Synthesis of Carboxylic Ester by Organotin Catalyzed Transesterification

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (4): 59-61.

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Synthesis of Carboxylic Ester by Organotin Catalyzed Transesterification

Tian Laijin¹, Fu Fangxin^1,2, Tian Junlian¹, Liu Shuxiang¹

1. Department of Chemistry, Qufu Normal University, Qufu 273165;
2. Department of Chemistry, Northeast Normal University, Changchun

Received:1995-09-15 Revised:1996-04-26 Online:1996-08-10 Published:1996-08-10

Abstract

Abstract: The catalytic activities of four organotin compounds BuSnCl₃(Ⅰ),Bu₂SnCl₂(Ⅱ), Bu₂SnO(Ⅲ) and ClBu₂SnOSnBu₂Cl(Ⅳ) for the reaction of ethyl hexylate with allyl alcohol were reported. A series of acrylic esters was synthesized by catalytic transesterification of methyl acrylate and alcohols with (Ⅳ).It was found that methyl 3-trichlorostannylpropionate readily undergoes an autocatalysed transesterification with alcohols, forming the correspounding propionate analogs.The catalytic activity of organotins for transesterification possibly comes from the coordination of the carbonyl oxygen in ester to the tin atom.

Key words: organotin, catalysis, transesterification, carboxylic ester

Tian Laijin, Fu Fangxin, Tian Junlian, Liu Shuxiang. Synthesis of Carboxylic Ester by Organotin Catalyzed Transesterification[J]. Chinese Journal of Applied Chemistry, 1996, 0(4): 59-61.

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Synthesis of Carboxylic Ester by Organotin Catalyzed Transesterification

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