石墨炔在锂/钠离子电池负极中的应用

doi:10.11944/j.issn.1000-0518.2018.09.180117

摘要/Abstract

摘要：

二维石墨炔优异的物理和化学性质受到了广泛的关注。近几年,与石墨炔相关的理论、合成和应用研究快速发展,并取得显著成果。基于石墨炔独特的制备方式与可控的分子结构,其已经在很多传统的研究领域展现出潜力,也在一些新兴的研究方向上产生重要影响,表明石墨炔的研究正逐渐成为一个非常热门研究领域。而石墨炔在电化学储能方面的研究越来越多,文章概述了石墨炔与电化学储能相关的优异特性,总结了石墨炔的常规制备方法,重点讨论了在低温制备优势下石墨炔家族成员的迅速壮大和相应石墨炔新成员独特结构对电化学储锂和储钠行为的影响。

关键词: 石墨炔, 二维材料, 锂离子电池, 钠离子电池, 负极

Abstract:

Two-dimensional graphdiyne has received widely attentions due to its outstanding physical and chemical properties. Many remarkable progresses of graphdiyne in the theories, preparations, and applications have been received in recent years. Based on its native particularities in the preparations and molecular structure, graphdiyne has already shown many promises in the traditional research areas, and brought important impacts in some new research directions, demonstrating that the graphdiyne has gradually become a hot research field. Its applications in electrochemical energy storage have received more and more attentions. This paper describes the original advantages of graphdiyne in the electrochemical energy storages, summarizes the developments in preparations, and mainly discusses the expansion of graphdiyne family via low-temperature synthesis and their electrochemical behaviors in storing the lithium/sodium ions.

Key words: graphdiyne, 2D material, lithium-ion battery, sodium-ion battery, anode

左自成,李玉良. 石墨炔在锂/钠离子电池负极中的应用[J]. 应用化学, 2018, 35(9): 1057-1066.

ZUO Zicheng,LI Yuliang. Applications of Graphdiyne in Li⁺/Na⁺ Battery Anodes[J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1057-1066.

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