中华医学超声杂志

应用化学 ›› 1994, Vol. 0 ›› Issue (5): 45-48.

• 研究论文 • 上一篇    下一篇

甲酰基甲酸氨基硫脲席夫碱二价金属离子配合物的研究

田君濂, 毕思玮, 高恩庆, 李延团, 李桂芝, 刘树祥   

  1. 曲阜师范大学化学系 曲阜 273165
  • 收稿日期:1994-01-12 修回日期:1994-04-07 出版日期:1994-10-10 发布日期:1994-10-10
  • 基金资助:
    山东省自然科学基金资助项目

Study on Biologically Active Schiff Base Complexes of Formylformic Acid with Thiosemicarbazide

Tian Junlian, Bi Siwei, Gao Enqing, Li Yantuan, Li Guizhi, Liu Shuxiang   

  1. Department of Chemistry, Qufu Normal University, Qufu 273165
  • Received:1994-01-12 Revised:1994-04-07 Published:1994-10-10 Online:1994-10-10

PDF

358

被引次数

97 | 12

摘要： 合成了甲酰基甲酸氨基硫脲席夫碱(H2FFTSC)的配合物。元素分析和摩尔电导等确定其组成为M(HFFTSC)2·nH2O(M=Co(Ⅱ),Ni(Ⅱ),n=2;M=Zn(Ⅱ),n=1;M=Mn(Ⅱ),Pb(Ⅱ),n=0)和Cu(FFTSC)·H2O,红外吸收光谱等研究表明配体通过羧酸棍氧原子、甲亚胺氮原子和硫酮基(或硫醇基)的硫原子和金属离子配位。测试了配合物的杀菌活性。

关键词: 甲酰基甲酸氨基硫脲席夫碱, 过渡元素, 配合物, 抗菌活性

Abstract: Some bivalent metal ion complexes of Schiff bases derived from formylformic acid and thiosemicarbazide were synthesized.The composition of the complexes were determined as M(HFFTSC)2·nH2O(M=Co(Ⅱ),Ni(Ⅱ),n=2;M=Zn(Ⅱ),n=1;M=Mn(⒓),Pb(1),n=0) and Cu(FFTSC)·H2O based on the elemental analysis data and molar conductance measurements.The IR results showed that the ligand behaves as in a tridentate manner.The antibacterial activity of the complexes were examined.

Key words: formylformic acid thiosemicarbazide Schiff base, transition element, complex, antibacterial activity

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