Multiple-Responsive Coordination Polymers Based on a Carboxybenzyl Viologen Ligand

doi:10.19894/j.issn.1000-0518.220187

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (3): 397-403.DOI: 10.19894/j.issn.1000-0518.220187

• Full Papers • Previous Articles Next Articles

Multiple-Responsive Coordination Polymers Based on a Carboxybenzyl Viologen Ligand

Jin-Jian LIU¹^,²(), Yi-Wei LU²

^1.Modern College of Humanities and Science of Shanxi Normal University，Linfen 041000，China
^2.School of Chemistry and Material Science，Shanxi Normal University，Taiyuan 030031，China

Received:2022-05-23 Accepted:2022-11-15 Published:2023-03-01 Online:2023-03-27
Contact: Jin-Jian LIU
About author:liujj@sxnu.edu.cn
Supported by:
the Shanxi Province Graduate Education Innovation Project(2021L608)

1. .pdf(516KB)

Abstract

Abstract:

With the continuous development of smart materials， multiple-responsive viologen coordination polymers are expected to be applied in engineering fields such as materials science and biology， and have aroused extensive interest. In order to obtain such compounds， a carboxybenzyl viologen ligand， 1，1'-bis（4-carboxybenzyl）-4，4'-bipyridine dichloride （H₂BpybcCl₂） is used as the functional ligand to react with the transition metal ions Ni²⁺ （1），Mn²⁺ （2） and Co²⁺ （3） to form three isostructural two-dimensional （2D） coordination polymers ｛［M₂（Bpybc）₃（H₂O）₆］·（OH）₄·nH₂O｝ _n . Due to the existence of viologen radicals， the three compounds exhibited photochromic behaviors under UV light irradiation. Upon heating， the three compounds also showed obvious color changes due to d-d transitions in the coordination field caused by dehydration.

Key words: Viologens, Coordination polymers, Photochromism, Thermochromism

CLC Number:

O612

Jin-Jian LIU, Yi-Wei LU. Multiple-Responsive Coordination Polymers Based on a Carboxybenzyl Viologen Ligand[J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 397-403.

Figures/Tables 4

Fig.1 Crystal structure （A） and two-dimensional infinite layer （B） for compound 1

Fig.2 The color changes of crystals for compounds 1 （A）， 2 （B） and 3 （C） under irradiation； The color changes of crystals for compounds 1 （D）， 2 （E） and 3 （F） under heating

Fig.3 UV-Vis spectra for compounds 1 （A）， 2 （B） and 3 （C） before and after irradiation or heating； EPR spectra for compounds 1 （D）， 2 （E） and 3 （F） before and after irradiation or heating

Fig.4 XPS core-level spectra （A： C1s； B： N1s； C： O1s； D： Co2p） of compound 3 before irradiation （3） and after irradiation （3P）

References 22

1	LI G P， HAO P F， FU Y L， et al. Bipyridyltriazolium chlorobismuthate with thermo-/photochromic and photoluminescent switching behaviors based on ET and CT［J］. Inorg Chem， 2016， 55（21）： 11342-11347.
2	SUN J K， YANG X D， YANG G Y， et al. Bipyridinium derivative-based coordination polymers： from synthesis to materials applications［J］. Coord Chem Rev， 2019， 378： 533-560.
3	HAO P F， GUO C Y， WANG M D， et al. Lattice water controlled photo- and thermochromism of N-protonated carbomethoxypyridinium iodoargentate hybrids［J］. Inorg Chem， 2019， 58： 3364-3373.
4	隋琪. 紫精-双羧酸化合物的设计合成及其变色性质研究［D］. 上海：华东师范大学， 2018.
	SUI Q. Design， synthesis and chromic properties of viologen-dicarboxyl compounds［D］. Shanghai： East China Normal University， 2018.
5	SUN J K， WANG P， YAO Q X， et al. Solvent- and anion-controlled photochromism of viologen-based metal-organic hybrid materials［J］. J Mater Chem， 2012， 22： 12212-12219.
6	YANG X D， CHEN C， ZHANG J， et al. The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers［J］. Inorg Chem Commun， 2015， 60： 122-125.
7	GE B D， HAN S D， WANG G M， et al. Coordination-driven strategy towards crystalline hybrid photochromic materials via the marriage of a non-photochromic extended dipyridine unit and zincophosphate［J］. J Mater Chem C， 2019， 7： 3920-3923.
8	ZHANG C， SUN L， YAN Y， et al. A novel photo- and hydrochromic europium metal-organic framework with good anion sensing properties［J］. J Mater Chem C， 2017， 5（35）： 8999-9004.
9	CHEN Z W， LU G， LI P X， et al. Influence of supramolecular interactions on electron-transfer photochromism of the crystalline adducts of 4，4'-bipyridine and carboxylic acids［J］. Cryst Growth Des， 2014， 14： 2527-2531.
10	LI P， WANG M， CAI L， et al. Rare electron-transfer photochromic and thermochromic difunctional compounds［J］. J Mater Chem C， 2015， 3（2）： 253-256.
11	LIU J， LU Y， LU W. Metal-dependent photosensitivity of three isostructural 1D CPs based on the 1，1′-bis（3-carboxylatobenzyl）-4，4′-bipyridinium moiety［J］. Dalton Trans， 2020， 49： 4044-4049.
12	DONG Z P， ZHAO G G， LIU P Y， et al. A metal-organic framework constructed by a viologen-derived ligand： photochromism and discernible detection of volatile amine vapors［J］. New J Chem， 2019， 43： 9032-9038.
13	LI W B， YAO Q X， SUN L， et al. A viologen-based coordination polymer exhibiting high sensitivity towards various light sources［J］. CrystEngComm 2017， 19： 722-726.
14	LI S L， HAN M， ZHANG Y， et al. X-Ray and UV dual photochromism， thermochromism， electrochromism， and amine-selective chemochromism in an anderson-like Zn7 cluster-based 7-fold interpenetrated framework［J］. J Am Chem Soc， 2019， 141（32）： 12663-12672.
15	LIU J， LU Y， LU W. Sun， UV and X-ray triple photochromic properties of three coordination polymers based on 1，1′-bis（3-carboxylatobenzyl）-4，4′-bipyridinium ligand［J］. CrystEngComm， 2020， 22： 2121-2127.
16	SUN Y， ZHANG J， JU Z， et al. Two-dimensional noninterpenetrating transition metal coordination polymers with large honeycomb-like hexagonal cavities constructed from a carboxybenzyl viologen ligand［J］. Cryst Growth Des， 2005， 5（5）： 1939-1943.
17	ZHANG P， YANG X， SUN L， et al. The effect of different substituent groups of auxiliary ligands on the photochromic behaviors of bipyridinium-based coordination polymers［J］. Inorg Chem Commun， 2017， 75： 8-11.
18	LIU J， GUAN Y， LIN M， et al. Anion-mediated architecture and photochromism of rigid bipyridinium-based coordination polymersc［J］. Cryst Growth Des， 2016， 16（5）： 2836-2842.
19	YANG X， CHEN C， ZHANG Y， et al. Halogen-bridged metal-organic frameworks constructed from bipyridinium-based ligand： structures， photochromism and non-destructive readout luminescence switching［J］. Dalton Trans， 2016， 45（11）： 4522-4527.
20	LIU J， LU Y， LU W. Metal-controlled architecture and photochromism of three coordination polymers based on N，N′- bis（carboxyethyl）-4，4′-bipyridinium ligand［J］ . Dyes Pigm， 2020， 180： 108498.
21	LI X， TU Z， LI L， et al. A novel viologen-based coordination polymer with multi-stimuli responsive chromic properties： photochromism， thermochromism， chemochromism and electrochromism［J］. Dalton Trans， 2020， 49（1）： 3228-3233.
22	LIU J， LU Y， LU W. Photochromism and hydrochromism of three two-dimensional coordination polymers constructed from a carboxybenzyl viologen ligand［J］. Dyes Pigm， 2020， 182： 108631.

[1]	Jin-Jian LIU, Na LIU, Feng-Yi YANG. Synthesis and Photochromic Properties of Two Isostructural Viologen Coordination Polymers [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 245-251.
[2]	LI Jiting, HU Bingcheng, YU Chuanming, LIU Cheng. Synthesis and Properties of Pyridyl Dithienylethene Axially Coordinated to Mn(Ⅱ)-Porphyrin [J]. Chinese Journal of Applied Chemistry, 2017, 34(4): 402-407.
[3]	XIE Fei,WEI Zhixian. Advances on Tetrazole-1-acetic Acid-Based Metal Coordination Polymers [J]. Chinese Journal of Applied Chemistry, 2017, 34(10): 1099-1109.
[4]	LI Yuanyuan, YANG Chun. Photochromism of Ionic Liquid-like Polyoxometalates Functionalized by Sulfonic Acid [J]. Chinese Journal of Applied Chemistry, 2015, 32(7): 808-815.
[5]	LI Yuanyuan, YANG Chun. Photochromism of Ionic Liquid-like Polyoxometalates Functionalized by Sulfonic Acid [J]. Chinese Journal of Applied Chemistry, 2015, 32(7): 0-0.
[6]	SUN Aibing, YU Chuanming, HU Bingcheng. Synthesis and Property of Symmetrical Bispyridylthienylethenes Photochromic Compound [J]. Chinese Journal of Applied Chemistry, 2015, 32(12): 1431-1436.
[7]	KU Zong-Jun*, ZHANG Zhong-Hai, XIAO Li-Yuan. Synthesis and thermal decomposition and photochromic kinetics of a charge-transfer salt (C3H5N2)3[PMo12O40] [J]. Chinese Journal of Applied Chemistry, 2010, 27(02): 173-177.
[8]	Wu Xinyan, Wu Chengtai. Synthesis and Properties of Indolinospirobenzopyrans Bearing Crown Moiety [J]. Chinese Journal of Applied Chemistry, 1998, 0(2): 106-108.
[9]	Fang Zheng, Zhang Hongjiang, Wang Shuzhi, Yang Zhifan, Fang Tianru, Xu Suxian, Wang Fusong. Synthesis and Properties of Dichromogenic Compounds Containing Both Phenoxynaphthacenequinone and Azobenzene Photochromes [J]. Chinese Journal of Applied Chemistry, 1997, 0(1): 1-5.
[10]	Fang Zheng, Yang Zhifan, Wang Shuzhi, Xu Suxian, Fang Tianru, Wang Fusong. Synthesis and Photochromism of Naphthyloxynaphthacenequinone [J]. Chinese Journal of Applied Chemistry, 1996, 0(1): 77-79.
[11]	Xiao Yufang, Liu Renhua, Yao Zhongqi. Synthesis and Photochromic Mechanism of Two Azobenzene Crown Ether Compounds [J]. Chinese Journal of Applied Chemistry, 1995, 0(5): 42-45.
[12]	Li Zhongjie, Tan Yongsheng, Dong Yigong. Synthesis of N,N'-1,4-Butylene Bis(Spiroindolinenaphthoxazine) [J]. Chinese Journal of Applied Chemistry, 1994, 0(2): 93-95.
[13]	Li Zhongjie, Tan Yongsheng, Ma Yinmin, Wang Xiaoxin. SYNTHESIS OF SOME SUBSTITUTED INDOLINOSPIRONAPHTHOXAZINES [J]. Chinese Journal of Applied Chemistry, 1992, 0(4): 83-86.
[14]	Zhu Sisan, Yue Bin, Wan Guojiang, Shi Xiaoqun, Gu Yidong. ON PHOTOCHROMISM OF DMF AND DMSO COORDINATED METAL DECATUNGSTATES IN NON-AQUEOUS SOLVENTS [J]. Chinese Journal of Applied Chemistry, 1992, 0(3): 41-45.
[15]	Wu Daocheng, Zhou Shiguang. A NOVEL THERMOCHROMIC COMPOUND TiO[VO(SO₄)₂(H₂O)₃]2H₂O [J]. Chinese Journal of Applied Chemistry, 1991, 0(2): 69-71.

Multiple-Responsive Coordination Polymers Based on a Carboxybenzyl Viologen Ligand

RichHTML

PDF

Supplement

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 4

References 22

Related Articles 15

Recommended Articles

Metrics

Comments