Preparation and Electrochemical Performances of Li(Ni1/3Co1/3Mn1/3)0.95Al0.05O2 Cathode Material for Lithium-ion Batteries

doi:10.3724/SP.J.1095.2014.30270

Chinese Journal of Applied Chemistry

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Preparation and Electrochemical Performances of Li(Ni_1/3Co_1/3Mn_1/3)_0.95Al_0.05O₂ Cathode Material for Lithium-ion Batteries

LIU Jianben^1*, MO Rubao², WU Xianming¹

(1.College of Chemistry and Chemical Engineering，Jishou University,Jishou 416000,China;
2.JiuGui Liquor Co.,Ltd，Jishou 416000,China)

Received:2013-05-30 Revised:2013-08-15 Published:2014-04-10 Online:2014-04-10

Abstract

Abstract: A series of cathode materials Li(Ni1/3Co1/3Mn1/3)1-xAlxO2(0≤x≤0.1) was synthesized by chemical method. The microstructure, surface morphology and electrochemical performance of products synthesized were characterized by X-ray diffraction, scanning electron microscopy and electrochemical techniques. The influence of different mixed Al content on the properties of ceramic materials was studied. The results indicat that the as-prepared Li(Ni1/3Co1/3Mn1/3)1-xAlxO2 has a hexagonal α-NaFeO2 structure with a space group of R3m and hexagonal system. Initial discharge capacity of Li(Ni1/3Co1/3Mn1/3)0.95Al0.05O2 is 166.30 mA·h/g in the voltage window of 2.5～4.5 V and shows only 4.43% reduction after 60 cycles. AC impedance method was adopted to study the electrochemical circulation mechanism of Li(Ni1/3Co1/3Mn1/3)O2 and Li(Ni1/3Co1/3Mn1/3)0.95Al0.05O2, and Al-coped cathode material is suitable for high rate discharging.

Key words: lithium-ion battery, cathode materials, Li(Ni1/3Co1/3Mn1/3)0.95Al0.05O2, electrochemical-performance

CLC Number:

O646
TM911

LIU Jianben1*, MO Rubao2, WU Xianming1. Preparation and Electrochemical Performances of Li(Ni_1/3Co_1/3Mn_1/3)_0.95Al_0.05O₂ Cathode Material for Lithium-ion Batteries[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30270.

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Preparation and Electrochemical Performances of Li(Ni_1/3Co_1/3Mn_1/3)_0.95Al_0.05O₂ Cathode Material for Lithium-ion Batteries

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