Adsorption Properties of Carboxymethyl-β-cyclodextrin Functionalized Ferroferric Oxide Magnetic Nanocomposites on Rhodamine B

doi:10.11944/j.issn.1000-0518.2015.01.140147

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (1): 110-117.DOI: 10.11944/j.issn.1000-0518.2015.01.140147

• Full Papers • Previous Articles Next Articles

Adsorption Properties of Carboxymethyl-β-cyclodextrin Functionalized Ferroferric Oxide Magnetic Nanocomposites on Rhodamine B

SUN Linlin, ZHOU Yehong, WANG Fei, SHUANG Shaomin, DONG Chuan^*

Institute of Environmental Science, College of Environmental and Resource Sciences,Shanxi University,Taiyuan 030006,China

Received:2014-04-25 Revised:2014-06-24 Published:2015-01-06 Online:2015-01-06
Contact: Corresponding author:DONG Chuan, professor; Tel:0351-7010958; Fax:0351-7018613; E-mail:dc@sxu.edu.cn; Research interests:environmental analytical chemistry
Supported by:
Supported by the National Natural Science Foundation of China(No.21175086)

Abstract

Abstract:

Carboxymethyl-β-cyclodextrin(CM-β-CD) synthesized by S_N2 substitution was employed successfully on the modification of the surface of the Fe₃O₄ magnetic nanoparticles(MNPs) using a layer-by-layer method. The as-prepared CM-β-CD functionalized magnetic nanocomposites(CM-β-CD-MNPs) were characterized by transmission electron microscopy(TEM), Fourier transform infrared spectroscopy(FTIR) and vibrating sample magnetometer(VAM). The adsorption properties of CM-β-CD-MNPs on rhodamine B(RhB) were investigated. The results show that CM-β-CD-MNPs are nearly spherical, with an average particle diameter of 16 nm, and are superparamagnetic with a relatively high saturation magnetization value of 54 emu/g. Adsorption kinetic coincides with the pseudo-second-order kinetic model and the adsorption equilibrium is reached within 1 h. Adsorption isotherm fits well to Langmuir adsorption model and the maximum adsorption reaches up to 135.1 mg/g.

Key words: carboxymethy-β-cyclodextrin, ferroferric oxide, adsorption, rhodamine B

CLC Number:

O647.3

SUN Linlin, ZHOU Yehong, WANG Fei, SHUANG Shaomin, DONG Chuan. Adsorption Properties of Carboxymethyl-β-cyclodextrin Functionalized Ferroferric Oxide Magnetic Nanocomposites on Rhodamine B[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 110-117.

References

[1] YAN Fanyong,CHEN Ligong,Yan Xilong, et al . Synthesis and Applications of Rhodamine Fluorescent Dyes[J]. Chem Prog ,2006,18(2):252-261(in Chinese).
颜范勇,陈立功,闫喜龙,等. 罗丹明类荧光染料的合成及应用[J]. 化学进展,2006,18(2):252-261.
[2] Slyusareva E,Gerasimova M,Plotnikov A, et al . Spectral Study of Fluorine Dyes Adsorption on Chitosan-based Polyelectrolyte Complexes[J]. J Colloid Interface Sci ,2014,417:80-87.
[3] LIU Xinxin,YANG Zhonglian,GAO Baoyu, et al . Coagulation Characteristics of Polyferric Chloride-Poly(epichlorohydrin-dimethylamine) Composite Flocculant for Simulated Water Treatment[J]. Environ Sci ,2013,34(9):3493-3501(in Chinese).
刘新新,杨忠莲,高宝玉,等. 聚合氯化铁-聚(环氧氯丙烷-二甲胺)复合絮凝剂在模拟水处理中的混凝特性研究[J]. 环境科学,2013,34(9):3493-3501.
[4] GUAN Weisheng,ZHAO Huan,HUO Pengwei, et al . Preparation of Titania Supported on Mesoporous SBA-15 and Photocatalytic Activity of Dye Wasterwater[J]. Environ Sci Technol ,2013,36(4):132-136(in Chinese).
关卫省,赵欢,霍鹏伟,等. 表面包覆TiO₂材料的制备及光催化降解染料废水[J]. 环境科学与技术,2013,36(4):132-136.
[5] Ramakrishna K R,Viraraghavan T. Dye Removal Using Low Cost Adsorbents[J]. Water Sci Technol ,2004,21(1):97-104.
[6] LI Xinjue,QIAN Feiyue,LI Mu, et al . the Removal of Dyeing Wastewater Biochemical by Activated Carbon on Ddifferent Types of Organic Matter in Water[J]. Environ Chem ,2012,31(3):396-397(in Chinese).
李欣珏,钱飞跃,李暮,等. 活性炭吸附对印染废水生化出水中不同种类有机物的去除效果[J]. 环境化学,2012,31(3):396-397.
[7] Connors K A . The Stability of Cyclodextrin Complexes in Solution[J]. Chem Rev ,1997,97(5):1325-1358.
[8] Li W H,Tan G G,Zhao L, et al . Computer-Aided Molecular Modeling Study of Enantioseparation of Iodiconazole and Structurally Related Triadimenol Analogues by Capillary Electrophoresis:Chiral Recognition Mechanism and Mathematical Model for Predicting Chiral Separation[J]. Anal Chim Acta ,2012,718:138-147.
[9] Zhang Z,Gu S Q,Ding Y P, et al . Mild and Novel Electrochemical Preparation of β -Cyclodextrin/Graphene Nanocomposite Film for Super-sensitive Sensing of Quercetin[J]. Biosens Bioelectron ,2014,57:239-244.
[10] Teblum E B,Landfester K. Miniemulsion Polymerization of Cyclodextrin Nanospheres for Water Purification from Organic Pollutants[J]. Eur Polym J ,2010,46(8):1671-2351.
[11] Chen M,Ding W H,Wang J, et al . Removal of Azo Dyes from Water by Combined Techniques of Adsorption, Desorption, and Electrolysis Based on A Supramolecular Sorbent[J]. Ind Eng Chem Res ,2013,52:2403-2411.
[12] Lu A H,Salabas E L,Ferdi S. Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application[J]. Angew Chem Int Edit ,2007,46(8):1222-1244.
[13] ZHANG Conglu,HU Xiaomin,YING Shiying, et al . Preparation of Magnetic Quaternary Chitosan Salt and Its Adsorption of Methyl Orange from Water[J]. Environ Sci ,2013,34(5):1815-1821(in Chinese).
张聪璐,胡筱敏,英诗颖,等. 壳聚糖季铵盐磁性颗粒的制备及其对甲基橙的吸附效果[J]. 环境科学,2013,34(5):1815-1821.
[14] Badruddoza A Z M,Hidajat K,Uddin M S. Selective Recognition and Separation of Nucleosides Using Carboxymethyl- β -Cyclodextrin Functionalized Hybrid Magnetic Nanoparticles[J]. Colloid Surf B ,2012,92:223-231.
[15] Badruddoza A Z M,Rahmanb M T,Ghosh S, et al . β -Cyclodextrin Conjugated Magnetic, Fluorescent Silica Core-Shell Nanoparticles for Biomedical Applications[J]. Carbohydr Polym ,2013,95:449-457.
[16] Chalasani R,Vasudevan S. Cyclodextrin Functionalized Magnetic Iron Oxide Nanocrystals:A Host-Carrier for Magnetic Separation of Non-Polar Molecules and Arsenic from Aqueous Media[J]. J Mater Chem ,2012,22:14925-14931.
[17] Mak S Y,Chen D H. Fast Adsorption of Methylene Blue on Polyacrylic Acid-Bound Iron Oxide Magnetic Nanoparticles[J]. Dyes Pigm ,2004,61:93-98.
[18] Xu X,Shen H,Xu J, et al . The Colloidal Stability and Core-Shell Structure of Magnetite Nanoparticles Coated with Alginate[J]. Appl Surf Sci ,2006,253(4):2158-2164.
[19] Caruntu D,Caruntu G,Chen Y X, et al . Synthesis of Variable-Sized Nanocrystals of Fe 3 O 4 with High Surface Reactivity[J]. Chem Mater ,2004,16:5527-5534.
[20] Kasnavia T,Vu D,Sabatini D A. Fluorescent Dye and Media Properties Affecting Sorption and Tracer Selection[J]. Ground Water ,1999,37(3):376-381.
[21] Bakkialakshmi S,Menaka T. Study on the Inclusion Interactions of β -Cyclodextrin with Rhodamine B Base[J]. Int J Chem Tech Res ,2012,4(1):223-231.
[22] WU Zhijian,LIU Haining,ZHANG Huifang. Research Progress on Mechanisms about the Effect of Ionic Strength on Adsorption[J]. Environ Chem ,2012,29(6):997-1003(in Chinese).
吴志坚,刘海宁,张慧芳. 离子强度对吸附影响机理的研究进展[J]. 环境化学,2012,29(6):997-1003.
[23] Ho Y S,McKay G. Pseudo-Second Order Model for Sorption Processes[J]. Process Biochem ,1999,34:451-465.
[24] García-Calzń J A,Díaz-García M E. Characterization of Binding Sites in Molecularly Imprinted Polymers[J]. Sens Actuat B-Chem ,2007,123:1180-1194.

Adsorption Properties of Carboxymethyl-β-cyclodextrin Functionalized Ferroferric Oxide Magnetic Nanocomposites on Rhodamine B

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ning YUAN, Jie MA, Jin-Ling ZHANG, Jian-Sheng ZHANG. Preparation of PCN-6（M） Bimetallic Organic Framework Materials by Steam-assisted Method and Their CO₂ and CH₄ Adsorption Performance [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 896-903.
[2]	Chen-Li HAO, Qing-Wei DING, Shi-Chang JIA, Yang-Bo MAO, Song-Bai WANG, Jun MA. Adsorption of Methylene Blue on Titanate Nanotubes Modified with Lipoic Acid [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 749-757.
[3]	Qin ZHANG, Wen-Bin LIU, Li-Jiao FAN, Yu-Ming XIE, Guo-Lin HUANG. Research Progress in the Preparation of Functionalized Mesoporous Silica and Its Application in Adsorption and Separation of Uranium from Water [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 169-187.
[4]	Qian YANG, Yang ZHANG, Ming-Yang LAI, Lin GUO, Jian-Bo JIA. Adsorption Performance of Rhodamine B on Magnetic Biochar Prepared at Different Pyrolysis Temperatures [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 288-298.
[5]	Yue-Hua ZHAO, Da-Peng WANG. Coadsorption Kinetics of Amino‑Functionalized Graphene Oxide and Fatty Acids at the Water/Oil Interface [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1274-1284.
[6]	Cong-Jun CAO, Han-Xiao MA, Cheng-Min HOU, Xiao-Jian DING, Biao GUAN. Adsorption of Cu（Ⅱ） from Solution by Modified Magnetic Ethyl Cellulose [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 969-979.
[7]	Song-Song XUE, Zheng-Feng XIE, Jia-Wei HE, Tian-Yi ZHANG, Bao-Ping XIA, Yu-Qin LI. Synthesis of Sulfonylhydrazone Probe with High Selectivity and Rapid Identification of Hg（Ⅱ） Ion and Its Application in Adsorption [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 760-768.
[8]	Jian-Shuang ZHANG, Mei-Zhen GAO, Meng-Yao WANG, Qi SHI, Jin-Xiang DONG. Zeolitic Imidazolate Framework ZIF‑71 for Adsorption and Separation of 2，3‑Butanediol/1，3‑Propanediol From Dilute Aqueous Solutions [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1735-1745.
[9]	Ding-Kun YUAN, Wei-Fan CHU, Jia-Hui NI. Preparation of Copper Ferrocyanide⁃Polyacrylamide/ Carboxymethyl Cellulose/Graphene Composite Hydrogel and Its Adsorption Performance of Rubidium [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1746-1756.
[10]	XUE Xiao-Kang, FU Hong, CHEN Li-Juan, LI Jie, YANG Fang. Preparation of Ferroferric Oxide Loaded Graphitized Carbon Black Magnetic Nanomaterials and Application in Detection of Pesticide Residues in Tea [J]. Chinese Journal of Applied Chemistry, 2021, 38(8): 995-1006.
[11]	NIU Zhan-Ning, TANG Hao-Qing, ZHENG Chao, TIAN Tian, ZHENG Li-Yun. Study on [RESA]Br@-COOH@Fe₃O₄ with Density Functional Theory [J]. Chinese Journal of Applied Chemistry, 2021, 38(7): 825-835.
[12]	LIU Wen-Bin, YANG Sha-Sha, HUANG Guo-Lin, FAN Li-Jiao, XIE Yu-Ming. Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 658-667.
[13]	TIAN Long, DOU Wei-Xin, YANG Wei-Ting, WANG Cheng. Size Effect of ZIF-8 on the Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 0-0.
[14]	TIAN Long, DOU Wei-Xin, YANG Wei-Ting, WANG Cheng. Size Effect of ZIF-8 on the Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 84-91.
[15]	SHI Yanlong, FENG Xiaojuan, YANG Ruihua, WANG Jianrong. Preparation of Superhydrophobic and Superoleophilic Corn Straw Fibers Oil Absorbents and Application to the Removal of Spilled Oil from Water [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 793-802.