Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (4): 554-561.DOI: 10.19894/j.issn.1000-0518.220302

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Study on Extraction Separation of NN-Dimethylformamide with Chloroform

Fei-Yue CHEN1,2, Zhen-Ning SU2, Quan-Zhong CHENG2, Bo-Ren TAN2, Zhi-Yong LI3, Xiao-Hua YU1(), Yong WANG2()   

  1. 1.Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Kunming 650093,China
    2.CAS Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China
    3.the Fourth Construction Co. Ltd. of China Electronics System Engineering,Shijiazhuang 050051,China
  • Received:2022-09-08 Accepted:2023-02-07 Published:2023-04-01 Online:2023-04-17
  • Contact: Xiao-Hua YU,Yong WANG
  • About author:wangyong@ipe.ac.cn
    85208478@qq.com
  • Supported by:
    the National Natural Science Foundation of China(22178350);the National Key R&D Program of China(2019YFC1907700);Yunnan Ten Thousand Talents Plan Young & Elite Talents Project(YNWR-QNBJ-2018-327)

Abstract:

The separation and recovery of NN-dimethylformamide (DMF) from the liquid containing high mass fraction of DMF is studied by continuous extraction in a pulsed disc and doughnut extraction column (PDDC), which combines with a distillation process. For the feed liquid with 38.46% DMF, chloroform is used as the extraction agent and DMF is extracted in a PDDC. The effects of the extraction operation parameters such as oil-water ratio, flow rate and pulse conditions on the DMF extraction are studied. The results show that the extraction efficiency of DMF increases with the addition of pulsation, the increase of oil-water ratio and the increase of two phase flow rate. Under the optimized conditions, the highest extraction ratio of DMF ias 99.94%, and the DMF mass fraction in raffinate is less than 0.5%. Furthermore, batch distillation experiments and simulation calculations are carried out for the separation of chloroform solution loaded with DMF. The results show that effective separation and recovery of chloroform and DMF can be achieved through continuous distillation.

Key words: N, N-Dimethylformamide, Chloroform, Disc and doughnut extraction column, Distillation

CLC Number: