Synthesis of a Novel Rhodamine-Based Probe and Its Selective Detection of Trivalent Metallic Ions

doi:10.11944/j.issn.1000-0518.2017.05.160475

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (5): 606-610.DOI: 10.11944/j.issn.1000-0518.2017.05.160475

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Synthesis of a Novel Rhodamine-Based Probe and Its Selective Detection of Trivalent Metallic Ions

HOU Shuhua,QU Zhongguo,ZHONG Keli,BIAN Yanjiang,TANG Lijun()

Department of Chemistry and Chemical Engineering,Bohai University,Jinzhou,Liaoning 121013,China

Received:2016-11-25 Accepted:2017-02-23 Published:2017-05-02 Online:2017-05-02
Contact: TANG Lijun
Supported by:
Supported by the National Natural Science Foundation of China(No.21476029, No.U1608222), Program for Liaoning Excellent Talents in University(No.LR2015001)

Abstract

Abstract:

Trivalent metallic ions(Cr³⁺, Fe³⁺ and Al³⁺) play important roles in environment and human health. It is exhausting using different sensor in different conditions for detection of all the trivalent metallic ions. Single probes for detecting all of these trivalent metallic cations simultaneously with high sensitivity and selectivity have attracted great attention. A novel rhodamine-based probe P was synthesized from rhodamine B. It is showed that probe P acts as a “turn on” fluorescent probe for trivalent metallic ions(Fe³⁺, Cr³⁺ and Al³⁺) recognition. Probe P is highly selective to trivalent metallic ions over other monovalent or divalent metallic ions in V(CH₃OH)：V(Tris-HCl)=9：1. Furthermore, probe P is highly sensitive to trivalent metallic ions. The detection limits of probe P for Cr³⁺, Al³⁺ and Fe³⁺ are 3.0×10^-4, 2.7×10^-4 and 1.0×10^-4 mol/L, respectively. Probe P could be used in the detection of Cr³⁺, Al³⁺ and Fe³⁺.

Key words: rhodamine, probe, trivalent ions

HOU Shuhua, QU Zhongguo, ZHONG Keli, BIAN Yanjiang, TANG Lijun. Synthesis of a Novel Rhodamine-Based Probe and Its Selective Detection of Trivalent Metallic Ions[J]. Chinese Journal of Applied Chemistry, 2017, 34(5): 606-610.

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Synthesis of a Novel Rhodamine-Based Probe and Its Selective Detection of Trivalent Metallic Ions

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