Advances of High-Performance Polymer Binders for Silicon-Based Anodes

doi:10.19894/j.issn.1000-0518.220284

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (5): 625-639.DOI: 10.19894/j.issn.1000-0518.220284

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Advances of High-Performance Polymer Binders for Silicon-Based Anodes

Bing-Shuai CHEN¹, Hai-Tao ZHUO²(), Shu HUANG³, Shao-Jun CHEN¹()

^1.School of Materials Science and Engineering，Shenzhen University，Shenzhen 518060，China
^2.School of Chemistry and Environmental Engineering，Shenzhen University，Shenzhen 518060，China
^3.BTR New Material Group Co. ?，Ltd. ，Shenzhen 518060，China

Received:2022-08-25 Accepted:2023-03-08 Published:2023-05-01 Online:2023-05-26
Contact: Hai-Tao ZHUO,Shao-Jun CHEN
About author:haitaozhuo@163.com
chenshaojun2@163.com
Supported by:
the Natural Science Foundation of Guangdong Province(2022A1515011985);Shenzhen Basic Research Project(JCYJ20190808115609663)

Abstract

Abstract:

Silicon （Si） has become the most promising anode material for the next generation lithium-ion battery because of its ultra-high theoretical specific capacity. However， the intercalation and removal of lithium-ions will cause a great change in the volume of silicon microparticles（SiMP）， which will lead to the pulverization of SiMP and irreversible attenuation of electrode capacity， which seriously limits the wide application of silicon-based materials. A large number of reports in the past have shown that polymer binder can effectively overcome the “island effect” caused by the volume expansion of SiMP. It could maintain the integrity of the electrode in the charge-discharge process， and then improve the electrochemical performance of the electrode. According to the structure classification of polymer binders， they can be roughly divided into four categories， linear， branched， cross-linked and conjugated. When the binders with different molecular structures are used as silicon-based negative electrode， the electrodes show different electrochemical properties. Particularly， when polymer binders with multiple molecular structures are designed， the practical application of silicon-based negative electrodes will be greatly promoted. By analyzing the effects of various polymer binders on the electrochemical properties of silicon anode， the differences of binders with different molecular structures can be clearly obtained， and then provide ideas for the development of silicon anode polymer binder in the future. Finally， this paper proposes the design direction of the next-generation polymer binder to promote its development towards large-scale application and industrial production.

Key words: Polymer, Chain structure, Binder, Silicon-based anode, Lithium ion battery

Bing-Shuai CHEN, Hai-Tao ZHUO, Shu HUANG, Shao-Jun CHEN. Advances of High-Performance Polymer Binders for Silicon-Based Anodes[J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 625-639.

Figures/Tables 9

References 89

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Binder	Binder ratio/%	Areal loading/（mg·cm^-2）	Initial CE/%	Cycling performance	Current rate/（mA·g^-1）	Year	Ref.
CS	20		89	1 969 mA·h/g after 100 cycles	500	2015	［22］
PVDF-b-PTFE	5	1		250 cycles	4 200	2020	［24］
PSA	20	1.2	72	2 371 mA·h/g after 100 cycles	1 800	2020	［26］
PSEA	10	1.5	85.1	400 cycles	2 100	2022	［27］
C-CS	8		89	950 mA·h/g after 50 cycles	500	2014	［28］
CGG	20	0.8		1 138 mA·h/g after 200 cycles	1 000	2019	［29］
1-CMT	20	0.75	90.96	1 176 mA·h/g after 200 cycles	2 000	2022	［30］

Binder	Binder ratio/%	Areal loading/（mg·cm^-2）	Initial CE/%	Cycling performance	Current rate/（mA·g^-1）	Year	Ref.
CS	20		89	1 969 mA·h/g after 100 cycles	500	2015	［22］
PVDF-b-PTFE	5	1		250 cycles	4 200	2020	［24］
PSA	20	1.2	72	2 371 mA·h/g after 100 cycles	1 800	2020	［26］
PSEA	10	1.5	85.1	400 cycles	2 100	2022	［27］
C-CS	8		89	950 mA·h/g after 50 cycles	500	2014	［28］
CGG	20	0.8		1 138 mA·h/g after 200 cycles	1 000	2019	［29］
1-CMT	20	0.75	90.96	1 176 mA·h/g after 200 cycles	2 000	2022	［30］

Binder	Binder ratio/%	Areal loading/（mg·cm^-2）	Initial CE/%	Cycling performance	Current rate/（mA·g^-1）	Year	Ref.
CS-PAANa	30	0.22	85.96	1 608 mA·h/g after 100 cycles	420	2019	［31］
CS-g-GA	20	0.5~0.6	73.11	1 868 mA·h/g after 350 cycles	2 100	2022	［32］
GA-g-PAA	10	1~1.2	82.7	2 196.1 mA·h/g after 150 cycles	400	2021	［33］
GA-g-PAA/P	10			100 cycles	400	2021	［34］
PVA-g-P （AA-LiAA-HEA）	10		90.9	2 265 mA·h/g after 200 cycles	1 000	2020	［36］

Binder	Binder ratio/%	Areal loading/（mg·cm^-2）	Initial CE/%	Cycling performance	Current rate/（mA·g^-1）	Year	Ref.
CS-PAANa	30	0.22	85.96	1 608 mA·h/g after 100 cycles	420	2019	［31］
CS-g-GA	20	0.5~0.6	73.11	1 868 mA·h/g after 350 cycles	2 100	2022	［32］
GA-g-PAA	10	1~1.2	82.7	2 196.1 mA·h/g after 150 cycles	400	2021	［33］
GA-g-PAA/P	10			100 cycles	400	2021	［34］
PVA-g-P （AA-LiAA-HEA）	10		90.9	2 265 mA·h/g after 200 cycles	1 000	2020	［36］

Binder	Binder ratio/%	Areal loading/（mg·cm^-2）	Initial CE/%	Cycling performance	Current rate/（mA·g^-1）	Year	Ref.
L-co-PAA	20	0.6~0.8	84	939 mA·h/g after 1000 cycles	840	2022	［39］
OS-PAA	10		62.39	1 386.2 mA·h/g after 100 cycles	200	2021	［40］
P（AA-co-nBA）	15	0.55~0.68	72.5	960 mA·h/g after 100 cycles	500	2020	［41］
PAA-borax	20	1.2~1.5	85	1 649 mA·h/g after 100 cycles	2 000	2020	［43］
PAA-co-SN	20	0.8	79.3	1 580 mA·h/g after 500 cycles	840	2022	［46］
PG-c-ECH	10	1.77	81.6	2 060 mA·h/g after 200 cycles	2 000	2021	［44］
β-CD-CMC	20		85.11	1 702 mA·h/g after 200 cycles	2 100	2022	［45］
PAM	20	0.6		1 526 mA·h/g after 500 cycles	716	2020	［47］
CMC-NaPAA-PAM	20	0.75	84	1 210.7 mA·h/g after 150 cycles	420	2019	［48］
GG/XNBR	20	0.53		1 929 mA·h/g after 100 cycles	1 000	2021	［50］
SHPET	20	1.2		870 mA·h/g after 250 cycles	4 200	2021	［53］
PAA-TUEG	10	0.5	87.2	2 744.3 mA·h/g after 300 cycles	2 100	2022	［54］
CMC/TU		0.8~1	89.9	1 059 mA·h/g after 150 cycles	840	2022	［55］
PAA-UPy	20	0.4~0.6	86.4	2 638 mA·h/g after 110 cycles	2 100	2018	［57］
UPy-PEG-UPy	15		81	1 454 mA·h/g after 400 cycles		2018	［58］
PAU-g-PEG	20	0.5~1	70.4	1 450.2 mA·h/g after 350 cycles	2 100	2020	［59］
CPAU	10		87.1	2 768.8 mA·h/g after 150 cycles	840	2021	［60］
CA-PAA	10	0.6	89.5	300 cycles	420	2021	［61］
PAA-β-CDp	20		85.9	2 326.4 mA·h/g after 100 cycles	200	2022	［62］
GCS-I-OSA	20	0.35~0.45	77.1	2 316 mA·h/g after 100 cycles	840	2021	［63］
CS-EDTA			62.8	721 mA·h/g after 200 cycles	1 000	2022	［64］
SHA	20	0.5~0.7	92.67	1 407 mA·h/g after 100 cycles	4 000	2022	［68］
γCDp/Py-PAA	10	1.35~1.45	88.2	300 cycles	2 100	2022	［70］
PAA-PEI	20	0.5~0.7		2 606 mA·h/g after 100 cycles	840	2021	［71］
PAA-PEI-c	20			100 cycles	1 400	2022	［72］
TEGPAA-TA	10	0.6	83.2	100 cycles	1 330	2021	［73］
c-Pec-g-PAAm	15	1.2		729 mA·h/g after 300 cycles	2 100	2020	［74］
PAA-BFPU	15	1.0	＞89	200 cycles	2 000	2020	［75］

Advances of High-Performance Polymer Binders for Silicon-Based Anodes

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Binder	Binder ratio/%	Areal loading/（mg·cm^-2）	Initial CE/%	Cycling performance	Current rate/（mA·g^-1）	Year	Ref.
CG	10		80	1 500 mA·h/g after 700 cycles	840	2018	［79］
ESVCA	40	0.53		1 786 mA·h/g after 200 cycles	500	2019	［80］
PPP	20	0.4		200 cycles	840	2020	［81］
PAAA	25	1.5		1 000 mA·h/g after 300 cycles	750	2018	［82］
CS-g-PANI	25	0.8~0.9	72.4	1 091 mA·h/g after 200 cycles	4 200	2020	［83］
Alg-g-PAMAT	15	1.2		701.2 mA·h/g after 200 cycles	2 100	2022	［85］
PF-co-PDs				1 250 mA·h/g after 500 cycles	420	2020	［87］
PFP-g-PEG	10	0.6		605 mA·h/g after 1000 cycles	1 400	2017	［88］
PFPQDA	33	0.8	72.3	2 227 mA·h/g after 150 cycles	840	2022	［89］

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