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锂离子电池硼酸盐电极材料的研究进展

唐安平1,2*,刘立华1,2,徐国荣1,2,申洁1,令玉林1,2   

  1. (1.湖南科技大学化学化工学院 湘潭 411201；2.理论化学与分子模拟省部共建教育部重点实验室 湘潭 411201)
  • 收稿日期:2012-04-06 修回日期:2012-06-09 出版日期:2012-11-10 发布日期:2012-11-10
  • 通讯作者: 唐安平，副教授; Tel:0731-58290683; Fax:0731-58290187; E-mail:anpingxt@126.com; 研究方向：新型化学电源及其电极材料
  • 基金资助:
    湖南省自然科学基金(12JJ2022)湖南省教育厅(11C0525)资助项目

Progress in Borate Electrode Materials for Lithium Ion Batteries

TANG Anping1,2*, LIU Lihua1,2, XU Guorong1,2, SHEN Jie1, LING Yulin1,2   

  1. (1.School of Chemistry and Chemical Engineering,Hunan University of Science and Technology,Xiangtan 411201,China;
    2.Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education,Xiangtan 411201,China)
  • Received:2012-04-06 Revised:2012-06-09 Published:2012-11-10 Online:2012-11-10

PDF

2386

被引次数

4

摘要： 硼酸盐作为新一代锂离子电池电极材料，其具有摩尔质量小、资源丰富、环境友好和理论比容量高等优点。 本文对LiFeBO3、LiMnBO3和LiCoBO3等硼酸盐正极材料以及Fe3BO6、FeBO3、Cr3BO6、Co2B2O5、Cu3B2O6和VBO3等硼酸盐负极材料的结构、制备方法、电化学性能的研究现状进行了综述，并对存在的主要问题提出了改进方法。

关键词: 锂离子电池, 硼酸盐, 正极材料, 负极材料

Abstract: Borate electrode materials for lithium ion batteries offer several appealing features, such as relatively light molar mass, abundant resources, environmental friendliness and relatively high theoretical specific capacities. In this article, we briefly reviewed the state-of-the art of borate cathode materials and borate anode materials, including LiFeBO3, LiMnBO3, LiCoBO3, Fe3BO6, FeBO3, Cr3BO6, Co2B2O5, Cu3B2O6 and VBO3. The recent research progress on their structures, preparation methods and electrochemical performances are presented. In addition, we proposed some possible solutions for the existed problems within these materials.

Key words: lithium ion batteries, borates, cathode materials, anode materials

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