Recent Advances in Application of Metal-Organic Frameworks for Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane

doi:10.19894/j.issn.1000-0518.220205

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (3): 329-340.DOI: 10.19894/j.issn.1000-0518.220205

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Recent Advances in Application of Metal-Organic Frameworks for Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane

Bing LI, Jun-Hui LIU(), Ya-Kun SONG, Xiang LI(), Xu-Ming GUO, Jian XIONG

College of Chemistry and Chemical Engineering，Henan University of Science and Technology，Luoyang 471023，China

Received:2022-06-28 Accepted:2022-11-16 Published:2023-03-01 Online:2023-03-27
Contact: Jun-Hui LIU,Xiang LI
About author:lixiang@haust.edu.cn
junhuil@haust.edu.cn；
Supported by:
the National Natural Science Foundation of China(21908043);the Key Project of Henan Province(222102320314);the Key Scientific Research Projects of Higher Education Institutions in Henan Province, China(22A150011)

Abstract

Abstract:

The growing demand for energy is driving the development of renewable and efficient energy materialsdue to the high consumption of fossil fuels. Hydrogen is considered as a potential energy carrier because of its abundant earth sources and clean burning. The preparation of clean and renewable hydrogen by hydrolyzing ammonia borane is one of the effective ways to solve energy problems. The development of efficient and safe catalysts has been the focus and hotspot in this field. Metal-organic framework materials （MOFs） are widely used in ammonia borane hydrolysis for hydrogen production due to their unique structural composition. This paper focuses on the role of MOFs materials in catalyst preparation and summarizes the role of different MOFs materials in catalytic hydrogen production by ammonia borane hydrolysis. In addition， the current problems are summarized and the future development of this field is pointed out.

Key words: Metal-organic framework, Ammonia borane, Hydrogen generation, Catalysts

CLC Number:

O643.3

Bing LI, Jun-Hui LIU, Ya-Kun SONG, Xiang LI, Xu-Ming GUO, Jian XIONG. Recent Advances in Application of Metal-Organic Frameworks for Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane[J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 329-340.

Figures/Tables 5

References 86

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Num	Catalysts	Approaches to application	TOF/（mol?mol^-1?min^-1）	E_a/（kJ?mol^-1）	Ref.
1	AuNi@MIL-101	a	66.2	-	［37］
2	Cu₂Ni₁@MIL-101	a	20.9	32.2	［38］
3	AuCo@MIL-101	a	23.5	-	［39］
4	RuCuCo@MIL-101	a	241.2	48	［40］
5	Cu₈Ni₁Co₁@MIL-101	a	72.1	29.1	［41］
6	1.62wt%Ru@MIL-101	a	144	-	［42］
7	Co/MIL-101-2	a	4.5	-	［43］
	Co/MIL-101-2-U	a	9.9	-	［43］
	Co/MIL-101-1	a	22.3	-	［43］
	Co/MIL-101-1-U	a	51.4	31.3	［43］
8	CuCo@MIL-101	a	19.6	-	［44］
9	Ru₁Co₁@MIL-96	a	320.7	36.0	［45］
10	Ru/MIL-96	a	231	47.7	［46］
11	Ru@MIL-53（Cr）	a	260.8	28.9	［47］
	Ru@MIL-53（Al）	a	266.9	33.7	［47］
12	CuPd_0.01@ZIF-67@ZIF-8	b	30.15	28.78	［48］
13	cZIF-67_μm	b	13.5	-	［49］
	cZIF-67_nm	b	13.2	-	［49］
14	Rh₂₅Co₇₅@ZIF-67	a	100.21	-	［50］
15	ZIF-67@Co	a	112.3	25.68	［51］
16	Cu_0.5@Co_0.5-MOF/5	b	129.8	26.5	［52］
17	fcc-Ni/C	b	2.10	40.15	［53］
	Hcp-Ni/C	b	4.32	35.49	［53］
	Hcp-CuNi/C	b	22.64	29.92	［53］
18	Co-MOF-74	a	22（h^-1）	-	［54］
	Co/Zn-MOF-74	a	176.5（h^-1）	32.8	［54］
19	Pd@Co@MIL-101	a	51	22	［55］
20	Ag-doped Ni/MIL-101	b	20.2	25	［56］
21	Co/NC-50	b	7.6	44.9	［57］
22	NiCo-NC	b	35.2	43.6	［58］
23	Ni_0.66Co_0.19P_0.15/OPC-300	b	95.24	38.9	［59］
24	Co-CoO _x @NCS-II	a	-	46.37	［60］
25	Pt/MIL-101	b	446.4	40.7	［61］
26	Co₄N-Co₃O₄	b	79	-	［62］
27	Cu@Ni₆-MOF	b	69.1	31.6	［63］
28	PdCo@NCHP	b	470.57	36.9	［64］

Num	Catalysts	Approaches to application	TOF/（mol?mol^-1?min^-1）	E_a/（kJ?mol^-1）	Ref.
1	AuNi@MIL-101	a	66.2	-	［37］
2	Cu₂Ni₁@MIL-101	a	20.9	32.2	［38］
3	AuCo@MIL-101	a	23.5	-	［39］
4	RuCuCo@MIL-101	a	241.2	48	［40］
5	Cu₈Ni₁Co₁@MIL-101	a	72.1	29.1	［41］
6	1.62wt%Ru@MIL-101	a	144	-	［42］
7	Co/MIL-101-2	a	4.5	-	［43］
	Co/MIL-101-2-U	a	9.9	-	［43］
	Co/MIL-101-1	a	22.3	-	［43］
	Co/MIL-101-1-U	a	51.4	31.3	［43］
8	CuCo@MIL-101	a	19.6	-	［44］
9	Ru₁Co₁@MIL-96	a	320.7	36.0	［45］
10	Ru/MIL-96	a	231	47.7	［46］
11	Ru@MIL-53（Cr）	a	260.8	28.9	［47］
	Ru@MIL-53（Al）	a	266.9	33.7	［47］
12	CuPd_0.01@ZIF-67@ZIF-8	b	30.15	28.78	［48］
13	cZIF-67_μm	b	13.5	-	［49］
	cZIF-67_nm	b	13.2	-	［49］
14	Rh₂₅Co₇₅@ZIF-67	a	100.21	-	［50］
15	ZIF-67@Co	a	112.3	25.68	［51］
16	Cu_0.5@Co_0.5-MOF/5	b	129.8	26.5	［52］
17	fcc-Ni/C	b	2.10	40.15	［53］
	Hcp-Ni/C	b	4.32	35.49	［53］
	Hcp-CuNi/C	b	22.64	29.92	［53］
18	Co-MOF-74	a	22（h^-1）	-	［54］
	Co/Zn-MOF-74	a	176.5（h^-1）	32.8	［54］
19	Pd@Co@MIL-101	a	51	22	［55］
20	Ag-doped Ni/MIL-101	b	20.2	25	［56］
21	Co/NC-50	b	7.6	44.9	［57］
22	NiCo-NC	b	35.2	43.6	［58］
23	Ni_0.66Co_0.19P_0.15/OPC-300	b	95.24	38.9	［59］
24	Co-CoO _x @NCS-II	a	-	46.37	［60］
25	Pt/MIL-101	b	446.4	40.7	［61］
26	Co₄N-Co₃O₄	b	79	-	［62］
27	Cu@Ni₆-MOF	b	69.1	31.6	［63］
28	PdCo@NCHP	b	470.57	36.9	［64］

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Recent Advances in Application of Metal-Organic Frameworks for Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane

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