Preparation and Characterization of Poly(Maleic Anhydride-co-Vinyl Acetate)Comblike Single-Cation Polymer Conductors

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (2): 24-27.

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Preparation and Characterization of Poly(Maleic Anhydride-co-Vinyl Acetate)Comblike Single-Cation Polymer Conductors

Yu Yanlei, Zong Huijuan

Department of Material Science, Fudan University, Shanghai 200433

Received:1996-08-28 Revised:1997-02-17 Published:1997-04-10 Online:1997-04-10

Abstract

Abstract: The comblike polymers with carboxylate groups and poly(ethylene oxide)side chains have been synthesized by alcoholysis of maleic anhydride-vinyl acetate copolymers with PEO monoether. The plasticized alkali polymer salt films showed conductivity up to 10^-5S/cm at room temperature. It was found that the conductivity increased when the length of the side chains increased appropriately. The effects of plasticizer, cation radius, temperature and frequency on the conductivity were also investigated.

Key words: maleic anhydride-vinyl acetate copolymer, polymer single-ion conductor, preparation, conductivity

Yu Yanlei, Zong Huijuan. Preparation and Characterization of Poly(Maleic Anhydride-co-Vinyl Acetate)Comblike Single-Cation Polymer Conductors[J]. Chinese Journal of Applied Chemistry, 1997, 0(2): 24-27.

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Preparation and Characterization of Poly(Maleic Anhydride-co-Vinyl Acetate)Comblike Single-Cation Polymer Conductors

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