中华医学超声杂志

应用化学 ›› 1996, Vol. 0 ›› Issue (6): 75-77.

• 研究简报 • 上一篇    下一篇

(Et4N)m·M(dmit)2型配合物的合成及其红外光谱

李洪启, 王爱勤, 宋燕西, 谭干祖, 姚钟麒, 俞贤达   

  1. 中国科学院兰州化学物理研究所 兰州 730000
  • 收稿日期:1996-02-16 修回日期:1996-05-20 出版日期:1996-12-10 发布日期:1996-12-10

Synthesis and Characterization of Organometallic Complexes(Et4N)m·M(dmit)2

Li Hongqi, Wang Aiqin, Song Yanxi, Tan Ganzu, Yao Zhongqi, Yu Xianda   

  1. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
  • Received:1996-02-16 Revised:1996-05-20 Published:1996-12-10 Online:1996-12-10

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摘要： 由二(1,3-二硫杂环戊烯-2-硫酮-4,5-二琉基)金属(M(dmit)2)制备的有机导体往往可形成二维结构的分列柱,分子间库仑斥力减小,金属性得到稳定.

关键词: 二(二硫杂环戊烯硫酮二巯基)金属, 配合物, 合成, 红外光谱

Abstract: A new type of tetraethylammonium-bis(1,3-dithiole-2-thione-4,5-dithiolate) metal complexes((Et4N)m·M (dmit)2) was synthesized,three of which(M=Mn,Co,Sn) were reported for the first time.The complexes were characterized by elemental analysis,ICP and 1H NMR spectra.The infrared and ultraviolet spectra of the complexes were also measured and discussed.

Key words: bis(dithiole-thione-dithiolate) metal, complex, synthesis, infrared spectrum

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