Research Progress of Nanomaterial Sensors in the Detection of Organophosphorus Pesticide Residues

doi:10.19894/j.issn.1000-0518.230293

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (4): 472-483.DOI: 10.19894/j.issn.1000-0518.230293

Research Progress of Nanomaterial Sensors in the Detection of Organophosphorus Pesticide Residues

Kong-Hao PENG¹, An-Qi BAI¹, Ying MENG¹, Hui YIN¹, Xin-Yao SU¹, Jin-Yu YANG¹, Shu-Rong LI¹^,², Ling-Yan ZHANG¹^,², Li-Xia LUO¹^,²(), Pei-Jun MENG¹^,²()

^1.School of Public Health，Baotou Medical College，Baotou 014040，China
^2.Inner Mongolia Autonomous Region Health Testing and Evaluation Engineering Technology Center，Baotou 014040，China

Received:2023-09-25 Accepted:2024-01-25 Published:2024-04-01 Online:2024-04-28
Contact: Li-Xia LUO,Pei-Jun MENG
About author:mengpeijun79@163.com；
luoluo_80@yeah.net
Supported by:
the National Natural Science Foundation of China(81960601);the Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region(NJYT23026);the Provincial Natural Science Foundation of Inner Mongolia Autonomous Region(2023MS08009);the Medical and Health Technology Plan Project of Health Commission of Inner Mongolia Autonomous Region(202201383);the College Students' Innovative Entrepreneurial Training Plan Program of Inner Mongolia Autonomous Region in 2023(S202310130001)

Abstract

Abstract:

Organophosphorus pesticides （OPs）， as one of the most toxic pesticides， have the characteristics of wide use， large usage and great harm to human health. With people's longing and continuous pursuit of a healthy life， it is particularly urgent and important to build accurate， sensitive， convenient and fast OPs residual analysis and detection sensor. Because of the unique optical， electrochemical and biological properties of nanomaterials， OPs detection sensors based on nanomaterials have the advantages of sensitivity， high efficiency and economy. In this paper， the domestic and foreign sensors for detecting OPs residues based on rare earth doped upconversion nanomaterials， metal nanomaterials， metal oxide nanomaterials， carbon nanomaterials and quantum dot nanomaterials from 2015 to 2023 are reviewed， providing ideas and basis for the subsequent development of nanomaterial-based OPs multi residue detection sensors.

Key words: Nanomaterials, Organophosphorus pesticides, Residues, Sensors

CLC Number:

O652

Kong-Hao PENG, An-Qi BAI, Ying MENG, Hui YIN, Xin-Yao SU, Jin-Yu YANG, Shu-Rong LI, Ling-Yan ZHANG, Li-Xia LUO, Pei-Jun MENG. Research Progress of Nanomaterial Sensors in the Detection of Organophosphorus Pesticide Residues[J]. Chinese Journal of Applied Chemistry, 2024, 41(4): 472-483.

Figures/Tables 6

References 55

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Nanomaterials matrix	Sensor type	Advantage	Disadvantage	The development trend
Rare earth doped upconversion nanomaterial	Fluorescence sensor	High sensitivity， good stability， simple sample pretreatment， real-time monitoring， with visualization	Need specific band light source irradiation excitation， detection scene is limited； The anti-interference ability of some fluorescence sensors needs to be enhanced	The nucleic acid aptamer， antigen and antibody with strong specificity were used to improve the specificity and anti-interference ability and realize the simultaneous detection of multiple residual targets
Metallic nanomaterial	Surface enhanced raman scattering sensor， colorimetric sensor， electrochemical sensor	High sensitivity， good stability， simple sample preparation， the sensitive electrochemical sensor is efficient， rapid detection	The anti-interference ability of some sensors needs to be enhanced， and the related sensors using the principle of enzyme inhibition can only detect the total amount of organophosphorus pesticides， and cannot achieve accurate detection of single residue	Using the characteristics of its own materials and other materials to construct a composite sensor， further improve the detection sensitivity， repeatability and anti-interference ability of the sensor
Metal oxide nanomaterial	Electrochemical sensor， surface enhanced raman scattering sensor， spectrophotometer sensor	Wide detection linear range， high sensitivity， high efficiency， low cost， can be used in the field of rapid detection， metal oxide properties， can be used in a variety of sensors	The anti-interference ability needs to be strengthened， the related sensors using the principle of enzyme inhibition cannot realize the simultaneous detection of multiple residues， and the repeatability needs to be improved	The composite sensor is constructed by using the characteristics of its own material and other materials， and the unique properties of the matrix material are fully utilized to optimize the performance of the sensor
Carbon nanomaterials	Electrochemical sensor， colorimetric sensors	High sensitivity， strong stability， portable， can realize the field rapid detection.	The related sensor based on the principle of enzyme inhibition can not realize the simultaneous detection of multiple residues， and the repeatability needs to be improved	The stability and modifiability of the material combined with other materials are utilized to further improve the sensor's specificity and multi-residue detection capability
Quantum dot nanomaterials	Photoelectric chemical sensor， Fluorescence sensor	High sensitivity， good stability， strong anti-interference ability	Some quantum dot composites are potentially toxic； Some sensors have poor specificity	Low-toxic or non-toxic quantum dots are used to build sensors and composite with other materials to improve sensor detection performance

Nanomaterials matrix	Sensor type	Advantage	Disadvantage	The development trend
Rare earth doped upconversion nanomaterial	Fluorescence sensor	High sensitivity， good stability， simple sample pretreatment， real-time monitoring， with visualization	Need specific band light source irradiation excitation， detection scene is limited； The anti-interference ability of some fluorescence sensors needs to be enhanced	The nucleic acid aptamer， antigen and antibody with strong specificity were used to improve the specificity and anti-interference ability and realize the simultaneous detection of multiple residual targets
Metallic nanomaterial	Surface enhanced raman scattering sensor， colorimetric sensor， electrochemical sensor	High sensitivity， good stability， simple sample preparation， the sensitive electrochemical sensor is efficient， rapid detection	The anti-interference ability of some sensors needs to be enhanced， and the related sensors using the principle of enzyme inhibition can only detect the total amount of organophosphorus pesticides， and cannot achieve accurate detection of single residue	Using the characteristics of its own materials and other materials to construct a composite sensor， further improve the detection sensitivity， repeatability and anti-interference ability of the sensor
Metal oxide nanomaterial	Electrochemical sensor， surface enhanced raman scattering sensor， spectrophotometer sensor	Wide detection linear range， high sensitivity， high efficiency， low cost， can be used in the field of rapid detection， metal oxide properties， can be used in a variety of sensors	The anti-interference ability needs to be strengthened， the related sensors using the principle of enzyme inhibition cannot realize the simultaneous detection of multiple residues， and the repeatability needs to be improved	The composite sensor is constructed by using the characteristics of its own material and other materials， and the unique properties of the matrix material are fully utilized to optimize the performance of the sensor
Carbon nanomaterials	Electrochemical sensor， colorimetric sensors	High sensitivity， strong stability， portable， can realize the field rapid detection.	The related sensor based on the principle of enzyme inhibition can not realize the simultaneous detection of multiple residues， and the repeatability needs to be improved	The stability and modifiability of the material combined with other materials are utilized to further improve the sensor's specificity and multi-residue detection capability
Quantum dot nanomaterials	Photoelectric chemical sensor， Fluorescence sensor	High sensitivity， good stability， strong anti-interference ability	Some quantum dot composites are potentially toxic； Some sensors have poor specificity	Low-toxic or non-toxic quantum dots are used to build sensors and composite with other materials to improve sensor detection performance

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Research Progress of Nanomaterial Sensors in the Detection of Organophosphorus Pesticide Residues

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