Advances in Black Phosphorus Anode Advantages and Optimization in Li-ion Battery Anodes

doi:10.19894/j.issn.1000-0518.220324

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (4): 571-582.DOI: 10.19894/j.issn.1000-0518.220324

• Energy Materials • Previous Articles Next Articles

Advances in Black Phosphorus Anode Advantages and Optimization in Li-ion Battery Anodes

Fang-Zheng HU¹, Xing GAO², Lei LIU¹, Tian-Heng YUAN¹, Ning CAO¹, Kai LI¹, Ya-Tao WANG³, Jian-Hua LI³, Hui-Qin LIAN¹(), Xiao-Dong WANG², Xiu-Guo CUI¹()

^1.Beijing Key Laboratory of Special Elastomers，Beijing Institute of Petrochemical Technology，Beijing 102617，China
^2.State Key Laboratory of Organic-Inorganic Composites，Beijing University of Chemical Technology，Beijing 100029，China
^3.Kailuan R&D Center of Coal Chemical Industry，Tangshan 064012，China

Received:2022-10-07 Accepted:2023-02-15 Published:2023-04-01 Online:2023-04-17
Contact: Hui-Qin LIAN,Xiu-Guo CUI
About author:cuixiuguo@bipt.edu.cn； lianhuiqin@bipt.edu.cn
Supported by:
the National Natural Science Foundation of China(51573021)

Abstract

Abstract:

In the context of the development of new energy sources to reduce carbon emissions and achieve carbon neutralization， power batteries represented by lithium-ion batteries are given higher expectations. The development of electrode materials with high capacity， high multiplicity and high stability is a key step to achieve this goal. Graphite cathodes and silicon carbon cathodes are relatively mature at present， and maintain their respective advantages. Black phosphorus has two-dimensional layered structure and high lithium potential， which shows outstanding advantages in realizing extremely fast charging， but there are also some problems such as volume expansion. In view of the problems of black phosphorus anode， researchers studied the optimization from various dimensions， including structure optimization， surface interface optimization and the pre-lithiation strategy. In this paper， the possibility that black phosphorus can be used as anode electrode of extremely fast charging lithium ion battery is demonstrated， the optimization progress of black phosphorus negative electrode is then reviewed， and its own views and suggestions are put forward. The challenges and development direction of black phosphorus anode electrode are pointed out， and the development prospect of black phosphorus anode electrode is prospected.

Key words: Black phosphorus, Lithium-ion battery, Anode material, Ultra-fast charging

CLC Number:

O646

Fang-Zheng HU, Xing GAO, Lei LIU, Tian-Heng YUAN, Ning CAO, Kai LI, Ya-Tao WANG, Jian-Hua LI, Hui-Qin LIAN, Xiao-Dong WANG, Xiu-Guo CUI. Advances in Black Phosphorus Anode Advantages and Optimization in Li-ion Battery Anodes[J]. Chinese Journal of Applied Chemistry, 2023, 40(4): 571-582.

Figures/Tables 9

References 98

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Active materials	First cycle reversible specific capacity/（mA·h·g^-1）	Initial coulomb efficiency/%	Ampere density/（A·g^-1）/number of cycles/capacity retention rate/%	Ref.
Graphite	224	99.8	4 C/200/98.2	［42］
PG-SPS	1 302	60.2	10/1 000/33.2	［67］
BP-G/PANI	1 650	76	13/2 000/26.7	［68］

Active materials	First cycle reversible specific capacity/（mA·h·g^-1）	Initial coulomb efficiency/%	Ampere density/（A·g^-1）/number of cycles/capacity retention rate/%	Ref.
Graphite	224	99.8	4 C/200/98.2	［42］
PG-SPS	1 302	60.2	10/1 000/33.2	［67］
BP-G/PANI	1 650	76	13/2 000/26.7	［68］

Active materials	Optimization policy	Initial coulomb efficiency/%	First cycle reversible specific capacity/（mA·h·g^-1）	Ampere density/（A·g^-1）\|number of cycles/capacity retention rate/%	Ref.
L-BP-S/Super P	BP Nano-crystallization	40.2	441.1	1.0/200/91.7	［69］
BPQDS/N-graphene	BPQDS	76.8	1 583	0.5/100/80.3	［70］
BP/G/CNTs	Conductive frame	73.4	1 375	2.0/3 000/40.0	［76］
BPC	Conductive frame	90.5	2 512.4	1.0 C/100/63.4	［77］
BP-GO-PANI	Conductive coating	38	884	5.0/2 000/108.4	［71］
P/CNT-10% LiF	Pre-lithiation	81	1 330	0.2/500/58.9	［95］

Active materials	Optimization policy	Initial coulomb efficiency/%	First cycle reversible specific capacity/（mA·h·g^-1）	Ampere density/（A·g^-1）\|number of cycles/capacity retention rate/%	Ref.
L-BP-S/Super P	BP Nano-crystallization	40.2	441.1	1.0/200/91.7	［69］
BPQDS/N-graphene	BPQDS	76.8	1 583	0.5/100/80.3	［70］
BP/G/CNTs	Conductive frame	73.4	1 375	2.0/3 000/40.0	［76］
BPC	Conductive frame	90.5	2 512.4	1.0 C/100/63.4	［77］
BP-GO-PANI	Conductive coating	38	884	5.0/2 000/108.4	［71］
P/CNT-10% LiF	Pre-lithiation	81	1 330	0.2/500/58.9	［95］

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Advances in Black Phosphorus Anode Advantages and Optimization in Li-ion Battery Anodes

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