中华医学超声杂志

应用化学 ›› 1992, Vol. 0 ›› Issue (4): 78-80.

• 研究简报 • 上一篇    下一篇

稀土三氟醋酸盐与邻菲罗啉配合物的合成

董南, 朱龙观   

  1. 杭州大学化学系, 杭州 310028
  • 收稿日期:1991-04-24 修回日期:1991-10-15 出版日期:1992-08-10 发布日期:1992-08-10
  • 基金资助:
    国家自然科学基金

SYNTHESIS OF COMPLEXES OF 1,10-PHENANTHROLINE WITH RARE EARTH TRIFLUOROACETATE

Dong Nan, Zhu Longguan   

  1. Department of Chemistry, Hangzhou University , Hangzhou 310028
  • Received:1991-04-24 Revised:1991-10-15 Published:1992-08-10 Online:1992-08-10

PDF

345

被引次数

1

摘要： 稀土三氟醋酸盐与双齿杂环胺形成的配合物报道不多。Heller[1]在乙醇中合成了Nd(CF3COO)3Phen(Phen为邻菲罗啉)并用作激光材料;Singh等[2]报道了在乙酸乙酯和苯溶剂中Ln(CF3COO)3(Pheh)的合成和性质;Zhou Jialie等[3]报道了Ln(CF3COO)3(Pheh)。

关键词: 稀土, 三氟醋酸, 邻菲罗啉, 配合物, 合成

Abstract: Five complexes of 1,10-phenanthroline with rare earth trifluoroacetate were prepared from water-organic solvents. The complexes have been characterized by elemental analysis, infrared spectra, UV spectra, conductivity measurements, X-ray powder patterns and thermal analysis and are found to have following constitution:Ln(CF3COO)3(Phen)4·nH2O(Ln=La、Pr, Nd, Sm, Er).

Key words: rare earth, trifluoroacetic acid, phenanthroline, complex, synthesis

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