Synthesis, Crystal Structure and Fluorescent Property of a Silver Coordination Compound

doi:10.11944/j.issn.1000-0518.2015.10.150036

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (10): 1127-1133.DOI: 10.11944/j.issn.1000-0518.2015.10.150036

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Synthesis, Crystal Structure and Fluorescent Property of a Silver Coordination Compound

XUE Mengwei,PAN Zhaorui(),SHI Xiaoran,SHAO Yang

School of Environmental Science,Nanjing Xiaozhuang University,Nanjing 211171,China

Received:2015-01-29 Accepted:2015-06-23 Published:2015-10-10 Online:2015-10-10
Contact: PAN Zhaorui
Supported by:
Supported by the National Natural Science Foundation of China(No.21301094), Nanjing Xiaozhuang University Students Scientific Research Project(No.2014XSKY036

Abstract

Abstract:

A new silver coordination compound [Ag(mtyaa)]₂·5(H₂O)(mtyaa:2-(5-methyl-1,3,4-thiadiazol-2-ylthio)acetic acid anion) has been synthesized by diffusion method and characterized by single-crystal X-ray diffraction, elemental analysis, FTIR spectroscopy, thermal analysis and powder X-ray diffraction. The crystal belongs to a triclinic system with a P1¯ space group. The cell parameters are:a=0.8473(4) nm, b=1.0620(5) nm, c=1.2055(6) nm, α=102.321(8)°, β=99.951(9)°, γ=96.298(9)°, V=1.0317(9) nm³, Z=2, D_c=2.203 g/cm³, F(000)=676, R₁=0.0670, wR₂=0.1558. The mtyaa ligand takes two kinds of coordination modes and the tetracoordinated Ag center is bridged by an endocyclic nitrogen atom and a sulfur atom from the adjacent mtyaa ligand to form a two dimensional structure. The two dimensional structure is further linked to a three dimensional network by numerous hydrogen bonds. The fluorescent property of the title compound was discussed. The result shows that the title compound exhibits two weak emission peaks at 467 and 492 nm and one broad emission band with a maximum at ca. 530 nm when the excitation wavelength is 350 nm.

Key words: (methyl-thiadiazol-ylthio)acetic acid, silver compound, crystal structure, hydrogen bond, fluorescence

XUE Mengwei,PAN Zhaorui,SHI Xiaoran,SHAO Yang. Synthesis, Crystal Structure and Fluorescent Property of a Silver Coordination Compound[J]. Chinese Journal of Applied Chemistry, 2015, 32(10): 1127-1133.

References

[1]	Metrangolo P,Resnati G. Halogen Bonding:Fundamentals and Applications(Structure and Bonding)[M]. Springer:Heidelberg,2010.
[2]	Chen C L,Kang B S,Su C Y. Recent Advances in Supramolecular Design and Assembly of Silver(Ⅰ) Coordination Polymers[J]. Aust J Chem,2006,59(1):3-18.
[3]	Desiraju G R. Crystal Engineering: From Molecule to Crystal[J]. J Am Chem Soc,2013,135(27):9952-9967.
[4]	Dura' G,Carrio'n M C,Jalo'n F A,et al. Metal Supramolecular Frameworks with Silver and Ditopic Bis(pyrazolyl)methane Ligands: Effect of the Anions and Ligand Substitution[J]. Cryst Growth Des,2014,14(7):3510-3529.
[5]	Aakero'y C B,Champness N R,Janiak C. Recent Advances in Crystal Engineering[J]. Cryst Eng Comm,2010,12(1):22-43.
[6]	Desiraju G R. A Bond by Any Other Name[J]. Angew Chem Int Ed,2011,50(1):52-59.
[7]	Prins L J,Reinhoudt D N,Timmerman P. Noncovalent Synthesis Using Hydrogen Bonding[J]. Angew Chem Int Ed,2001,40(13):2382-2426.
[8]	Schug K A,Lindner W. Noncovalent Binding between Guanidinium and Anionic Groups:Focus on Biological- and Synthetic-Based Arginine/Guanidinium Interactions with Phosph[on]ate and Sulf[on]ate Residues[J]. Chem Rev,2005,105(1):67-113.
[9]	Dunitz J D,Gavezzotti A. Molecular Recognition in Organic Crystals:Directed Intermolecular Bonds or Nonlocalized Bonding?[J]. Angew Chem Int Ed,2005,44(12):1766-1787.
[10]	Guzmán-Percástegui E,Alvarado-Rodríguez J,Cruz-Borbolla J,et al.Subtle C-H····Hal (Hal=Cl,Br) Bonding as Predominant Synthon in the Assembly of Supramolecular Architectures Based on Luminescent Tin(Ⅳ) Complexes. Crystallography, Hirshfeld Surfaces, DFT Calculations, and Fluorescence[J]. Cryst Growth Des,2014,14(8):3742-3757.
[11]	Burattini S,Greenland B W,Merino D H,et al.A Healable Supramolecular Polymer Blend Based on Aromatic π-π Stacking and Hydrogen-Bonding Interactions[J]. J Am Chem Soc,2010,132(34):12051-12058.
[12]	Nishio M. CH/π Hydrogen Bonds in Crystals[J]. Cryst Eng Comm,2004,6(5):130-158.
[13]	Metrangolo P,Resnati G. Halogen Bonding:Where We Are and Where We Are Going[J]. Cryst Growth Des,2012,12(12):5835-5838.
[14]	Zhang M L,Li D S,Wang J J,et al.Structural diversity and properties of ZnⅡ and CdⅡ Complexes with a Flexibledicarboxylate Building Block 1,3-Phenylenediacetate and Various Heterocyclic co-Ligands[J]. Dalton Trans,2009,27(27):5355-5364.
[15]	Jin H G,Yan Y Z,Li J,et al.1D to 3D Lanthanide Coordination Polymers Constructed from 5-Aminoisophthalic Acid and Oxalic Acid[J]. Inorg Chem Commun,2012,23(9):25-30.
[16]	Wang P,Fan R Q,Yang Y L,et al.1-D Helical Chain, 2-D Layered Network and 3-D Porous Lanthanide-organic Frameworks Based on Multiple Coordination Sites of Benzimidazole-5,6-dicarboxylic Acid:Synthesis, Crystal Structure, Photoluminescence and Thermal Stability[J]. Cryst Eng Comm,2013,15(5):4489-4506.
[17]	MA Meihua,PAN Zhaorui,XU Jiao,et al.Syntheses and Crystal Structures of Four Cobalt Supramolecular Architectures with Hmtyaa Ligand[J]. Chinese J Struct Chem,2010,29(6):843-852(in Chinese). 马美华,潘兆瑞,徐娇,等. 四个含有Hmtyaa配体钴配合物的合成和晶体结构[J]. 结构化学,2010,29(6):843-852.
[18]	PAN Zhaorui,ZHONG Hong,XIAN Hua. Syntheses and Crystal Structures of Nickel(Ⅱ) Coordination Compounds with 2-(5-Methyl-1.3,4-thiadiazol-2-ylthio)acetic Aicd[J]. Chinese J Inorg Chem,2010,26(11):1955-1960(in Chinese). 潘兆瑞,周宏,鲜华. 2-(5-甲基-1,3,4-噻二唑)-硫乙酸镍(Ⅱ)配合物的合成和晶体结构[J]. 无机化学学报,2010,26(11):1955-1960.
[19]	PAN Zhaorui. Syntheses and Crystal Structures of Rare Earth Coordination Compounds with 2-(5-Methyl-1.3,4-thiadiazol-2-ylthio)acetic Aicd[J]. Chinese J Inorg Chem,2011,27(10):2027-2032(in Chinese). 潘兆瑞. 2-(5-甲基-1,3,4-噻二唑)-硫乙酸稀土配合物的合成和晶体结构[J]. 无机化学学报,2011,27(10):2027-2032.
[20]	Liang Zhao L,Mak T C W. Assembly of Silver(Ⅰ) Two- and Three-Dimensional Coordination Networks with Complementary Tridentate Heteroaryl Ethynide Ligands[J]. Inorg Chem,2009,48(14):6480-6489.
[21]	Li G,Lei Z,Wang Q M. Luminescent Molecular Ag-S Nanocluster [Ag62S13(SBut)32](BF4)4[J]. J Am Chem Soc,2010,132(50):17678-17679.
[22]	Han L L,Zhang X Y,Chen J S,et al.Silver(Ⅰ)/Bipyrazole/Dicarboxylate Interpenetrated Coordination Networks:Spontaneous Chiral Resolution, Modulation of Topologies, Water Clusters, and Photoluminescences[J]. Cryst Growth Des,2014,14(5):2230-2239.
[23]	Glowacki E D,Irimia-Vladu M,Bauerb S,et al.Hydrogen-bonds in Molecular Solids- from Biological Systems to Organic Electronics Mater[J]. J Mater Chem B,2013,1(31):3742-3753.
[24]	Srogl J,Liu W S,Marshall D,et al.Bio-organometallic Organosulfur Chemistry. Transition Metal-Catalyzed Cross-Coupling Using Coenzyme M or Thioglycolic Acid as the Leaving Group[J]. J Am Chem Soc,1999,121(40):9449-9450.
[25]	Brukek 2000,SMART(Version 5.0),SAINT-plus(Version 6),SHELXTL(Version 6.1), and SADABS(Version 2.03);Bruker AXS Inc.:Madison,WI.
[26]	Ding C,Li X,Ding Y,et al.Novel Bis(4,4'-dipyridylamine) Ligand with a Flexible Butadiyne Linker:Syntheses, Structures, and Photoluminescence of d10 Metal Coordination Polymers[J]. Cryst Growth Des,2012,12(7):3465-3473.
[27]	Cui Y,Yue Y,Qian G,et al.Luminescent Functional Metal-organic Frameworks[J]. Chem Rev,2012,112(2):1126-1162.
[28]	Zheng S L,Tong M L,Tan S D,et al.Syntheses, Structures, and Properties of Three Novel Coordination Polymers of Silver(Ⅰ) Aromatic Carboxylates with Hexamethylenetetramine Exhibiting Unique Metal-π Interaction[J]. Organometallics,2001,20(25):5319-5325.
[29]	Valeur B. Molecular Fluorescence:Principles and Applications[M]. Wiley-VCH:Weinheim,2002.
[30]	Wang Z J,Qin L,Zhang X,et al.Controlling Interpenetrating of Five Metal-organic Framework Based on Bis(4-pyridine-4-yl) Phenyl)amine[J]. Cryst Growth Des,2015,15(3):1303-1310.
[31]	Huang X C,Zheng S L,Zhang J P,et al.Synthesis, Structure, and Photoluminescent Studies of a New Novel Supramolecular [Ag(phen)(CN)] (phen) Complex[J]. Eur J Inorg Chem,2004,5(5):1024-1029.
[32]	Blasse G,Bleijenberg K C,Powell R C. Structure and Bonding42:Luminescence and Energy Transfer[M]. Springer-Verlag:Berlin,1980.

Synthesis, Crystal Structure and Fluorescent Property of a Silver Coordination Compound

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