanta ,2006,8(3):919-927.
[4] Hu C H,Xia M S. Adsorption and Antibacterial Effect of Copper Exchanged Montmorillonite on Escherichia coli K88[J]. Appl Clay Sci ,2006,(31):180-184.
[5] Lombardi B,Baschini M,Torres Sanchez RM. Optimization of Parameters and Adsorption Mechanism of Thiabendazole Fungicide by a Montmorillonite of North Patagonia Argentina[J]. Appl Clay Sci ,2003,(24):43-50.
[6] Damonte M,Torres Sanchez R M,dos Santos Afonso M. Some Aspects of the Glyphosate Adsorption on Montmorillonite and Its Calcined Form[J]. Appl Clay Sci ,2007,36(1/2/3):86-94.
[7] Jaynes J W,Zartman R,Hudnall W, et al . Absorption by Clays from Water and Corn Meal[J]. Appl Clay Sci ,2007,36(1/2/3):197-205.
[8] Yoshio O,Shunji S,Abhijit C, et al . Bactericidal Allophanic Materials Prepared from Allophane soil Ⅱ.Bactericidal Activities of Silverrphosphorus-silver-loaded Allophanic Specimens[J]. Appl Clay Sci ,2001,18:135-144.
[9] LIU Jianjun,YU Yingchun,WU Qu, et al . Preparation and Characterization of High Dispersed Nano Silver Montmorillonite Composites[J]. Chinese J Inorg Chem ,2004,20(3):321-323(in Chinese). 刘建军,于迎春,吴曲,等. 高分散纳米银蒙脱土复合材料的制备及表征[J]. 无机化学学报,2004,20(3):321-323.
[10] Zhou Y H,Xia M S,Ye Y, et al . Antimicrobial Ability of Cu 2+ -Montmorillonite[J]. Appl Clay Sci ,2004,27(3/4):215-218.
[11] Zhao D F,Zhou J,Liu N. Preparation and Characterization of Mingguang Palygorskite Supported with Silver and Copper for Antibacterial Behavior[J]. Appl Clay Sci ,2006,33:161-170.
[12] ZHAO Bing,WU Xin,WANG Guoqing. Study on the Antimicrobial Properties of Ag-carrying Montmorillonite[J]. Bull Chinese Ceram Soc ,2009,28(5):951-954(in Chinese). 赵兵,武昕,王国清. 载银蒙脱石无机抗茵剂的抗菌性能研究[J]. 硅酸盐通报,2009,28(5):951-954.
[13] DUAN Shue,ZHAI Yunhui,QU Yingjuan, et al . Synthesis and Antibacterial Activity of Silver-histimne Complex Doped Montmorillonite Antibacterial Agent[J]. Chem J Chinese Univ ,2012,33(12):2617-2622(in Chinese). 段淑娥,翟云会,屈颖娟,等. 银-组氨酸配合物-蒙脱石抗菌剂的制备及抗菌活性[J]. 高等学校化学学报,2012,33(12):2617-2622
[14] LIU Hui,ZHU Xiaping,FU Xiaojun, et al . Adsorption and Desorption Kinetics and Thermodynamics of Cadmium in Montmorillonite[J]. Multipurp Util Miner Resour ,2013,20(1):73-76(in Chinese). 刘慧,朱霞萍,付小君,等. 镉在蒙脱石上的吸附解吸动力学与热力学研究[J]. 矿产综合利用,2013,20(1):73-76.

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Influence of Reaction Temperature on the Amount of Silver Loaded on Montmorillonite and Its Sustained Release Performance

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