Adsorption Performance of Rhodamine B on Magnetic Biochar Prepared at Different Pyrolysis Temperatures

doi:10.19894/j.issn.1000-0518.220169

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (2): 288-298.DOI: 10.19894/j.issn.1000-0518.220169

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Adsorption Performance of Rhodamine B on Magnetic Biochar Prepared at Different Pyrolysis Temperatures

Qian YANG, Yang ZHANG, Ming-Yang LAI, Lin GUO, Jian-Bo JIA()

School of Biotechnology and Health Sciences，Wuyi University，Jiangmen 529000，China

Received:2022-05-06 Accepted:2022-11-06 Published:2023-02-01 Online:2023-02-27
Contact: Jian-Bo JIA
About author:jbjiagu@163.com
Supported by:
the National Natural Science Foundation of China(21974097);the Education Department of Guangdong Province(2020KSYS004)

Abstract

Abstract:

Using rice straw as the raw material， an one-step magnetization carbonization method is used for oxygen-limited pyrolysis at 550， 600， 650 and 700 ℃ to prepare high-efficient and easy-separable magnetic biochar （MBC）. The physicochemical properties of MBC are characterized using X-ray diffraction （XRD）， scanning electron microscopy （SEM）， Emmett and Teller analysis （BET） and Fourier transform infrared spectrometer （FT-IR）， and the effects of different temperatures on their structural properties and adsorption performances are investigated. The effects of metal cations （Na⁺， Fe³⁺， Mg²⁺， Cu²⁺） and pH on the adsorption performance are also investigated. The results show that the specific surface area and pore volume of MBC increase with the increase of pyrolysis temperature， and the adsorption ability or capacity of MBC is significantly affected by temperature. The equilibrium adsorption capacities of the four different pyrolysis temperatures are 35.696， 36.962， 53.118 and 54.810 mg/g for Rhodamine B（RhB）， respectively. The adsorption of RhB by the four kinds of MBC was in accordance with the pseudo second order kinetic equation， indicating that the adsorption of RhB by MBC was affected by many factors. Langmuir and Freundlich equations were used to fit the isotherm adsorption results， and the adsorption isotherms were in line with Freundlich model， indicating that the adsorption of RhB by MBC was dominated by the physical adsorption of multi molecular layers. The adsorption capacity of MBC on RhB increases and then decreases with the increase of pH due to electrostatic adsorption and ion exchange， and reaches the maximum capacity at pH 6. After the addition of Na⁺， Fe³⁺， Cu²⁺， Mg²⁺ metal cations， the adsorption capacities of the four kinds of MBC for RhB are all lower than the equilibrium adsorption capacities. The increase of Na⁺ and Fe³⁺ ion concentrations has a certain upward trend on the adsorption capacity of some MBC for RhB. However， the increase of Cu²⁺ and Mg²⁺ ion concentrations has little effect on the adsorption of RhB by MBC.

Key words: Rice straw, Pyrolysis temperature, Magnetic biochar, Rhodamine B, Metal cation

CLC Number:

O647.3

Qian YANG, Yang ZHANG, Ming-Yang LAI, Lin GUO, Jian-Bo JIA. Adsorption Performance of Rhodamine B on Magnetic Biochar Prepared at Different Pyrolysis Temperatures[J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 288-298.

Figures/Tables 12

References 35

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Pyrolysis temperature/℃	BET surface area/（m²·g^-1）	Total pore volume/（cm3·g^-1）	Micropore volume/（cm3·g^-1）	Micropore area/（m²·g^-1）
550	314.779	0.123	0.121	260.450
600	331.710	0.137	0.119	257.683
650	418.436	0.172	0.151	327.129
700	427.418	0.211	0.120	261.633

Pyrolysis temperature/℃	BET surface area/（m²·g^-1）	Total pore volume/（cm3·g^-1）	Micropore volume/（cm3·g^-1）	Micropore area/（m²·g^-1）
550	314.779	0.123	0.121	260.450
600	331.710	0.137	0.119	257.683
650	418.436	0.172	0.151	327.129
700	427.418	0.211	0.120	261.633

MBC	q_e（exp）/（mg·g^-1）	Pseudo first-order kinetic model			Pseudo second-order kinetic model
MBC	q_e（exp）/（mg·g^-1）	q_e（cal）/（mg·g^-1）	K₁/min^-1	R²	q_e（cal）/（mg·g^-1）	K₂/min^-1	R²
MBC-550	35.696	34.604	2.096	0.978	34.967	0.167	0.990
MBC-600	36.962	36.455	1.955	0.981	36.838	0.146	0.993
MBC-650	53.118	51.039	1.110	0.967	51.971	0.042	0.990
MBC-700	54.810	52.827	0.972	0.984	53.755	0.036	0.995

MBC	q_e（exp）/（mg·g^-1）	Pseudo first-order kinetic model			Pseudo second-order kinetic model
MBC	q_e（exp）/（mg·g^-1）	q_e（cal）/（mg·g^-1）	K₁/min^-1	R²	q_e（cal）/（mg·g^-1）	K₂/min^-1	R²
MBC-550	35.696	34.604	2.096	0.978	34.967	0.167	0.990
MBC-600	36.962	36.455	1.955	0.981	36.838	0.146	0.993
MBC-650	53.118	51.039	1.110	0.967	51.971	0.042	0.990
MBC-700	54.810	52.827	0.972	0.984	53.755	0.036	0.995

MBC	T/℃	Freundlich isotherm model			Langmuir isotherm model
MBC	T/℃	K_F	N	R²	q_max/（mg·g^-1）	K_L	R²
MBC-550	20	2.224	2.496	0.999	20.594	0.026	0.962
	30	2.272	1.995	0.993	36.558	0.015	0.973
	40	2.962	3.322	0.979	14.637	0.052	0.954
MBC-600	20	2.704	2.645	0.995	21.566	0.030	0.935
	30	3.684	2.402	0.993	40.203	0.026	0.976
	40	2.956	3.067	0.981	16.961	0.043	0.871
MBC-650	20	11.283	3.313	0.990	49.978	0.090	0.929
	30	13.760	3.547	0.991	54.975	0.116	0.899
	40	14.795	3.906	0.971	49.343	0.180	0.935
MBC-700	20	12.554	3.318	0.991	53.779	0.102	0.893
	30	16.993	3.496	0.990	68.877	0.108	0.937
	40	15.660	3.509	0.980	59.61	0.146	0.940

Adsorption Performance of Rhodamine B on Magnetic Biochar Prepared at Different Pyrolysis Temperatures

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Figures/Tables 12

References 35

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MBC	ΔG/（kJ·mol^-1）			ΔH/（kJ·mol^-1）	ΔS/（kJ·mol^-1）
MBC	20 ℃	30 ℃	40 ℃	ΔH/（kJ·mol^-1）	ΔS/（kJ·mol^-1）
MBC-550	-3.807	-4.175	-5.950	-38.345	24.545
MBC-600	-4.793	-5.492	-5.737	-59.762	43.872
MBC-650	-8.821	-9.794	-10.557	-23.631	4.717
MBC-700	-9.085	-10.289	-10.426	-12.266	6.742

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