应用化学 ›› 2020, Vol. 37 ›› Issue (11): 1221-1235.DOI: 10.11944/j.issn.1000-0518.2020.11.200208

• 综合评述 • 上一篇    下一篇

基于金属有机框架中空材料的研究进展

陈佳琪, 周焱, 孙敬文, 朱俊武, 汪信*, 付永胜*   

  1. 南京理工大学软化学与功能材料教育部重点实验室 南京 210094
  • 收稿日期:2020-07-10 修回日期:2020-08-05 接受日期:2020-08-24 出版日期:2020-11-01 发布日期:2020-11-04
  • 通讯作者: 付永胜,教授; Tel/Fax:025-84315054; E-mail:fuyongsheng@163.com; 研究方向:纳米功能材料在能量存储与转化中的应用
    共同通讯联系人:汪信,教授; Tel/Fax:025-84305667; E-mail:wangx@njust.edu.cn; 研究方向:功能材料的软化学法制备及其在能源、环境中的应用
  • 基金资助:
    国家自然科学基金(51772156和 51872144)和江苏省自然科学基金(BK20180019和BK20171423)项目资助

Recent Progress of Metal Organic Frameworks-Based Hollow Materials

CHEN Jiaqi, ZHOU Yan, SUN Jingwen, ZHU Junwu, WANG Xin*, FU Yongsheng*   

  1. Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology,Nanjing 210094,China
  • Received:2020-07-10 Revised:2020-08-05 Accepted:2020-08-24 Published:2020-11-01 Online:2020-11-04
  • Contact: FU Yongsheng, professor; Tel/Fax:025-84315054; E-mail:fuyongsheng@163.com; Research interests:synthesis of functional materials and the applications in energy storage and conversion
    Co-rresponding author:WANG Xin, professor; Tel/Fax:025-84305667; E-mail:wangx@njust.edu.cn; Research interests:preparation of functional materials via soft chemistry and their applications in energy and environment
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.51772156, No.51872144), the Natural Science Foundation of Jiangsu Province(No.BK20180019, No.BK20171423)

摘要: 金属有机框架(MOFs)中空材料因其大的比表面积、低密度、较高的负载能力和良好的离子渗透性,如氢氧化物、磷化物、硫化物等纳米材料,在能源储存与转换领域有良好的发展前景。 本文主要总结了基于不同形貌MOFs中空材料的制备途径和形成机理,着重介绍了其在超级电容器、锂离子电池和电催化等方面的应用,最后论述了基于MOFs中空材料的未来发展前景和挑战。

关键词: 金属有机框架, 中空, 制备, 超级电容器, 锂离子电池, 电催化

Abstract: Metal organic frameworks (MOFs) hollow materials, such as hydroxide, phosphide and sulfide, have attracted great attention in the applications of energy storage and conversion owing to their advantageous features of large specific area, low density, high loading capacity and excellent ion permeability. This review summarizes various synthetic strategies and formation mechanism for different structural MOFs-derived hollow materials. The promising electrochemical applications in the supercapacitors, lithium ion battery, and electrocatalysis are prominently elucidated. An outlook of development prospects and challenges for MOFs hollow structured derivatives is also discussed.

Key words: metal organic frameworks, hollow, synthesis, supercapacitor, lithium ion battery, electrocatalysis

中图分类号: