应用化学 ›› 1995, Vol. 0 ›› Issue (6): 71-73.

• 研究论文 • 上一篇    下一篇

2,4-二硝基和二氰基高立方烷的合成

管晓培, 杜建卫, 孙建光, 于永忠   

  1. 北京理工大学化学工程与材料学院, 北京 100081
  • 收稿日期:1995-02-06 修回日期:1995-08-24 出版日期:1995-12-10 发布日期:1995-12-10

Synthesis of 2,4-Dinitro-and Dicyano-Homocubanes

Guan Xiaopei, Du Jianwei, Sun Jianguang, Yu Yongzhong   

  1. College of Chemical Engineering and Materials Science, Beijing Institute of Technology, Beijing 100081
  • Received:1995-02-06 Revised:1995-08-24 Published:1995-12-10 Online:1995-12-10

摘要: 近年来,作为新型的高能量密度材料,含能多面体烷衍生物的合成引起人们极大兴趣.高立方烷的张力能计算值为523kJ/mol,比立方烷稍低;但热稳定性比立方烷好,240℃以下基本不分解.

关键词: 高立方烷, 硝基, 氰基, 氧化

Abstract: Dinitro-and dicvano-homocubanes were synthesized from homocubane-2,4-di-carboxylic acid.DSC analysis of their thermal decomposition is also presented.

Key words: homocubane, nitro, cyano, oxidation