二维材料插层改性方法研究进展

doi:10.11944/j.issn.1000-0518.2020.08.200086

摘要/Abstract

摘要： 二维材料凭借其独特的电学、光学、磁学等性质引起了广泛关注,如何处理二维材料使其改性是目前的研究热点。插层方法是目前调控二维材料性质的主要方法之一。插层过程中,客体粒子插入主体材料的范德华层间,造成二维材料物理与化学性质的变化。气相、液相、固相插层均可以使二维材料的性质得到提升。本文主要介绍二维材料插层方法,分析其不同优势和限制条件,并展望如何综合应用插层方法更好地提升二维材料电学、光学等性能。

关键词: 二维材料, 插层方法, 插层化合物

Abstract: Two-dimensional (2D) materials have attracted widespread attention due to their unique electrical, optical, and magnetic properties, and how to modify two-dimensional materials is a research hotspot. The intercalation method is one of the main methods of improving the properties of 2D materials. During the intercalation process, guest particles are inserted between the van der Waals layers of the host material, causing changes in the physical and chemical properties of the 2D materials. Gas phase intercalation, liquid phase intercalation, and solid phase intercalation can improve properties of 2D materials. This article mainly introduces the intercalation methods of 2D materials, analyzes their advantages and drawbacks, and proposes how to apply intercalation methods to improve electrical, optical properties of 2D materials.

Key words: two-dimensional material, intercalation method, intercalation compound

王蕾, 宫勇吉. 二维材料插层改性方法研究进展[J]. 应用化学, 2020, 37(8): 855-864.

WANG Lei, GONG Yongji. Research Progress of Intercalation Methods of Two-Dimensional Materials[J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 855-864.

参考文献

[1] Novoselov K S,Geim A K,Morozov S V,et al. Electric Field Effect in Atomically Thin Carbon Films[J]. Science,2004,306(5696):666-669.
[2] Zhan D,Sun L,Ni Z H,et al. FeCl₃-Based Few-Layer Graphene Intercalation Compounds: Single Linear Dispersion Electronic Band Structure and Strong Charge Transfer Doping[J]. Adv Funct Mater,2010,20(20):3504-3509.
[3] Jung N,Kim B,Crowther A C,et al. Optical Reflectivity and Raman Scattering in Few-Layer-Thick Graphene Highly Doped by K and Rb[J]. ACS Nano,2011,5(7):5708-5716.
[4] Bao W,Wan J,Han X,et al. Approaching the Limits of Transparency and Conductivity in Graphitic Materials Through Lithium Intercalation[J]. Nat Commun,2014,5(1):1-9.
[5] Koski K J,Wessells C D,Reed B W,et al. Chemical Intercalation of Zerovalent Metals into 2D Layered Bi₂Se₃ Nanoribbons[J]. J Am Chem Soc,2012,134(33):13773-13779.
[6] Jung N,Kim N,Jockusch S,et al. Charge Transfer Chemical Doping of Few Layer Graphenes:Charge Distribution and Band Gap Formation[J]. Nano Lett,2009,9(12):4133-4137.
[7] Mashtalir O,Naguib M,Mochalin V N,et al. Intercalation and Delamination of Layered Carbides and Carbonitrides[J]. Nat Commun,2013,4(1):1-7.
[8] Stark M S,Kuntz K L,Martens S J,et al. Intercalation of Layered Materials from Bulk to 2D[J]. Adv Mater,2019,31(27):1808213.
[9] Whittingha S M. Intercalation Chemistry[M]. Elsevier,2012.
[10] Zhao W,Tan P,Zhang J,et al. Charge Transfer and Optical Phonon Mixing in Few-Layer Graphene Chemically Doped with Sulfuric Acid[J]. Phys Rev B,2010,82(24):245423.
[11] Falardeau E,Hanlon L,Thompson T. Direct Synthesis of Stage 1-3 Intercalation Compounds of Arsenic Pentafluoridein Graphite[J]. Inorg Chem,1978,17(2):301-303.
[12] Müller-Warmuth W,Schöllhorn R. Progress in Intercalation Research[M]. Springer Science & Business Media,2012.
[13] Eklund P,Kambe N,Dresselhaus G,et al. In-Plane Intercalate Lattice Modes in Graphite-Bromine Using Raman Spectroscopy[J]. Phys Rev B,1978,18(12):7069.
[14] Mansour A E,Dey S,Amassian A,et al. Bromination of Graphene:A New Route to Making High Performance Transparent Conducting Electrodes with Low Optical Losses[J]. ACS Appl Mater Interfaces,2015,7(32):17692-17699.
[15] Jung N,Crowther A C,Kim N,et al. Raman Enhancement on Graphene:Adsorbed and Intercalated Molecular Species[J]. ACS Nano,2010,4(11):7005-7013.
[16] Eklund P,Dresselhaus G,Dresselhaus M,et al. Raman Scattering from In-Plane Lattice Modes in Low-Stage Graphite-Alkali-Metal Compounds[J]. Phys Rev B,1977,16(8):3330.
[17] Nemanich R,Solin S,Guerard D. Raman Scattering from Intercalated Donor Compounds of Graphite[J]. Phys Rev B,1977,16(6):2965.
[18] Eklund P,Subbaswamy K. Analysis of Breit-Wigner Line Shapes in the Raman Spectra of Graphite Intercalation Compounds[J]. Phys Rev B,1979,20(12):5157.
[19] Boeri L,Bachelet G B,Giantomassi M,et al. Electron-Phonon Interaction in Graphite Intercalation Compounds[J]. Phys Rev B,2007,76(6):064510.
[20] Caswell N,Solin S. Vibrational Excitations of Pure FeCl₃ and Graphite Intercalated with Ferric Chloride[J]. Solid State Commun,1978,27(10):961-967.
[21] Underhill C,Leung S,Dresselhaus G,et al. Infrared and Raman Spectroscopy of Graphite-Ferric Chloride[J]. Solid State Commun,1979,29(11):769-774.
[22] Kim N,Kim K S,Jung N,et al. Synthesis and Electrical Characterization of Magnetic Bilayer Graphene Intercalate[J]. Nano Lett,2011,11(2):860-865.
[23] Zhao W,Tan P H,Liu J,et al. Intercalation of Few-Layer Graphite Flakes with FeCl₃:Raman Determination of Fermi Level, Layer by Layer Decoupling, and Stability[J]. J Am Chem Soc,2011,133(15):5941-5946.
[24] Hooley J,Bartlett M,Liengme B,et al. A Mossbauer Study of Graphite Iron Chloride Compounds[J]. Carbon,1968,6(5):681-685.
[25] Kanetani K,Sugawara K,Sato T,et al. Ca Intercalated Bilayer Graphene as a Thinnest Limit of Superconducting C₆Ca[J]. Proc Natl Acad Sci USA,2012,109(48):19610-19613.
[26] Sugawara K,Kanetani K,Sato T,et al. Fabrication of Li-Intercalated Bilayer Graphene[J]. AIP Adv,2011,1(2):022103.
[27] Koski KJ, ha J J,Reed B W,et al. High-Density Chemical Intercalation of Zero-Valent Copper into Bi₂Se₃ Nanoribbons[J]. J Am Chem Soc,2012,134(18):7584-7587.
[28] Xiong F,Wang H,Liu X,et al. Li Intercalation in MoS₂:In Situ Observation of Its Dynamics and Tuning Optical and Electrical Properties[J]. Nano Lett,2015,15(10):6777-6784.
[29] Gong Y,Yuan H,Wu C L,et al. Spatially Controlled Doping of Two-Dimensional SnS₂ Through Intercalation for Electronics[J]. Nat Nanotechnol,2018,13(4):294-299.
[30] Yang W,Xiao J,Ma Y,et al. Tin Intercalated Ultrathin MoO₃ Nanoribbons for Advanced Lithium-Sulfur Batteries[J]. Adv Energy Mater,2019,9(7):1803137.
[31] Chen K P,Chung F R,Wang M,et al. Dual Element Intercalation into 2D Layered Bi₂Se₃ Nanoribbons[J]. J Am Chem Soc,2015,137(16):5431-5437.
[32] Naguib M,Kurtoglu M,Presser V,et al. Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂[J]. Adv Mater,2011,23(37):4248-4253.
[33] Jung Y,Zhou Y,Cha J J. Intercalation in Two-Dimensional Transition Metal Chalcogenides[J]. Inorg Chem Front,2016,3(4):452-463.
[34] Luo W,Wan J,Ozdemir B,et al. Potassium Ion Batteries with Graphitic Materials[J]. Nano lett,2015,15(11):7671-7677.
[35] Wang C,He Q,Halim U,et al. Monolayer Atomic Crystal Molecular Superlattices[J]. Nature,2018,555(7695):231-236.
[36] Oakes L,Carter R,Hanken T,et al. Interface Strain in Vertically Stacked Two-Dimensional Heterostructured Carbon-MoS₂ Nanosheets Controls Electrochemical Reactivity[J]. Nat Commun,2016,7:11796.
[37] Winter M,Besenhard J O,Spahr M E,et al. Insertion Electrode Materials for Rechargeable Lithium Batteries[J]. Adv Mater,1998,10(10):725-763.
[38] Hui J,Burgess M,Zhang J,et al. Layer Number Dependence of Li⁺ Intercalation on Few-Layer Graphene and Electrochemical Imaging of Its Solid-Electrolyte Interphase Evolution[J]. ACS Nano,2016,10(4):4248-4257.
[39] Lin Z,Liu Y,Halim U,et al. Solution-Processable 2D Semiconductors for High-Performance Large-Area Electronics[J]. Nature,2018,562(7726):254-258.
[40] Yu W,Li J,Herng T S,et al. Chemically Exfoliated VSe₂ Monolayers with Room-Temperature Ferromagnetism[J]. Adv Mater,2019,31(40):e1903779.
[41] Hor Y S,Checkelsky J G,Qu D,et al. Superconductivity and Non-Metallicity Induced by Doping the Topological Insulators Bi₂Se₃ and Bi₂Te₃[J]. J Phys Chem Solids,2011,72(5):572-576.
[42] Bediako D K,Rezaee M,Yoo H,et al. Heterointerface Effects in the Electrointercalation of Van Der Waals Heterostructures[J]. Nature,2018,558(7710):425-429.