应用化学 ›› 1989, Vol. 0 ›› Issue (6): 58-60.

• 研究简报 • 上一篇    下一篇

四(烷硫基苯基)卟啉及其金属配合物的合成

王先元, 张健, 李广年   

  1. 中国科学院成都有机化学研究所
  • 收稿日期:1988-10-28 修回日期:1989-07-04 出版日期:1989-12-10 发布日期:1989-12-10
  • 基金资助:
    国家自然科学基金

SYNTHESES OF ms-TETRA(ALKYLTHIOPHENYL)PORPHYRINS AND THEIR METAL COMPLEXES

Wang Xianyuan, Zhang Jian, Li Guangnian   

  1. Chengdu Institute of Organic Chemistry, Academia Sinica
  • Received:1988-10-28 Revised:1989-07-04 Published:1989-12-10 Online:1989-12-10

摘要: 某些人工合成的金属卟啉,由于其活化分子氧的功能,被广泛用作生物模拟氧化反应中的催化剂[1,2]。金属四苯基卟啉及其衍生物是用得最普遍的模型化合物。文献中巳报道过各种四苯基卟啉衍生物的合成方法[3-5],但尚未见带烷硫基的四苯基卟啉衍生物的系统合成方法。本文报道这类四苯基卟啉衍生物及其金属配合物的合成。

关键词: 四(烷硫基苯基)卟啉, 金属卟啉, 配合物, 合成

Abstract: ms-Tetra (p-alkylthiophenyl) porphyrins and ms-tetra (o-alkylthiophenyl) porphyrins(alkyl=methyl, ethyl, propyl) were synthesized by refluxing the mixture of pyrrole,and para or ortho (alkylthio) benzaldehydes in propionic acid or in acetic acid. Some metal complexes of these porphyrins were prepated by refluxing the mixture of the porphyrin and the corresponding metal salt in acetic acid or in DMF. All the porphyrins described were identified by visible spectrophotometry, nuclear magnetic resonance spectroscopy and elemental analysis.

Key words: ms-Tetra(alkylthiophenyl)porphyrin, Metalloporphyrin, Complex Synthesis