应用化学

• 研究论文 • 上一篇    下一篇

石蜡相变微胶囊的制备与表征

刘先之,刘凌志,门永锋*   

  1. (中国科学院长春应用化学研究所,高分子物理与化学国家重点实验室 长春 130022)
  • 收稿日期:2011-02-28 修回日期:2011-03-30 出版日期:2012-01-10 发布日期:2012-01-10
  • 通讯作者: 门永锋,研究员; Tel:0431-85262907; Fax:0431-85262954; E-mail:men@ciac.jl.cn; 研究方向:高分子物理

SSynthesis and Characterization of Chitosan/paraffin Phase Change Microcapsules

LIU Xianzhi, LIU Lingzhi, MEN Yongfeng*   

  1. (State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of
    Applied Chemistry,Chinese Academy of Sciences,Changchun 130022)
  • Received:2011-02-28 Revised:2011-03-30 Published:2012-01-10 Online:2012-01-10
  • Contact: MEN Yongfeng

摘要:

采用复乳交联法制备了以相变石蜡为芯材、壳聚糖为壁材的新型储能相变微胶囊。 此相变微胶囊具有很高的相变焓值(可达110 J/g以上),并且可以根据具体需要改变芯材的温度;TGA研究表明,该相变微胶囊具有很好的热稳定性,在150 ℃以下可以稳定存在;由于壳材料进行了化学交联反应,使得该相变微胶囊具有很好溶剂稳定性,可以在水、乙醇和乙醚等常见溶剂中稳定存在。

关键词: 微胶囊, 相变材料, 石蜡, 壳聚糖

Abstract:

Phase change microcapsules were synthesized using chitosan as the shell material and paraffin as the core material via multi-emulsionization and cross-linking method. During the phase change of the paraffin, the microcapsules can store and release energy. The enthalpy value of the phase change of the microcapsules is higher than 110 J/g. The suitable phase change temperature can be obtained by changing the core material. The resultant microcapsules show excellent thermal stability, and remain stable below 150 ℃ as demonstrated by TGA measurement. The microcapsules also exhibit good solvent-resistance because of the cross-linking between chitosan and glutaraldehyde.

Key words: microcapsules, phase change material, paraffin, chitosan

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