Metal-Organic Framework-Based Anti-icing Coatings: Synthesis and Their Properties

doi:10.19894/j.issn.1000-0518.200327

Chinese Journal of Applied Chemistry ›› 2021, Vol. 38 ›› Issue (7): 800-806.DOI: 10.19894/j.issn.1000-0518.200327

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Metal-Organic Framework-Based Anti-icing Coatings: Synthesis and Their Properties

ZHANG Yi-Fan¹, SHI Yan-Dong^2*, GUO Hao¹, GAO Jian¹, WEI Wei¹, LIU Mei-Hua¹, ZHENG Chun-Bai¹, WANG Bo-Wei³, DENG Peng-Yang¹

¹CAS Key Laboratory of High-perfomance Synthetic Rubber and Its Composite Materials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
²Aero Engine Corporation of China, Changchun Control Technology Co., LTD., Changchun 130000, China
³Guangdong Hudian Cushion Materials Technology Co., LTD., Foshan 528200, China

Received:2020-11-02 Accepted:2021-01-14 Published:2021-07-01 Online:2021-09-01
About author:National Natural Science Foundation of China (No.51803208) and Foshan Science and Technology Innovation Project (No.2016IT100082)

Abstract

Abstract: In this paper, a MOF-based anti-icing coating was prepared by in situ synthesis of the silicone oil lubricating layer on the UiO-66-NH₂ coating via click reaction. The amount of silicone oil on surface wastuned by reaction time. The anti-icing performance of the oil-grafted MOF coatings (OGMCs) with different amounts of silicone oil was investigated. The surface morphology and composition were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectrometer (FT-IR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and contact goniometer. The results show that silicone oil is successfully synthesized and covalently bond to MOF. The OGMCs keep the original micro-nanostructures of MOF coating, as well as the crystal structure of UiO-66. The amount of silicone oil on OGMC increases with reaction time, however, the ice nucleation temperature and ice adhesion decreases first and then increases when the reaction time increases. The anti-icing performance of MOF coating is closely related with the amount of silicone oil. The anti-icing performance of OGMC is optimized when the reaction time is 12~18 h and the molar ratio of Si to Zr is 8~12. The ice nucleation temperature reaches -29.6 ℃ and the ice adhesion reaches 8.8 kPa.

Key words: Metal-organic framework, Anti-icing, Lubricating, Micro-nanostructures

CLC Number:

O633

ZHANG Yi-Fan, SHI Yan-Dong, GUO Hao, GAO Jian, WEI Wei, LIU Mei-Hua, ZHENG Chun-Bai, WANG Bo-Wei, DENG Peng-Yang. Metal-Organic Framework-Based Anti-icing Coatings: Synthesis and Their Properties[J]. Chinese Journal of Applied Chemistry, 2021, 38(7): 800-806.

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Metal-Organic Framework-Based Anti-icing Coatings: Synthesis and Their Properties

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