Synthesis, Characterization, Photothermal Properties of Dichalcone Containing Polymethoxy Aromatic Group

doi:10.19894/j.issn.1000-0518.210048

Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (02): 235-240.DOI: 10.19894/j.issn.1000-0518.210048

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Synthesis, Characterization, Photothermal Properties of Dichalcone Containing Polymethoxy Aromatic Group

Yu-Fang SHI(), Ying-Jin WANG, Jin-Yu SUN, Ming-Gen ZHAO

Key Laboratory of Materials and Computational Chemistry, Department of Chemistry, Xinzhou Teachers University, Xinzhou 034000, China

Received:2021-01-28 Accepted:2021-05-31 Published:2022-02-10 Online:2022-02-09
Contact: Yu-Fang SHI
Supported by:
Fund for Shanxi "1331 Project" Key Subjects Construction(2018122)

1. .pdf(158KB)

Abstract

Abstract:

A novel dichalcone derivative, 1, 4-bis [3- (3, 4, 5-trimethoxyphenyl) -2-acryloyl] benzene (BTAB), was synthesized and characterized by nuclear magnetic resonance (NMR) spectroscopy and liquid chromatography-mass spectrometer (LC-MS). The thermogravimetry (TG) /differential scanning thermogravimetry (DSC) analysis shows that the melting point of the compound is 230.6℃ and the thermal stability is good. The maximal wavelengths of ultravioletabsorption and fluorescence emissions are determined as λ_max/UV=357.5 nm, λ_max/EM=541 nm, respectively. The energies of the highest occupied and lowest orbital of molecules and polarizability of BTAB were obtained using the density functional theory method. The phenomenon of intramolecular charge transfer was also found from the molecular orbitals. The optical nonlinearities of the BTAB was confirmed by the single beam Z-scan technique. The third-order nonlinear absorption coefficient β and the fifth order nonlinear absorption coefficient γ are 3.15×10^-14m/W and 2.7×10^-28m³/W², respectively, which belongs to double photon absorption. All these results demonstrate that the chalcone ketones BTAB is promising for non-linear optical applications.

Key words: Dichalcone derivative, Theoretical calculation, Photothermal properties

CLC Number:

O625.4

Yu-Fang SHI, Ying-Jin WANG, Jin-Yu SUN, Ming-Gen ZHAO. Synthesis, Characterization, Photothermal Properties of Dichalcone Containing Polymethoxy Aromatic Group[J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 235-240.

Figures/Tables 6

Scheme 1　Synthetic route of BTAB

Fig.1 DSC／TG curves of BTAB

Fig.2 UV-Vis absorption spectrum of BTAB

Fig.3 Fluorescence emission spectrum of BTAB

Fig.4 Geometry and molecular orbitals of BTAB

Fig.5 Open-aperture Z-scan curve of BTAB

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Synthesis, Characterization, Photothermal Properties of Dichalcone Containing Polymethoxy Aromatic Group

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