应用化学 ›› 1996, Vol. 0 ›› Issue (5): 44-47.

• 研究论文 • 上一篇    下一篇

氧化锶催化性质 Ⅱ.SrO,MgO上异丙醇的分解反应

费金华, 郑小明, 周烈华, 吴念慈   

  1. 杭州大学催化研究所 杭州 310028
  • 收稿日期:1995-11-02 修回日期:1996-05-05 出版日期:1996-10-10 发布日期:1996-10-10
  • 基金资助:
    浙江省自然科学基金;浙江省教委基金

The Catalytic Character of SrO Ⅱ.Study of the Decomposition of Isopropanol over MgO and SrO Catalysts

Fei Jinhua, Zheng Xiaoming, Zhou Liehua, Wu Nianci   

  1. Institute of Catalysis, Hangzhou University, Hangzhou 310028
  • Received:1995-11-02 Revised:1996-05-05 Published:1996-10-10 Online:1996-10-10

摘要: SrO,MsO对异丙醇的分解反应有各自的作用形式,因而产物分布也有明显差别。MgO上异丙醇分解,在较低温度时,主要产物为丙酮和丙烯;随温度升高,生成丙烯的量增加,而丙酮的量减少,直至消失,在SrO上,异丙醇在较高温度时反应,产物几乎为丙酮,丙烯的生成量极少。认为:产物中丙烯来源于异丙醇在催化剂表面强酸中心上的脱水;丙酮在MgO上来源于强碱中心和酸中心协同作用异丙醇的脱氢,而在SrO上则是SrO表面极强的碱中心作用异丙醇而脱氢制得。

关键词: 氧化锶, 氧化镁, 催化剂, 异丙醇, 分解

Abstract: In this paper the surface properties of MgO and SrO were investigated by means of temperature-programmed desorption. The results show that there are two types of both basic sites and acidic sites on MgO catalyst, while only one type strong basic sites on SrO catalyst. These basic sites, acidic sites and their synergistic action have different effect on the decomposition of isopropanol. On MgO, propene results from the elimination of water from isopropanol over strong acidic sites and acetone comes from the dehydrogenation of isopropanol over strong basic sites in cooperation with acidic sites. On SrO, acetone is the sole product resulted from the dehydrogenation of isopropanol under the action of very strong basic sites.

Key words: strontium oxide, magnesia, catalyst, isopropanol, decomposition