应用化学 ›› 1996, Vol. 0 ›› Issue (2): 101-103.

• 研究简报 • 上一篇    下一篇

铀酰的双席夫碱类配合物的合成与表征

范玉华, 毕彩丰   

  1. 山东建材学院应用化学系 济南 250022
  • 收稿日期:1995-08-18 修回日期:1995-11-20 出版日期:1996-04-10 发布日期:1996-04-10

Preparation and Characterization of Coordination Compounds of Uranyl with Bis-Schiff Bases

Fan Yuhua, Bi Caifeng   

  1. Department of Applied Chemistry. Shandong Institute of Building Materials, Jinan 250022
  • Received:1995-08-18 Revised:1995-11-20 Published:1996-04-10 Online:1996-04-10

摘要: 过渡金属及稀土金属离子的双席夫碱类配合物已有不少报道,但婀系元素铀酞的邻香草醛或水杨醛二胺类双席夫碱配合物未见报道.

关键词: 硝酸铀酰, 双席夫碱, 配合物

Abstract: Two new solid coordination compounds of uranyl with bis-Schiff base o-vanillin-o-phenylenediamine (H2L1) or salicylidene o-phenylenediamine (H2L2) have been prepared and characterized by elemental analysis, DTA-TG,IR, UV, molar conductance and X-ray diffraction analyses. The compositions of the coordination compounds UO2L1H2O and UO2L2C2H5OH were confirmed and their possible structures were conjectured.

Key words: uranyl nitrate, bis-Schiff base, coordination compound