Research Progress on Chemical Resourse Utilization of Sulfur Dioxide

doi:10.19894/j.issn.1000-0518.210078

Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (02): 223-234.DOI: 10.19894/j.issn.1000-0518.210078

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Research Progress on Chemical Resourse Utilization of Sulfur Dioxide

Ying CHEN¹, Tian-Ding HU¹, Yun-Li LIU¹, Pu ZHANG², Yun-Fei ZHI¹(), Shao-Yun SHAN¹()

^1.Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China
^2.Faculty of Environment Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

Received:2021-02-22 Accepted:2021-06-17 Published:2022-02-10 Online:2022-02-09
Contact: Yun-Fei ZHI,Shao-Yun SHAN
Supported by:
National Natural Science Foundation of China(21766016);Yunnan Ten Thousand Talents Plan Young& Elite Talents Project(YNWR-QNBJ-2018-198);Yunnan Youth Program of Basic Research Project(202001AU070023);Kunming Science and Technology Program of the Science and Technology Council Project(2019-1-G-25318000003480);Academician Workstation(2019IC002)

Abstract

Abstract:

Excessive emission of sulfur dioxide (SO₂) poses a serious threat to the natural environment, making the capture and utilization of SO₂widely concerned in industrial production. Currently, technologies of capturing SO₂have been relatively mature, and the value-added utilization of the captured SO₂has become a hot-point issue. Among various SO₂utilization technologies, chemical utilization is considered to be one of the most promising methods for realizing value-addition of SO₂because of the advantages of excellent atomic economy and low energy consumption. In this paper, the oxidation and reduction of SO₂and organic synthesis using SO₂in inorganic and organic reactions are reviewed. The reaction mechanism and reaction conditions of conversion of SO₂, and the influence of different catalysts on the reactions are introduced. The challenges of severe reaction conditions and high dependence on catalysts in chemical utilization of SO₂are pointed out. The further research directions of chemical utilization of SO₂are prospected.

Key words: Sulfur dioxide, Chemical utilization, Reduction, Oxidation, Catalysis, Addition, Polymerization

CLC Number:

O613
O627

Ying CHEN, Tian-Ding HU, Yun-Li LIU, Pu ZHANG, Yun-Fei ZHI, Shao-Yun SHAN. Research Progress on Chemical Resourse Utilization of Sulfur Dioxide[J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 223-234.

Figures/Tables 10

Fig.1 Scheme of SO2chemical resource utilization

Fig.2 Mechanism of reduction of SO2by CO［17］

Fig.3 SO2reduction catalyzed by a series of three-component cobalt-based catalysts［25］

Fig.4 Conversion of SO2to SO3on V2O5WO3／TiO2catalyst［38］

Fig.5 Mechanism for removing SO2using copper tailing［41］

Fig.6 Synthesis of sulfite 2a by SO2capture and fixation method［51］

Fig.7 Possible mechanism of the three-component reaction of aryl boric acid，SO2and hydrazine catalyzed by palladium［61］

Fig.8 Synthesis mechanism of dialkyl sulfone from SO2under photocatalysis［68］

Fig.9 Mechanism of SO2and cyclohexene oxide copolymerization catalyzed by cellulose Cr（Salen）type catalyst［77］

Fig.10 Scheme of reaction between SO2and regenerated eugenol［44］

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Research Progress on Chemical Resourse Utilization of Sulfur Dioxide

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