Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate

doi:10.11944/j.issn.1000-0518.2015.01.140071

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (1): 85-92.DOI: 10.11944/j.issn.1000-0518.2015.01.140071

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Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate

WU Qiong, XING Na^*, MA Xitong, XU Liting, XING Yongheng

College of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian,Liaoning 116029,China

Received:2014-03-10 Revised:2014-05-15 Published:2015-01-06 Online:2015-01-06
Contact: Corresponding author:XING Na, lecturer; Tel/Fax:0411-82156987; E-mail: scarllet_na@163.com; Research interests:coordination chemistry and industrial catalysis
Supported by:
Supported by the National Natural Science Foundation of China(No.21306073; No.21371086); The Science and Technology Fund for Outstanding Young Talents in Dalian(No.2012J21DW007)

Abstract

Abstract:

Cyclohexane oxidation is one of the most important industrial reactions. In order to find more efficient and cheap catalysts for this reaction, we studied the catalytic activity of ammonium paramolybdate(APM). By GC analysis, we focus on the effects of the species and the amount of the acids on the reactivity. Compared with nitric acid, lactic acid is more effective for the oxidation of cyclohexanol to cyclohexanone, and thus improve the TON(turn over number) value of the target products from 124 to 161. Furthermore, we propose a possible reaction mechanism of this new way for green oxidation of cyclohexane.

Key words: ammonium paramolybdate, lactic acid, nitric acid, cyclohexane oxidation, mechanism

CLC Number:

O643

WU Qiong,XING Na,MA Xitong,XU Liting,XING Yongheng. Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 85-92.

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Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate

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