应用化学 ›› 1988, Vol. 0 ›› Issue (6): 1-10.

• 综述 •    下一篇

鲜味剂和咸味剂的结构化学兼论与其它味道间的相互作用和转化

曾广植   

  1. 中国科学院上海有机化学研究所
  • 收稿日期:1988-03-21 修回日期:1988-05-20 出版日期:1988-12-10 发布日期:1988-12-10

STRUCTURAL CHEMISTRY OF UMAMI AND SALTY TASTANTS IN ADDITION TO A DISCUSSION ON THEIR INTERRELATION AND TRANSFORMATION TO OTHER TASTANTS

Zeng Guangzhi(Tseng Kuang-chih)   

  1. Shanghai Institute of Organic Chemistry, Academia Sinica
  • Received:1988-03-21 Revised:1988-05-20 Published:1988-12-10 Online:1988-12-10

摘要:

味觉是动物为适应其内在新陈代谢的需求而形成的对外界食物信息感的天性之一。鲜咸甜感为食诱信息;苦涩辣感为拒食信息;酸感因时、地、主、客情况不同而属前者或后者。基本呈味分子的结构特征是:首先它们应有极性始能为与其极性相对应的味受体所吸引,这一化学现象,可用Lewis酸A、碱B表示。酸者为可离解之酸性物HA;苦者多属可极化性及共价键性均强之碱性物B;咸者乃强离子性中性盐A+-B-。估计酸受体正负极间距离最短;咸受体B′--A′+间约相距4.84—6.56Å。甜者多属带共价键性之两性物A-B或AH-B,相距约2.8-5.4Å。估计苦受体系高焓脂质洞穴,故苦者无正负极距要求,仅需有较强可极化性。这些生味基结构可与一疏水部分C结合,C多为增强味感的助味组份。鲜者则可认为系咸甜两种结构要素相结合所产生的另一种味结构A+B-(C1-9)AH-B。本文介绍咸味及鲜味分子的结构化学。

关键词: 酸, 苦, 咸, 甜, 鲜, 结构化学

Abstract:

Gustation is an animal sense of feeling the urge of internal metabolism in response to its environmental food messages. It is one of the instincts formed through the selective process in nature for survival struggles. Umami, saltiness and sweetness are signal of food attractart while bitterness, astringency and pungency are those of food repellent. Sourness can be either one contingent upon the time and place of the subject and/or the object. Feature structures of basic tastants are as follows: First of all they must be polarized 2such that they can be attracted by the corresponding receptors of opposite polarity. As these interactions are a chemical phenomenon, Lewis'generalized idea of acid A and base B may be employed to epitomize the structure high lights of different tastant molecules. Sour molecules are acidic ionizable compounds represented as HA and bitter molecules are basic ones often of a covalent nature readily polarizable, assigned here as B. Salty molecules are neutral salts A+ B- of high ionic character and the sweet tastants arc amphoterie compounds with covalent character A-B or AH-B. These formulae stand for the essential sapophoric groups with whicha hydrophobic part C may be attached and may serves as an auxosapophorie moiety. Umami molecules may te regarded as a structural combination of the latter two essences A+B--(C1-9)AH-B to form an entirely new tastant. The structrual chemistry of salty and umami molecules are then especially introduced in this paper.

Key words: Sourness, Bitterness, Saltinnss, Sweetness, Umami, Structure-chemistry