应用化学 ›› 2010, Vol. 27 ›› Issue (11): 1359-1361.DOI: 10.3724/SP.J.1095.2010.90885

• 研究简报 • 上一篇    下一篇

甲苯对水/AOT/醇反相微乳液体系电导行为的影响

张海礁1,刘洁翔1,张晓光2*,韩恩山1   

  1. (1.河北工业大学化工学院 天津;2.南开大学化学学院 天津 300071)
  • 出版日期:2010-11-10 发布日期:2010-11-10
  • 通讯作者: 张晓光,男,讲师; E-mail:xgzhang@nankai.edu.cn; 研究方向:胶体与界面化学及其应用
  • 基金资助:
    天津市自然科学基金(08JCYBJC00700)资助项目

The Influence of Toluene on Conductivity Behavior of Water/AOT/Alkanol Reverse Microemulsions

ZHANG Hai-Jiao1, LIU Jie-Xiang1, ZHANG Xiao-Guang2*, HAN En-Shan1   

  1. (1.College of Chemical Engineering,Hebei University of Technology,Tianjin;
    2.College of Chemistry,Nankai University,Tianjin 300071)
  • Published:2010-11-10 Online:2010-11-10

摘要:

采用电导法研究了以二(2-乙基己基)琥珀酸酯磺酸钠(AOT)为表面活性剂、庚醇和癸醇分别与甲苯的混合溶剂为油相的反相微乳液体系在有无添加剂氯化钠时的电导行为。 结果表明,甲苯对水/AOT/癸醇体系电导渗滤有明显的抑制作用,而对水/AOT/庚醇体系没有影响;添加氯化钠对水/AOT/庚醇(癸醇)/甲苯体系的电导率基本无影响。

关键词: 醇, 甲苯, 渗滤, 二(乙基己基)琥珀酸酯磺酸钠, 添加剂

Abstract:

The conductivity behaviors of water-in-toluene-alkanol(heptanol, decanol) reverse microemulsions stabilized solely by sodium bis(2-ethylhexyl) sulfosuccinate(AOT) with and without the additives(sodium chloride) were investigated through conductance measurements. The results showed that the percolation phenomenon was apparently inhibited by toluene in the water/AOT/decanol system, while no effect in the water/AOT/heptanol system. The conductance of water/AOT/heptanol/toulene and water/AOT/decanol/toulene systems had a hardly change in the present of sodium chloride.

Key words: alkanol, toluene, percolation, bis(ethylhexyl) sulfosuccinate, additives

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