基于金属有机框架中空材料的研究进展

doi:10.11944/j.issn.1000-0518.2020.11.200208

摘要/Abstract

摘要： 金属有机框架(MOFs)中空材料因其大的比表面积、低密度、较高的负载能力和良好的离子渗透性,如氢氧化物、磷化物、硫化物等纳米材料,在能源储存与转换领域有良好的发展前景。本文主要总结了基于不同形貌MOFs中空材料的制备途径和形成机理,着重介绍了其在超级电容器、锂离子电池和电催化等方面的应用,最后论述了基于MOFs中空材料的未来发展前景和挑战。

关键词: 金属有机框架, 中空, 制备, 超级电容器, 锂离子电池, 电催化

Abstract: Metal organic frameworks (MOFs) hollow materials, such as hydroxide, phosphide and sulfide, have attracted great attention in the applications of energy storage and conversion owing to their advantageous features of large specific area, low density, high loading capacity and excellent ion permeability. This review summarizes various synthetic strategies and formation mechanism for different structural MOFs-derived hollow materials. The promising electrochemical applications in the supercapacitors, lithium ion battery, and electrocatalysis are prominently elucidated. An outlook of development prospects and challenges for MOFs hollow structured derivatives is also discussed.

Key words: metal organic frameworks, hollow, synthesis, supercapacitor, lithium ion battery, electrocatalysis

中图分类号:

O614

陈佳琪, 周焱, 孙敬文, 朱俊武, 汪信, 付永胜. 基于金属有机框架中空材料的研究进展[J]. 应用化学, 2020, 37(11): 1221-1235.

CHEN Jiaqi, ZHOU Yan, SUN Jingwen, ZHU Junwu, WANG Xin, FU Yongsheng. Recent Progress of Metal Organic Frameworks-Based Hollow Materials[J]. Chinese Journal of Applied Chemistry, 2020, 37(11): 1221-1235.

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