应用化学 ›› 2022, Vol. 39 ›› Issue (6): 927-940.DOI: 10.19894/j.issn.1000-0518.210386

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电解海水析氢反应过渡金属基催化剂的研究进展

王岩, 张树聪, 汪兴坤, 刘志承, 王焕磊, 黄明华()   

  1. 中国海洋大学材料科学与工程学院,青岛 266100
  • 收稿日期:2021-07-31 接受日期:2021-11-23 出版日期:2022-06-01 发布日期:2022-06-27
  • 通讯作者: 黄明华
  • 基金资助:
    国家自然科学基金(21775142);山东省自然科学基金(ZR2020ZD10)

Research Progress on Transition Metal⁃Based Catalysts for Hydrogen Evolution Reaction via Seawater Electrolysis

Yan WANG, Shu-Cong ZHANG, Xing-Kun WANG, Zhi-Cheng LIU, Huan-Lei WANG, Ming-Hua HUANG()   

  1. School of Materials Science and Engineering,Ocean University of China,Qingdao 266100,China
  • Received:2021-07-31 Accepted:2021-11-23 Published:2022-06-01 Online:2022-06-27
  • Contact: Ming-Hua HUANG
  • About author:huangminghua@ouc.edu.cn
  • Supported by:
    the National Natural Science Foundation of China(21775142);the Natural Science Foundation of Shandong Province(ZR2020ZD10)

摘要:

海水作为地球上最丰富的自然资源之一,在实现大规模的电解水制氢方面具有得天独厚的优势。然而,海水中的Cl-、Ca2+和Mg2+等使催化剂在阴极发生腐蚀、毒化或降解,导致其稳定性、活性以及使用寿命显著降低。近年来,为了解决上述问题,人们致力于设计开发廉价的高效稳定析氢反应(HER)催化剂,进而提高电解海水制氢效率。本文首先介绍了电解海水的优势及其HER所面临的挑战,其次从活性和稳定性等方面重点论述了硒化物、硫化物、氮化物以及磷化物等过渡金属基催化剂在电解海水HER中的研究进展,最后总结和展望了电解海水HER催化剂未来的发展前景。

关键词: 海水, 电催化, 析氢反应, 过渡金属基催化剂

Abstract:

As one of the most abundant natural resources on earth, seawater has unique advantages in realizing large-scale hydrogen production from electrochemical water splitting. However, the catalysts at the cathode could be corroded, poisoned or degraded by Cl, Ca2+ and Mg2+ in seawater, resulting in a significant reduction in their activity and stability. Therefore, the development of cheap, efficient and stable electrocatalysts for hydrogen evolution reaction (HER) on the cathode has attracted intense attention. This review firstly elaborates the major advantages and challenges for hydrogen production from seawater electrolysis. Afterwards, the research progress on transition metal-based HER catalysts for seawater electrolysis, such as selenides, sulfides, phosphates, nitrides and so on, is summarized and discussed. Finally, the future perspectives in the design of efficient and stable HER catalysts for seawater electrolysis are summarized and put forward.

Key words: Seawater, Electrocatalysis, Hydrogen evolution reaction, Transition metal-based catalysts

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