Research Progress of AB2 Laves Phase Hydrogen Storage Alloys

doi:10.19894/j.issn.1000-0518.220304

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (5): 640-652.DOI: 10.19894/j.issn.1000-0518.220304

• Review • Previous Articles Next Articles

Research Progress of AB₂ Laves Phase Hydrogen Storage Alloys

Hai-Xiang XIU¹^,², Wan-Qiang LIU¹(), Dong-Ming YIN²(), Yong CHENG², Chun-Li WANG², Li-Min WANG²

^1.School of Materials Science and Engineering，Changchun University of Science and Technology，Changchun 130022，China
^2.State Key Laboratory of Rare Earth Resources Utilization，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China

Received:2022-09-15 Accepted:2023-03-08 Published:2023-05-01 Online:2023-05-26
Contact: Wan-Qiang LIU,Dong-Ming YIN
About author:dmyin@ciac.ac.cn
wqliu1979@126.com
Supported by:
the Major Science and Technology Project of Inner Mongolia(2021ZD0029);the National Key R&D Program of China(2020YFE0204500)

Abstract

Abstract:

AB₂ hydrogen storage alloy has attracted extensive research interest due to its advantages of high theoretical hydrogen storage capacity， long cycle life and high cost performance. However， AB₂ hydrogen storage alloy has some disadvantages such as activation difficulty， toxicity and high platform， which hinders its practical application. In recent years， aiming at the defects of AB₂ alloy， researchers have carried out a lot of modification studies and made great progress. This paper summarizes the research progress of AB₂-type hydrogen storage alloys in the past 30 years， focuses on the methods to improve its hydrogen storage performance， and puts forward the key research directions of AB₂-type alloys in the future.

Key words: AB₂ type hydrogen storage alloy, Laves phase, Modification treatment

CLC Number:

O614

Hai-Xiang XIU, Wan-Qiang LIU, Dong-Ming YIN, Yong CHENG, Chun-Li WANG, Li-Min WANG. Research Progress of AB₂ Laves Phase Hydrogen Storage Alloys[J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 640-652.

Figures/Tables 8

References 72

1	徐硕，余碧莹.中国氢能技术发展现状与未来展望［J］. 北京理工大学学报（社会科学版）， 2021， 23（6）： 1-12.
	XU S， YU B Y. Current development and prospect of hydrogen energy technology in China［J］. J B Inst Technol （Soc Sci Ed）， 2021， 23（6）： 1-12.
2	王丽娜，时哲，王玉辉. 氢能产业发展现状及展望［J］. 工业炉， 2022， 44（1）： 24-28.
	WANG L N， SHI Z， WANG Y H. Current situation and prospect of hydrogen energy industry［J］. Ind Furnace， 2022， 44（1）： 24-28.
3	刘翠伟，裴业斌，韩辉，等. 氢能产业链及储运技术研究现状及发展趋势［J］. 油气储运， 2022， 41（5）： 498-514.
	LIU C W， PEI Y B， HAN H， et al. Research status and development trend of hydrogen energy industry chain and the storage and transportation technologies［J］. Oil Gas Storage Transportation， 2022， 41（5）： 498-514.
4	雷超，李韬. 碳中和背景下氢能利用关键技术及发展现状［J］. 发电技术， 2021， 42（2）： 207-217.
	LEI C， LI T. Key technologies and development status of hydrogen energy utilization under the background of carbon neutrality［J］. Power Generation Technol， 2021， 42（2）： 207-217.
5	杨春. 我国氢能产业发展现状及战略政策动态研究［J］. 电工技术， 2022（2）： 20-22.
	YANG C. Research on the development status and strategic policy trends of chinas hydrogen energy［J］. Electr Eng， 2022（2）： 20-22.
6	周健，邓一荣，李晓源. 中国氢能发展的现状、挑战与建议［J］. 环境科学与管理， 2022， 47（3）： 15-19.
	ZHOU J， DENG Y R， LI X Y. Current status， challenges and suggestions of hydrogen power promotion in China［J］. Environ Sci Manage， 2022， 47（3）： 15-19.
7	ZHAO S， LIANG L， LIU B， et al. Superior dehydrogenation performance of α-AlH₃ catalyzed by Li₃N： realizing 8.0 wt.% capacity at 100 ℃［J］. Small， 2022， 18（17）： 2107983.
8	DING N， LI Y， LIANG F， et al. Highly efficient hydrogen storage capacity of 2.5 wt.% above 0.1 MPa using Y and Cr codoped V-based alloys［J］. ACS Appl Energy Mater， 2022， 5（3）： 3282-3289.
9	LING L， WANG C， REN M， et al. Unraveling the synergistic catalytic effects of TiO₂ and Pr₆O₁₁ on superior dehydrogenation performances of α-AlH₃［J］. ACS Appl Mater Interfaces， 2021， 13（23）： 26998-27005.
10	ZHENG W， SONG W， WU T， et al. Experimental investigation and thermodynamic modeling of the ternary Ti-Fe-Mn system for hydrogen storage applications［J］. J Alloys Compd， 2022， 891： 161957.
11	LU X， ZHANG L， ZHENG J， et al. Construction of carbon covered Mg₂NiH₄ nanocrystalline for hydrogen storage［J］. J Alloys Compd， 2022， 905： 164-169.
12	YU H， YANG X， JIANG X， et al. LaNi_5.5 particles for reversible hydrogen storage in N-ethylcarbazole［J］. Nano Energy， 2021， 80： 105476.
13	TÉLIZ E， ABBOUD M， FACCIO R， et al. Hydrogen storage in AB₂ hydride alloys： diffusion processes analysis［J］. J Electroanal Chem， 2020， 879： 114781.
14	LIU H， ZHANG J， SUN P， et al. Effect of oxygen on the hydrogen storage properties of TiFe alloys［J］. J Energy Storage， 2022， 55： 105543.
15	SUJAN G K， PAN Z， LI H， et al. An overview on TiFe intermetallic for solid-state hydrogen storage： microstructure， hydrogenation and fabrication processes［J］. Crit Rev Solid State Mater Sci， 2020， 45（5）： 410-427.
16	GRIGOROVA E， TZVETKOV P， TODOROVA S， et al. Facilitated synthesis of Mg₂Ni based composites with attractive hydrogen sorption properties［J］. Materials， 2021， 14（8）： 1936.
17	YOUP S M， KWAK Y J， CHOI E. Rate-controlling steps for the hydriding reaction of the intermetallic compound Mg₂Ni［J］. J Nanosci Nanotechnol， 2020， 20（11）： 7010-7017.
18	BAUM Z J， DIAZ L L， KONOVALOVA T， et al. Materials research directions toward a green hydrogen economy： a review［J］. ACS Omega， 2022， 7（37）： 32908-32935.
19	YE Y， YUE Y， LU J， et al. Enhanced hydrogen storage of a LaNi₅ based reactor by using phase change materials［J］. Renew Energy， 2021， 180： 734-743.
20	吴朝玲. 无钕稀土LPC系贮氢合金电极材料的开发研究［D］. 成都：四川大学， 2003.
	WU C L. Research on Nd-free LPC-type hydrogen storage alloys for hydride electrodes［D］. Chengdu： Sichuan University， 2003.
21	李学军，崔舜，周增林，等. 稀土（镁）系AB₂型贮氢合金的研究进展［J］. 材料导报， 2008（7）： 77-81.
	LI X J， CUI S， ZHOU Z L， et al. Research development of RE-（Mg）-system AB₂-type hydrogen storage alloys［J］. Mater Rev， 2008（7）： 77-81.
22	YARTYS V A， LOTOTSKYY M V. Laves type intermetallic compounds as hydrogen storage materials： a review［J］. J Alloys Compd， 2022： 165219.
23	秦高梧，谢红波，潘虎成，等. 一类介于晶体与准晶体之间的有序结构［J］. 金属学报， 2018， 54（11）： 1490-1502.
	QIN G W， XIE H B， PAN H C， et al. A new class of ordered structure between crystals and quasicrystals［J］. Acta Metall Sin， 2018， 54（11）： 1490-1502.
24	赵栋梁，韩忠刚，翟亭亭，等. TiFe基合金储氢活化性能研究进展［J］. 稀有金属， 2020， 44（4）： 337-351.
	ZHAO D L， HAN Z G， ZHAI T T， et al. Advances in activation property of hydrogen storage for TiFe-based alloy［J］. Chin J Rare Met， 2020， 44（4）： 337-351.
25	YU X， XIA B， WU Z， et al. Phase structure and hydrogen sorption performance of Ti-Mn-based alloys［J］. Mater Sci Eng A， 2004， 373（1/2）： 303-308
26	苏强. AB₂型Laves相储氢合金吸氢机理及掺杂元素作用机制的研究［D］. 南宁：广西大学， 2004.
	SU Q. Study on Absorb-hydrogen mechanism and functions of substitute element in AB₂ type Laves phase hydrogen storage alloys［D］. Nanning： Guangxi University， 2004.
27	SCHÜLKE M， KISS G， PAULUS H， et al. Complex surface analytical investigations on hydrogen absorption and desorption processes of a TiMn₂-based alloy［J］. Anal Bioanal Chem， 2009， 393： 1843-1856.
28	XIUMEI G， ERDONG W， SUCHENG W. Hydrogen storage properties of Laves phase Ti_1- xZrx（Mn_0.5Cr_0.5）₂ alloys［J］. Rare Met， 2006， 25（6）： 218-223.
29	张羊换，王国清，董小平，等. AB₂型Laves相贮氢合金的研究进展［J］. 金属功能材料， 2005（4）： 25-30.
	ZHANG Y H， WANG G Q， DONG X P， et al. Development research of AB₂-type Laves phase hydrogen storage alloy［J］. Met Funct Mater， 2005（4）： 25-30.
30	邓庆洲，陈德敏，杨柯，等. 一种快速凝固AB₂型储氢合金的球磨改性［J］. 物理化学学报， 1999（5）： 420-425.
	DENG Q Z， CHEN D M， YANG K， et al. Modification of a rapidly solidified AB₂ type hydrogen storage alloy by ball-milling［J］. Acta Phys-Chim Sin， 1999（5）： 420-425.
31	杨晓光. Zr-Cr-Ni系AB₂型Laves相贮氢合金及其电化学性能的研究［J］. 材料导报， 1996（1）： 78.
	YANG X G. Study on the electrochemical properties of Zr-Cr-Ni AB₂ type Laves phase hydrogen storage alloys［J］. Mater Rev， 1996（1）： 78.
32	WANG X L， SUDA S. Surface characteristics of fluorinated hydriding alloys［J］. J Alloys Compd， 1995， 231（1/2）： 380-386.
33	刘新，全钰泰. 碱液对AB₂型储氢合金活化性能的影响［J］. 渝州大学学报（自然科学版）， 2001（3）： 50-52.
	LIU X， QUAN Y T. The effect of alkaline solution on activation of AB₂hydrogen storage alloy［J］. J Chongqing Technol Business Univ （Nat Sci Ed）， 2001（3）： 50-52.
34	邢磊，李一鸣，张羊换，等. 快淬-退火La₄MgNi₁₉合金的电化学储氢性能及其失效行为［J］. 稀有金属， 2017， 41（12）： 1318-1326.
	XING L， LI Y M， ZHANG Y H， et al. Electrochemical hydrogen storage performances and degradation behavior of rapidquenching-annealed La₄MgNi₁₉ alloy［J］. Chin J Rare Met， 2017， 41（12）： 1318-1326.
35	刘泽民，张素银，邵诚，等. 无稀土MnBi永磁合金的研究进展［J］. 科技资讯， 2016， 14（34）： 80-84.
	LIU Z M， ZHANG S Y， SHAO C， et al. The research progress of rare-earth free permanent magnetic alloy in MnBi［J］. Sci Technol Inf， 2016， 14（34）： 80-84.
36	张羊换，李平，王新林，等. 快淬对AB₂型贮氢合金电化学性能与微观结构的影响［J］. 功能材料， 2004（3）： 298-301.
	ZHANG Y H， LI P， WANG X L， et al. The effects of rapid quenching on the electrochemical characteristics and microstructures of AB₂ Laves phase electrode alloys［J］. J Funct Mater， 2004（3）： 298-301.
37	张羊换，李平，王新林，等. 熔体快淬对AB₂型Laves相储氢电极合金循环寿命的影响［J］. 稀有金属材料与工程， 2004（12）： 1321-1324.
	ZHANG Y H， LI P， WANG X L， et al. The effect of rapid quenching on the cycle lives of H₂-storage electrode alloys with AB₂ Laves phase［J］. Rare Met Mater Eng， 2004（12）： 1321-1324.
38	ZHANG Y， ZHANG W， SONG X， et al. Effects of spinning rate on structures and electrochemical hydrogen storage performances of RE-Mg-Ni-Mn-based AB₂-type alloys［J］. T Nonferr Met Soc， 2016， 26（12）： 3219-3231.
39	翟亭亭. La-Mg-Ni系AB₂型贮氢合金的结构、贮氢性能及容量衰退机理研究［D］. 沈阳：东北大学， 2015.
	ZHAI T T. Structure， hydrogen storage properties anddegradation mechanism of capacity of La-Mg-Ni system AB₂ type alloys［D］. Shenyang： Northeastern University， 2015.
40	张云龙. 非计量比Zr基Laves相合金的微结构及储氢性能［D］. 西安：西北工业大学， 2017.
	ZHANG Y L. Microstructures and hydrogen storage properties of non-stoichiometric Zr-based Laves phase alloys［D］. Xi′an： Northwestern Polytechnical University， 2017.
41	刘海镇，徐丽，郭秀梅，等. Ti-Mn系AB₂型Laves相储氢合金研究［J］. 稀有金属， 2019， 43（9）： 928-934.
	LIU H Z， XU L， GUO X M， et al. Hydrogen storage properties of Ti-Mn based AB₂-type Laves phase alloys［J］. Chin J Rare Met， 2019， 43（9）： 928-934.
42	YOUNG K， OUCHI T， KOCH J， et al. Compositional optimization of vanadium-free hypo-stoichiometric AB₂ metal hydride alloy for Ni/MH battery application［J］. J Alloys Compd， 2012， 510（1）： 97-106.
43	姜婉婷，罗永春，赵磊，等. 稀土元素对R-Y-Ni系A₂B₇型无镁储氢合金微观结构和电化学性能的影响［J］. 无机化学学报， 2018， 34（10）： 1817-1825.
	JIANG W T， LUO Y C， ZHAO L， et al. Effect of rare earth elements on the microstructure and electrochemical properties of Mg-free R-Y-Ni based A₂B₇-type hydrogen storage alloys［J］. Chin J Inorg Chem， 2018， 34（10）： 1817-1825.
44	LI K， LUO Y， WANG W， et al. Effects of scandium on hydrogen storage and electrochemical properties of AB₂-type Zr_1- xScxMn_0.6V_0.2Ni_1.2Co_0.1（x=0~1） alloys［J］. J Chin Rare Earth Soc， 2013， 31（4）： 442-449.
45	QIN C， WANG H， LIU J， et al. Tuning hydrogen storage thermodynamic properties of ZrFe₂ by partial substitution with rare earth element Y［J］. Int J Hydrog Energy， 2021， 46（35）： 18445-18452.
46	YAO Z， LIU L， XIAO X， et al. Effect of rare earth doping on the hydrogen storage performance of Ti_1.02Cr_1.1Mn_0.3Fe_0.6 alloy for hybrid hydrogen storage application［J］. J Alloys Compd， 2018， 731： 524-530.
47	ZHOU L， LI W， HU H， et al. Ce-doped TiZrCrMn alloys for enhanced hydrogen storage［J］. Energy Fuels， 2022， 36（7）： 3997-4005.
48	尚宏伟. 稀土镁基AB₂型LaMgNi₄系贮氢合金电化学性能及气态储氢性能的研究［D］. 包头：内蒙古科技大学， 2013.
	SHAGN H W. An investigation on the electrochemical performance andgaseous hydrogen storage performance of RE-Mg based LaMgNi₄-type hydrogen storage alloy［D］. Baotou： Inner Mongolia University of Science and Technology， 2013.
49	SIVOV R B， ZOTOV T A， VERBETSKY V N. Interaction of ZrFe₂ doped with Ti and Al with hydrogen［J］. Inorg. Mater， 2010， 46（4）： 372-376.
50	杨康，蒋利军，苑慧萍，等. Ce替代Y对Y_1- xCexFe₂（x=0，0.15，0.25和0.50）合金吸氢性能的影响［J］. 稀有金属， 2017， 41（11）： 1202-1207.
	YANG K， JIANG L J， YUAN H P， et al. Hydrogen absorption property of Y_1- xCexFe₂（x=0， 0.15， 0.25 and 0.50） alloys with Ce substitution for Y［J］. Chin J Rare Met， 2017， 41（11）： 1202-1207.
51	ZOTOV T， MOVLAEV E， MITROKHIN S， et al. Interaction in （Ti，Sc） Fe₂-H₂ and （Zr，Sc） Fe₂-H₂ systems［J］. J Alloys Compd， 2008， 459（1/2）： 220-224.
52	ZHAO S， WANG H， LIU J. Exploring the hydrogen-induced amorphization and hydrogen storage reversibility of Y（Sc）_0.95Ni₂ Laves phase compounds［J］. Materials， 2021， 14（2）： 276.
53	SIVOV R， ZOTOV T， VERBETSKY V. The influence Y， Gd and Dy doping on hydrogen sorption properties of ZrFe₂［J］. Interact Hydrogen Isot Struct Mater （IHISM-08 Junior）， Sarov， 2009： 201-208.
54	WONG D F， YOUNG K， NEI J， et al. Effectsof Nd-addition on the structural， hydrogen storage， andelectrochemical properties of C14 metal hydride alloys［J］. J Alloys Compd， 2015， 647： 507-518.
55	庞浩良. 元素替代对Y系AB₂型储氢合金结构和性能的影响研究［D］. 广州：华南理工大学， 2018.
	PANG H L. Alloying substitution on structure and properties of Y based AB₂ hydrogen storage alloys［D］. Guangzhou： South China University of Technology， 2018.
56	黎子鸣. YFe₂基新型稀土合金结构与性能的关系［D］. 广州：华南理工大学， 2019.
	LI Z M. The relation between structure and properties in novel YFe₂-based rare earth alloys［D］. Guangzhou： South China University of Technology， 2019.
57	QIN C， ZHOU C， OUYANG L， et al. High-pressure hydrogen storage performances of ZrFe₂ based alloys with Mn， Ti， and V addition［J］. Int J Hydrogen Energy， 2020， 45（16）： 9836-9844.
58	李吉刚，盛鹏，徐丽，等. （Ti_1- xZrx）yCr_2.0- zVz合金制备和吸放氢性能的研究［J］. 中国科技论文， 2017， 12（24）： 2761-2766.
	LI J G， SHENG P， XU L， et al. Preparation and hydrogen absorption/desorption properties of （Ti_1- xZrx）yCr_2.0- zVz alloys［J］. China Sci Paper， 2017， 12（24）： 2761-2766.
59	AOKI K， LI H W， DILIXIATI M， et al. Formation of crystalline and amorphous hydrides by hydrogenation of C15 Laves phase YFe₂［J］. Mater Sci Eng， 2007， 449： 2-6.
60	AOKI K， LI X， MASUMOTO T. Factors controlling hydrogen-induced amorphization of C15Laves compounds［J］. Acta Metallurgica Et Materialia， 1992， 40（7）： 1717-1726.
61	CHUNG U I， KIM Y G， LEE J Y. General features of hydrogen-induced amorphization in RM₂ （R=rare earth， M=transition element） Laves phases［J］. Philos Mag B， 1991， 63（5）： 1119-1130.
62	LI J， GUO Y， JIANG X， et al. Hydrogen storage performances， kinetics and microstructure of Ti_1.02Cr_1.0Fe_0.7- xMn_0.3Alx alloy by Al substituting for Fe［J］. Renew Energy， 2020， 153： 1140-1154.
63	吴天栋. Zr基Laves相储氢合金的构效关系及抗毒化行为［D］. 西安：西北工业大学， 2017.
	WU T D. Structure-activity relationship of Zr-based Laves phase hydrogen storage alloys and poisoning resistance against gaseous impurities［D］. Xi′an： Northwestern Polytechnical University， 2017.
64	张思方. 元素替代对Zr基AB₂型贮氢合金相结构与电化学性能的影响［D］. 长沙：中南大学， 2008.
	ZHANG S F. Effect of elemental substitution on phase structure and electrochemical properties of Zr-based AB₂ hydrogen storage alloys［D］. Changsha： Central South University， 2008.
65	李晋平，李冬梅，郎卫平，等. ZrCr_2- xFex合金表面性质及中毒研究［J］. 矿冶工程， 1994（4）： 61-63.
	LI J P， LI D M， LANG W P， et al. Study on surface properties and toxicity of ZrCr_2- xFex alloy［J］. Min Metall Eng， 1994（4）： 61-63.
66	LUAN B， CUI N， ZHAO H， et al. Effects of potassium-boron addition on the performance of titanium based hydrogen storage alloy electrodes［J］. Int J Hydrogen Energy， 1996， 21（5）： 373-379.
67	YU X， WU Z， HUANG T， et al. Effect of carbon addition on activation and hydrogen sorption characteristics of TiMn_1.25Cr_0.25 alloy［J］. Mater Chem Phys， 2004， 83（2/3）： 273-277.
68	YOUNG K， OUCHI T， HUANG B， et al. Effects of B， Fe， Gd， Mg， and C on the structure， hydrogen storage， and electrochemical properties of vanadium-free AB₂ metal hydride alloy［J］. J Alloys Compd， 2012， 511（1）： 242-250.
69	DRAŠNER A， BLAẐINA Ẑ. The influence of Si and Ge on the hydrogen sorption properties of the intermetallic compound ZrCr₂［J］. J Alloys Compd， 1993， 199（1/2）： 101-104.
70	ZOTOV T A， SIVOV R B， MOVLAEV E A， et al. IMC hydrides with high hydrogen dissociation pressure［J］. J Alloys Compd， 2011， 509： S839-S843.
71	LIU S， LU G. Interaction of cationic vesicle with ribonucleotides （AMP， ADP， and ATP） and physicochemical characterization of DODAB/ribonucleotides complexes［J］. Biophys Chem， 2007， 127（1/2）： 19-27.
72	YOUNG K， REICHMAN B， FETCENKO M A. Electrochemical performance of AB₂ metal hydride alloys measured at -40 ℃［J］. J Alloys Compd， 2013， 580： S349-S352.

Element	Add methods	Master alloy	Capacity	Activation performance	Platform slope	Ref.
Sc	Substituted Zr	ZrMn_0.6V_0.2Ni_1.2Co_0.1	Increased	Easy	Unknown	［44］
Y	Substituted Zr	ZrFe₂	Increased	Easy	Increased	［45］
La	Doped	Ti_1.02Cr_1.1Mn_0.3Fe_0.6	Increased	Easy	Increased	［46］
Ho	Doped	Ti_1.02Cr_1.1Mn_0.3Fe_0.6	Increased	Easy	Increased	［46］
Ce	Doped	Ti_0.8Zr_0.2Cr_0.75Mn_1.25	Increased	Easy	Increased	［47］
Pr	Substituted La	LaMgNi₄	Increased	Easy	Unknown	［48］
Nb	Substituted La	LaMgNi₄	Increased	Easy	Unknown	［48］
Sm	Substituted La	LaMgNi₄	Increased	Easy	Unknown	［48］

Element	Add methods	Master alloy	Capacity	Activation performance	Platform slope	Ref.
Sc	Substituted Zr	ZrMn_0.6V_0.2Ni_1.2Co_0.1	Increased	Easy	Unknown	［44］
Y	Substituted Zr	ZrFe₂	Increased	Easy	Increased	［45］
La	Doped	Ti_1.02Cr_1.1Mn_0.3Fe_0.6	Increased	Easy	Increased	［46］
Ho	Doped	Ti_1.02Cr_1.1Mn_0.3Fe_0.6	Increased	Easy	Increased	［46］
Ce	Doped	Ti_0.8Zr_0.2Cr_0.75Mn_1.25	Increased	Easy	Increased	［47］
Pr	Substituted La	LaMgNi₄	Increased	Easy	Unknown	［48］
Nb	Substituted La	LaMgNi₄	Increased	Easy	Unknown	［48］
Sm	Substituted La	LaMgNi₄	Increased	Easy	Unknown	［48］

Element	Add methods	Master alloy	Capacity	Pressure of platform	Ref.
Mo	Substituted Fe	YFe₂	Decreased	Increased	［55］
Al	Substituted Fe	YFe₂	Decreased	Unknown	［56］
Ti	Substituted Zr	ZrFe₂	Decreased	Decreased	［57］
Mn	Substituted Fe	ZrFe₂	Increased	Decreased	［57］
Zr	Substituted Ti	TiCr₂	Increased	Decreased	［58］

Element	Add methods	Master alloy	Capacity	Pressure of platform	Ref.
Mo	Substituted Fe	YFe₂	Decreased	Increased	［55］
Al	Substituted Fe	YFe₂	Decreased	Unknown	［56］
Ti	Substituted Zr	ZrFe₂	Decreased	Decreased	［57］
Mn	Substituted Fe	ZrFe₂	Increased	Decreased	［57］
Zr	Substituted Ti	TiCr₂	Increased	Decreased	［58］

Alloy	Capacity before poisoning/（m·g^-1）	Capacity before poisoning/（m·g^-1）	Capacity retention rate/%
ZrCr_0.8Fe_1.2	154.1	0	0
ZrCr_0.6Fe_1.4	141.5	80.3	56.7
ZrCr_0.4Fe_1.6	122.9	98.3	79.7
ZrCr_0.2Fe_1.8	96.0	38.0	39.6

Research Progress of AB₂ Laves Phase Hydrogen Storage Alloys

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 72

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Peng BU, Hong-Liang LI. Preparation and Upconversion Luminescence Study of Rare Earth Yb³⁺/Tm³⁺ Doped NaGd（MO₄）₂ Phosphors [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 374-379.
[2]	Li-Yan CHEN, Zi-Ming ZHAO, Jin-Qi TAO, Yu-Zhen ZHANG, Gang CHENG, Yun-Jun SHEN. Synthesis of Mono- and Binuclear Disulfur-Chelated Organoplatinum（Ⅱ） Complexes and Its OLEDs Application [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 236-244.
[3]	Jin-Jian LIU, Na LIU, Feng-Yi YANG. Synthesis and Photochromic Properties of Two Isostructural Viologen Coordination Polymers [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 245-251.
[4]	Li-Jun WU, Shou-Jie GUO, Chao ZHANG, Zhi-Sheng LI, Wei-Cong LI, Chang-Chun YANG. In⁃situ Electrochemical Preparation of Li⁃Na Alloy and the Co⁃storage of Li⁺ and Na⁺ Ions [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1757-1765.
[5]	Zi-Ang WANG, Li-Xing CAO, Pan SHAO, Meng-Yu ZHU, En-Ning LIU, Shuang LIANG, Yang XING, Ling DI, Zhan-Xu YANG. Detection and Theoretical Study of Fukui Function of Nitroaromatics by Carbazole‑Based Iridium（Ⅲ） Phosphorescent Probe [J]. Chinese Journal of Applied Chemistry, 2022, 39(10): 1617-1626.
[6]	Yun-Long TANG. Construction of Novel Ferroelectric Polarization Topologies and Their Atomic‑Scale Properties [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1319-1320.
[7]	Xue-Ting WU, Yang YU, Shu-Yan SONG, Hong-Jie ZHANG. Artificial Carbon Sequestration Technology—Research Progress on the Catalysts for Thermal Catalytic Reduction of CO₂ [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 599-615.
[8]	Song-Tao ZHANG, Ying-Hui WANG, Hong-Jie ZHANG. Nd³⁺ Sensitized Fluorescent Nanoprobes for Vascular Imaging in the Second Near Infrared Window [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 685-693.
[9]	Hui DU, Chen-Yang YAO, Hao PENG, Bo JIANG, Shun-Xiang LI, Jun-Lie YAO, Fang ZHENG, Fang YANG, Ai-Guo WU. Applications of Transition Metal⁃doped Iron⁃based Nanoparticles in Biomedicine [J]. Chinese Journal of Applied Chemistry, 2022, 39(3): 391-406.
[10]	Bo-Yang CUI, Hong-Da WU, Zong-Bao YU, Zong-Xing GENG, Tie-Qiang REN, Chun-Wei SHI, Zhan-Xu YANG. Preparation of Molybdenum Phosphide⁃based Catalyst and Its Application in Water Electrolysis [J]. Chinese Journal of Applied Chemistry, 2022, 39(3): 439-450.
[11]	Rui WANG, Ming-Yang GAO, Jing-Pei CAO. Effects of Alkali/Alkaline Earth Metals on Fast Pyrolysis of Pine Sawdust [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 289-297.
[12]	LI Chun, YU Yan-Hao. Research Progress on Mechanism and Application of Biomimetic Mineralization [J]. Chinese Journal of Applied Chemistry, 2022, 39(1): 74-85.
[13]	GUO Shao-Bo, LIANG Yan-Li, LIU Zhi-Feng, ZHANG Qiang, MA Jian-Qi. Synergistic Antibacterial Activity of Tetracycline Combined with Silver Nanoparticles [J]. Chinese Journal of Applied Chemistry, 2021, 38(11): 1462-1468.
[14]	WU Yu, LIU Jia-Cheng. Preparation and Characterization of Dye-sensitized Solar Cells by Inverted Coordination Self-assembly [J]. Chinese Journal of Applied Chemistry, 2021, 38(11): 1494-1502.
[15]	TIAN Shu-Yang, LYU Rong-Wen. Solvent-Free Oxidation of Benzyl Alcohol to Benzaldehyde Catalyzed by Magnesium Oxide Supported Bimetallic Gold-Palladium [J]. Chinese Journal of Applied Chemistry, 2021, 38(7): 789-799.