中华医学超声杂志

应用化学

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超分子凝胶在催化有机反应中的应用

许杨1,2,康传清1*,高连勋1*,孟庆新2   

  1. (1.中国科学院长春应用化学研究所 长春 130022；2.长春工业大学高分子材料系 长春 130022)
  • 收稿日期:2012-05-03 修回日期:2012-06-26 出版日期:2013-01-10 发布日期:2013-01-10
  • 通讯作者: 康传清，副研究员; Tel:0431-85262291; Fax:0431-85262926; E-mail:kangcq@ciac.jl.cn; 研究方向：有机合成，超分子自组装材料

Applications of Supramolecular Gels in Catalyzing Organic Reactions

XU Yang1,2, KANG Chuanqing1*, GAO Lianxun1*, MENG Qingxin2   

  1. (1.Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;
    2.Department of Polymer Materials,Changchun University of Technology,Changchun 130022,China)
  • Received:2012-05-03 Revised:2012-06-26 Published:2013-01-10 Online:2013-01-10

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2141

被引次数

3 | 1

摘要： 超分子凝胶是有机小分子通过分子间非共价作用形成的使溶剂固定的三维网络结构胶体。 综述关注了近年来超分子凝胶在催化有机反应中一个新的应用方向，依据凝胶剂结构特征和催化反应的类型对迄今报道的小分子凝胶催化剂进行了深入的总结与归类，揭示凝胶催化的独特性，并对其存在的问题和发展趋势进行了讨论。

关键词: 超分子凝胶, 催化, 自组装

Abstract: Supramolecular gels are the self-assembly of low molecular-mass organic gelators through non-bonding interactions to form a 3D entangled fiberous network which immobilizes liquids. This paper reviewed the application of supramolecular gels for catalyzing organic reactions which is a new extended application of supramolecular gels. Recent development of using supromolecular gels as catalysts was summarized and classified according to the gelator structures and reaction types, and particular attentions were given to the unique features of catalysis by the supramolecular system. The challenges and perspectives in this field were discussed.

Key words: supramolecular gels, catalysis, self-assembly

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