Research Progress in Photocatalytic Reduction of CO2 Enhanced by Oxygen Vacancy

doi:10.11944/j.issn.1000-0518.2020.03.190265

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (3): 256-263.DOI: 10.11944/j.issn.1000-0518.2020.03.190265

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Research Progress in Photocatalytic Reduction of CO₂ Enhanced by Oxygen Vacancy

GUO Hongxia(),CUI Jifang,LIU Li

Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials,College of Chemical Engineering,North China University of Science and Technology,Tangshan,Hebei 063210,China

Received:2019-10-10 Accepted:2019-12-25 Published:2020-03-01 Online:2020-03-10
Contact: GUO Hongxia
Supported by:
Supported by the National Natural Science Young Foundation of China(No.21908052)

Abstract

Abstract:

The photocatalytic reduction reactions can directly convert carbon dioxide (CO₂) into hydrocarbon solar fuels utilizing the endless solar energy and semiconductor photocatalysts, which can solve the greenhouse effect, global warming, environmental pollution, and energy crisis, therefore it has become the ideal way nowadays. The mechanism of photocatalytic reduction of CO₂ enhanced by oxygen vacancy and the photocatalytic systems with C1 and C2 components as reduction products were summarized in this paper. The first step in the CO₂ photoreduction (i.e. the formation of CO2·- anionic radical by capturing an electron from the conduction band of a photocatalyst) was considered to be the rate-limiting step. The introduction of oxygen vacancy and induced coordinately unsaturated metal atoms sites could strengthen the electron capture from CO₂ to CO2·-, thereby promoting the photocatalytic CO₂ reduction. The existential problems in the process of photocatalytic reduction of CO₂ enhanced by oxygen vacancy were explained objectively, and the development prospects were put forward.

Key words: photocatalysis, CO₂ reduction, oxygen vacancy, mechanism

GUO Hongxia, CUI Jifang, LIU Li. Research Progress in Photocatalytic Reduction of CO₂ Enhanced by Oxygen Vacancy[J]. Chinese Journal of Applied Chemistry, 2020, 37(3): 256-263.

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Research Progress in Photocatalytic Reduction of CO₂ Enhanced by Oxygen Vacancy

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