Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium

doi:10.19894/j.issn.1000-0518.200360

Chinese Journal of Applied Chemistry ›› 2021, Vol. 38 ›› Issue (6): 658-667.DOI: 10.19894/j.issn.1000-0518.200360

• Full Papers • Previous Articles Next Articles

Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium

LIU Wen-Bin, YANG Sha-Sha, HUANG Guo-Lin^*, FAN Li-Jiao, XIE Yu-Ming

National Defense Key Discipline Laboratory of Radioactive Geology and Exploration Technology, East China University of Technology, Nanchang 330013, China

Received:2020-12-02 Revised:2021-02-17 Published:2021-06-01 Online:2021-08-01
Supported by:
National Natural Science Foundation of China (No.21866005), Jiangxi Key Plan of Research and Development (No.20192BBH80011)

Abstract

Abstract: The preparation of a novel phosphate-functionalized xanthan gum/graphene oxide (P-XG/GO) which is cross-linked with xanthan gum and functionalized with phosphoric acid was investigated for the selective adsorption of uranium from aqueous solutions in this study. The results from scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) and Zeta potential analysis confirm that the cross-linking and phosphorylation modification are successful in our experiment. The effects of factors such as solution pH, initial concentration, adsorption time and temperature on the adsorption performance were studied and the most suitable adsorption conditions were obtained. The Langmuir isotherm model for adsorption data is well fitted, and the maximum adsorption capacity is 495.05 mg/g. Compared with the pseudo-first-order kinetic model, the pseudo-second-order kinetic model better fits the adsorption process.

Key words: Xanthan gum, Graphene oxide, Selective adsorption, Uranium

CLC Number:

O615

LIU Wen-Bin, YANG Sha-Sha, HUANG Guo-Lin, FAN Li-Jiao, XIE Yu-Ming. Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium[J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 658-667.

References

[1] AL-HOBAIB A S, AL-SUHYBANI A A. Removal of uranyl ions from aqueous solutions using barium titanate[J]. J Radioanal Nucl Chem, 2014, 299(1): 559-567.
[2] LADEIRA A C Q, MORAIS C A. Uranium recovery from industrial effluent by ion exchange-column experiments[J]. Miner Eng, 2005, 18(13): 1337-1340.
[3] LUO W, KELLY S D, KEMNER K M, et al. Sequestering uranium and technetium through co-precipitation with aluminum in a contaminated acidic environment[J]. Environ Sci Technol, 2009, 43(19): 7516-7522.
[4] BELTRAMI D, CHAGNES A, HADDAD M, et al. Recovery of uranium (VI) from concentrated phosphoric acid by mixtures of newbis(1,3-dialkyloxypropan-2-yl) phosphoric acids and tri-n-octylphosphine oxide[J]. Hydrometallurgy, 2013, 140: 28-33.
[5] FAVRE-REGUILLON A, LEBUZIT G, FOOS J, et al. Selective concentration of uranium from seawater by nanofiltration[J]. Ind Engine Chem Res, 2003, 42(23): 5900-5904.
[6] HUANG G, PENG W, YANG S, et al. Synthesis of magnetic chitosan/graphene oxide nanocomposites and its application for U(VI) adsorption from aqueous solution[J]. J Radioanal Nucl Chem, 2018, 317(1): 337-344.
[7] HE H, ZONG M, DONG F, et al. Simultaneous removal and recovery of uranium from aqueous solution using TiO₂ photoelectrochemical reduction method[J]. J Radioanal Nucl Chem, 2017, 313(1): 59-67.
[8] SHAO L, WANG X, REN Y, et al. Facile fabrication of magnetic cucurbit[6]uril/graphene oxide composite and application for uranium removal[J]. Chem Eng J, 2016, 286: 311-319.
[9] ZHANG Q, ZHAO D, DING Y, et al. Synthesis of Fe-Ni/graphene oxide composite and its highly efficient removal of uranium(VI) from aqueous solution[J]. J Clean Prod, 2019, 230: 1305-1315.
[10] GAO Y, LI Y, ZHANG L, et al. Adsorption and removal of tetracycline antibiotics from aqueous solution bygraphene oxide[J]. J Colloid Interface Sci, 2012, 368(1): 540-546.
[11] PENG W, LI H, LIU Y, et al. A review on heavy metal ions adsorption from water by graphene oxide and its composites[J]. J Mol Liq, 2017, 230: 496-504.
[12] PENG W, HUANG G, YANG S, et al. Performance of biopolymer/graphene oxide gels for the effective adsorption of U(VI) from aqueous solution[J]. J Radioanal Nucl Chem, 2019, 322(2): 861-868.
[13] YANG S, HUANG Y, HUANG G, et al. Preparation ofamidoxime-functionalized biopolymer/graphene oxide gels and their application in selective adsorption separation of U(VI) from aqueous solution[J]. J Radioanal Nucl Chem, 2020, 324(2): 847-855.
[14] MORSY A M A. Adsorptive removal of uranium ions from liquid waste solutions byphosphorylated chitosan[J]. Environ Technol Inno, 2015, 4: 299-310.
[15] PRODROMOU M, PASHALIDIS I. Uranium adsorption by non-treated and chemically modified cactus fibres in aqueous solutions[J]. J Radioanal Nucl Chem, 2013, 298(3): 1587-1595.
[16] CAI Y, CHEN L, YANG S, et al. Rational synthesis of novelphosphorylated chitosan-carboxymethyl cellulose composite for highly effective decontamination of U(VI)[J]. ACS Sustain Chem Eng, 2019, 7(5): 5393-5403.
[17] LIU L, LI C, BAO C, et al. Preparation and characterization ofchitosan/graphene oxide composites for the adsorption of Au(Ⅲ) and Pd(II)[J]. Talanta, 2012, 93: 350-357.
[18] LIU S, YAO F, ODERINDE O, et al. Green synthesis of orientedxanthan gum-graphene oxide hybrid aerogels for water purification[J]. Carbohydr Polym, 2017, 174: 392-399.
[19] ZHANG Z, DONG Z, WANG X, et al.Synthesis of ultralight phosphorylated carbon aerogel for efficient removal of U(Ⅵ): batch and fixed-bed column studies[J]. Chem Eng J, 2019, 370: 1376-1387.
[20] LI L, MA R, WEN T, et al.Functionalization of carbon nanomaterials by means of phytic acid for uranium enrichment[J]. Sci Total Environ, 2019, 694: 133697.
[21] LI Y, DU Q, LIU T, et al. Comparative study ofmethylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes[J]. Chem Eng Res Des, 2013, 91(2): 361-368.
[22] QU R, ZHANG Y, QU W, et al. Mercury adsorption by sulfur- and amidoxime-containing bifunctional silica gel based hybrid materials[J]. Chem Eng J, 2013, 219: 51-61.
[23] XIAO J, JING Y, YAO Y, et al. Synthesis ofamidoxime-decorated 3D cubic mesoporous silica via self-assembly co-condensation as a superior uranium(VI) adsorbent[J]. J Mol Liq, 2019, 277: 843-855.
[24] ZHAO C, LIU J, YUAN G, et al. A novel activated sludge-graphene oxide composites for the removal of uranium(Ⅵ) from aqueous solutions[J]. J Mol Liq, 2018, 271: 786-794.
[25] XIAO J, JING Y, WANG X, et al.Preconcentration of Uranium(VI) from aqueous solution by amidoxime-functionalized microspheres silica material: kinetics, isotherm and mechanism study[J]. Chem Select, 2018, 3(43): 12346-12356.
[26] FAROOGHI A, SAYADI M H, REZAEI M R, et al. An efficient removal of lead from aqueous solutions using FeNi₃@SiO₂ magnetic nanocomposite[J]. Surf Interfaces, 2018, 10: 58-64.
[27] WANG S, WANG K, DAI C, et al. Adsorption of Pb²⁺ on amino-functionalized core-shell magnetic mesoporous SBA-15 silica composite[J]. Chem Eng J, 2015, 262: 897-903.
[28] ZHUANG S, CHENG R, KANG M, et al. Kinetic and equilibrium of U(Ⅵ) adsorption onto magnetic amidoxime-functionalized chitosan beads[J]. J Clean Prod, 2018, 188: 655-661.
[29] DEBNATH S, MAITY A, PILLAY K. Magneticchitosan-GO nanocomposite: synthesis, characterization and batch adsorber design for Cr(VI) removal[J]. J Environ Chem Eng, 2014, 2(2): 963-973.
[30] CHEN H, WANG Y, ZHAO W, et al.Phosphorylation of graphehe oxide to improve adsorption of U(VI) from aquaeous solutions[J]. J Radioanal Nucl Chem, 2017, 313(1): 175-189.
[31] CAI Y, WU C, LIU Z, et al. Fabrication of aphosphorylated graphene oxide-chitosan composite for highly effective and selective capture of U(Ⅵ)[J]. Environ Sci: Nano, 2017, 4(9): 1876-1886.
[32] WANG F, LI H, LIU Q, et al. Agraphene oxide/amidoxime hydrogel for enhanced uranium capture[J]. Sci Rep, 2016, 6(1): 19367.

Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Qin ZHANG, Wen-Bin LIU, Li-Jiao FAN, Yu-Ming XIE, Guo-Lin HUANG. Research Progress in the Preparation of Functionalized Mesoporous Silica and Its Application in Adsorption and Separation of Uranium from Water [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 169-187.
[2]	Yue-Hua ZHAO, Da-Peng WANG. Coadsorption Kinetics of Amino‑Functionalized Graphene Oxide and Fatty Acids at the Water/Oil Interface [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1274-1284.
[3]	Shan SHAO, Jian ZHANG, Kai-Qiang DENG, Jie YANG, Shao-Ming YANG. Detection of Dopamine by Enzyme‑Free Sensor Constructed by Nickel‑Cobalt Bimetallic‑porphyrin Organic Framework Composites [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1098-1107.
[4]	Qing-Fang NIU, Xin AI, Yi-Xuan WANG, Fang-Jiu HE, Bi LUO, Wen-Ting LIANG, Chuan DONG. Synthesis of Three‑Dimensional Reduced Graphene Oxide/β‑Cyclodextrin Complex and Its Electrochemical Detection of Levofloxacin in Water [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1129-1137.
[5]	Yi-Xin XU, Shuang WANG, Jing QUAN, Wan-Ting GAO, Tian-Qun SONG, Mei YANG. Preparation of Molybdenum Disulfide Quantum Dots/Reduced Graphene Oxide Composites and Their Photocatalytic Degradation of Organic Dyes， Tetracyclines and Cr（VI） [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 769-778.
[6]	ZHANG Ya-Jing, WANG Xiao-Hui, XU Ya-Juan, LIU Wen-Shu, ZHAO Li-Hui. Preparation of Graphene Nano-Drug Carrier System and Its Killing Effect on Tumor Cells [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 693-703.
[7]	TIAN Long, DOU Wei-Xin, YANG Wei-Ting, WANG Cheng. Size Effect of ZIF-8 on the Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 0-0.
[8]	TIAN Long, DOU Wei-Xin, YANG Wei-Ting, WANG Cheng. Size Effect of ZIF-8 on the Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 84-91.
[9]	XIAO Haimei, CAI Lei, ZHANG Zhaohui, CHEN Shan, ZHOU Shu, FU Jinli. Preparation of Ion-Imprinted Polymers Based on Magnetic Graphene Oxide/MIL-101 (Cr) and Selective Adsorption of Cu(Ⅱ) and Pb(Ⅱ) [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1076-1086.
[10]	GAO Siheng, YANG Yu, WU Jinling, QIN Lixia, KANG Shizhao, LI Xiangqing. Preparation and Photoelectric Performance of Graphene Oxide/Ultrafine Silver Composite [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 923-929.
[11]	FAN Liangjiao, TIAN Yuqin, QIAN Qin, CHEN Lei, GUO Hongwei, XIN Aiyuan, HOU Wanguo. Rheological Properties of Xanthan Gum/Guar Gum Mixed Solution and Its Borax-Crosslinked System [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 531-540.
[12]	WANG Wei, LI Juan, BAI Ru, HAN Zhen, FENG Xuewei, SUN Yue. Preparation of Au/Polyacrylamide@Graphene Oxide/Nano-palladium Electrode via Metal-Free Visible-Light-Induced Atom Transfer Radical Polymerization and Its Detection of Ethanol [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 595-603.
[13]	HUO ZhaoHui, YANG Xiaoshan, CHEN Xiaoli, ZHANG Gang, YIN Wei, CAO Manli, SHI Lei, QIU Yanxuan. Preparation of Ag/Two-Dimensional Graphitic Carbon Nitride/Reduced Graphene Oxide Composite and Its Photocatalytic Degradation of Antibiotics [J]. Chinese Journal of Applied Chemistry, 2020, 37(4): 471-480.
[14]	YU Zhiqiang, QU Jiangying, LI Jielan, ZANG Yunhao, GU Jianfeng, GAO Feng. Assembly of Graphene Oxide-Based Flexible Generator and Its Water Evaporation Power Generation Performance [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 1164-1171.
[15]	YU Zhiqiang, QU Jiangying, LI Jielan, ZANG Yunhao, GU Jianfeng, GAO Feng. Assembly of Graphene Oxide-Based Flexible Generator and Its Water Evaporation Power Generation Performance [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 0-0.