Research Progress of Biomass-Based Hard Carbon Anodes for Sodium-Ion Storage

doi:10.19894/j.issn.1000-0518.230364

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (4): 496-511.DOI: 10.19894/j.issn.1000-0518.230364

• Review • Previous Articles

Research Progress of Biomass-Based Hard Carbon Anodes for Sodium-Ion Storage

Rui-Yao WU¹^,², Dan-Dan OUYANG², Li-Li AI¹, An-Jie LIU¹, Hui ZHU², Xiao-Xin GAO³(), Jiao YIN²()

^1.College of Chemistry，Xinjiang University，Urumqi 830046，China
^2.Xinjiang Technical Institute of Physics & Chemistry，Chinese Academy of Sciences，Urumqi 830011，China
^3.Science & Technology Department of Xinjiang Uygur Autonomous Region，Urumqi 830011，China

Received:2023-11-20 Accepted:2024-02-17 Published:2024-04-01 Online:2024-04-28
Contact: Xiao-Xin GAO,Jiao YIN
About author:yinjiao@ms.xjb.ac.cn
13619967665@163.com；
Supported by:
the Key Research and Development Project of Xinjiang Uygur Autonomous Region（Nos.?2022B01023, 2022B02013, 2022LQ01005）, the “Western Light” Foundation of Chinese Academy of Sciences（No.?2019-XBQNXZ-A-002）, the Youth Innovation Promotion Association, Chinese Academy of Sciences（No.?2019427）, the National Natural Science Foundation of China Youth Foundation Program（No.?22205193）, the National Key Research and Development Project(2023YFB4203703);the Special Funds for the Central Government to Guide Local Scientific and Technological Development(ZYYD2023A06);the Silk Road Economic Belt Innovation-driven Development Pilot Zone, Wuchangshi National Independent Innovation Demonstration Zone Science and Technology Development Plan of China(2023LQ04002)

Abstract

Abstract:

Biomass-derived hard carbon has advantages of abundant raw-material resources， sustainability， low cost， and high sodium storage capacity， making it an ideal anode material for sodium-ion batteries （SIBs）. The microstructure of biomass-derived hard carbon materials is one of the key factors to influence the sodium-ion storage performance. This review summarizes the research status on the mechanism of biomass-derived hard carbon anodes for sodium-ion storage. Preparation methods for the high-performance biomass-derived hard carbon anodes were summarized from the point of views of biomass sources. The relationship between structural regulation and the sodium-ion storage enhancement was discussed. Last but not the least， future research directions were prospected for developing high-performance biomass-derived hard carbon anodes for SIBs.

Key words: Hard carbon, Biomass, Sodium-ion battery, Anode material

CLC Number:

O646

Rui-Yao WU, Dan-Dan OUYANG, Li-Li AI, An-Jie LIU, Hui ZHU, Xiao-Xin GAO, Jiao YIN. Research Progress of Biomass-Based Hard Carbon Anodes for Sodium-Ion Storage[J]. Chinese Journal of Applied Chemistry, 2024, 41(4): 496-511.

Figures/Tables 9

References 87

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Precursor	Synthetic method	Carbonization temperature/℃	Capacity/（mA·h·g^-1）	ICE/%	Rate capability	Cycle number	Cyclability/（mA·h·g^-1）	Ref.
Platanus flosses	One-step carbonization	1 300	324.6（0.02 A/g）	80	244/0.2 A/g	100	258（79.6%）	［34］
Cherry petals	One-step carbonization	1 000	310.1（0.02 A/g）	67.3	25/1 A/g	500	131.5（89.8%）	［35］
Oak leaves	One-step carbonization	1 000	360（0.02 A/g）	74.8	270/0.04 A/g	200	243（90%）	［41］
Bamboo	Acid pre-treatment and two-step carbonization	1 300	348.5（0.03 A/g）	84.1	333/0.05 A/g	500	300（91.6%）	［43］
Walnut shell	One-step carbonization	1 000	257（0.05 A/g）	71	48/2 A/g	300	170（70.8%）	［44］
Rice husk	Acid pre-treatment	1 300	372（0.025 A/g）	66	265/0.5 A/g	100	346（93%）	［45］
Pomelo peels	H₃PO₄ activation and one-step carbonization	700	314.5（0.05 A/g）	27	71/5 A/g	220	181（99.3%）	［46］
Navel orange peel	Hydrothermal treatment and one-step carbonization	1 300	337（0.1 A/g）	63	328/0.1 A/g	500	234（98.7%）	［47］
Hazelnut shells	Simple water washing	1 100	275（0.02 A/g）	79.4	233/0.03 A/g	250	244（88.83%）	［51］
Wine corks	Acid pre-treatment and two-step carbonization	1 600	358（0.03 A/g）	81	——	200	312（87%）	［55］
Lotus stems	One-step carbonization	1 400	351（0.1 A/g）	70	150/0.5 A/g	450	330（94.2%）	［64］
Kapok fibers	Hydrothermal treatment and activation	1 600	299.7（0.1 A/g）	90	358/0.5 A/g	100	267.9（89.4%）	［72］
Chitin powder	Acid pre-treatment and synthetic method	600	360（0.05 A/g）	47	320/0.05 A/g	10 000	——	［82］
Durian shell	KOH activation and	600	247.9（0.05 A/g）	56.02	345/1 A/g	200	——	［84］
Microcrystallinecellulos	Ice-assisted ball milling method	1000	122.3（1 A/g）	39.5	——	2 000	80（65.4%）	［86］
Tissue	Two-step carbonization	1 300	338（0.02 A/g）	91.2	170/2 A/g	1 000	286.5（93%）	［87］

Precursor	Synthetic method	Carbonization temperature/℃	Capacity/（mA·h·g^-1）	ICE/%	Rate capability	Cycle number	Cyclability/（mA·h·g^-1）	Ref.
Platanus flosses	One-step carbonization	1 300	324.6（0.02 A/g）	80	244/0.2 A/g	100	258（79.6%）	［34］
Cherry petals	One-step carbonization	1 000	310.1（0.02 A/g）	67.3	25/1 A/g	500	131.5（89.8%）	［35］
Oak leaves	One-step carbonization	1 000	360（0.02 A/g）	74.8	270/0.04 A/g	200	243（90%）	［41］
Bamboo	Acid pre-treatment and two-step carbonization	1 300	348.5（0.03 A/g）	84.1	333/0.05 A/g	500	300（91.6%）	［43］
Walnut shell	One-step carbonization	1 000	257（0.05 A/g）	71	48/2 A/g	300	170（70.8%）	［44］
Rice husk	Acid pre-treatment	1 300	372（0.025 A/g）	66	265/0.5 A/g	100	346（93%）	［45］
Pomelo peels	H₃PO₄ activation and one-step carbonization	700	314.5（0.05 A/g）	27	71/5 A/g	220	181（99.3%）	［46］
Navel orange peel	Hydrothermal treatment and one-step carbonization	1 300	337（0.1 A/g）	63	328/0.1 A/g	500	234（98.7%）	［47］
Hazelnut shells	Simple water washing	1 100	275（0.02 A/g）	79.4	233/0.03 A/g	250	244（88.83%）	［51］
Wine corks	Acid pre-treatment and two-step carbonization	1 600	358（0.03 A/g）	81	——	200	312（87%）	［55］
Lotus stems	One-step carbonization	1 400	351（0.1 A/g）	70	150/0.5 A/g	450	330（94.2%）	［64］
Kapok fibers	Hydrothermal treatment and activation	1 600	299.7（0.1 A/g）	90	358/0.5 A/g	100	267.9（89.4%）	［72］
Chitin powder	Acid pre-treatment and synthetic method	600	360（0.05 A/g）	47	320/0.05 A/g	10 000	——	［82］
Durian shell	KOH activation and	600	247.9（0.05 A/g）	56.02	345/1 A/g	200	——	［84］
Microcrystallinecellulos	Ice-assisted ball milling method	1000	122.3（1 A/g）	39.5	——	2 000	80（65.4%）	［86］
Tissue	Two-step carbonization	1 300	338（0.02 A/g）	91.2	170/2 A/g	1 000	286.5（93%）	［87］

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Research Progress of Biomass-Based Hard Carbon Anodes for Sodium-Ion Storage

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