Syntheses, Crystal Structures and Magnetic Properties of a 2D Cobalt(Ⅱ) Metal-Organic Framework Based on N,N'-Bis-(3-Pyridyl) Terephthalamide and 1,3,5-Benzenetricarboxylic Acid

doi:10.11944/j.issn.1000-0518.2019.12.190125

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (12): 1397-1405.DOI: 10.11944/j.issn.1000-0518.2019.12.190125

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Syntheses, Crystal Structures and Magnetic Properties of a 2D Cobalt(Ⅱ) Metal-Organic Framework Based on N,N'-Bis-(3-Pyridyl) Terephthalamide and 1,3,5-Benzenetricarboxylic Acid

WANG Qi^a,TONG Yuzhang^b,JIA Xiaopu^a,YANG Chun^a^*,WANG Qinglun^b^*,LIAO Daizheng^b

^aSchool of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China
^bDepartment of Chemistry,Nankai University,Tianjin 300071,China

Received:2019-04-28 Accepted:2019-07-09 Published:2019-12-01 Online:2019-12-10
Contact: YANG Chun,WANG Qinglun
Supported by:
Supported by the National Natural Science Foundation of China(No.21771111, No.21601092, No.21371104), the Natural Science Foundation of Hebei Province(No.B2016202280), and the Innovation and Entrepreneurship Training Program of Hebei Province for Undergraduate Students(No.201810080095)

Abstract

Abstract:

Based on N,N'-bis-(3-pyridyl)terephthalamide (3-bptpa) and 1,3,5-benzenetricarboxylic acid (1,3,5-H₃btc), a Co(Ⅱ) metal-organic framework [Co(3-bptpa)(1,3,5-Hbtc)]·2H₂O(1) with a 2D grid-like structure was hydrothermally synthesized. Complex 1 was characterized by X-ray crystallography, Fourier transform infrared (FT-IR) spectra, elemental analysis, thermal analysis and magnetic measurements. Each 1,3,5-Hbtc^2- provided one chelating and one bridging carboxylate groups to coordinate to Co(Ⅱ) cations. The centrosymmetric dimer [Co(3-bptpa)(1,3,5-Hbtc)]₂ was assembled into a 1D ladder-like chains by bridging carboxylate groups. The neighbouring chains were connected into 2D grid-like network by the coordination of 3-bptpa to Co(Ⅱ), resulting in the distorted CoN₂O₄ octahedral coordination sphere. The magnetic data of complex 1 in the temperature range 16~300 K were analyzed including the one-ion approximation for Co(Ⅱ) with spin-orbit coupling in O_h symmetry and intermolecular exchange interaction(zj') in the molecular field approximation leading to λ=-100.4 cm^-1 and zj'=-0.618 cm^-1. CCDC:1910964

Key words: dipyridine diamide ligand, hydrothermal synthesis, cobalt(Ⅱ);, metal-organic framework(MOF), magnetic properties

WANG Qi, TONG Yuzhang, JIA Xiaopu, YANG Chun, WANG Qinglun, LIAO Daizheng. Syntheses, Crystal Structures and Magnetic Properties of a 2D Cobalt(Ⅱ) Metal-Organic Framework Based on N,N'-Bis-(3-Pyridyl) Terephthalamide and 1,3,5-Benzenetricarboxylic Acid[J]. Chinese Journal of Applied Chemistry, 2019, 36(12): 1397-1405.

References

[1]	Li J R,Sculley J,Zhou H C.Metal Organic Frameworks for Separations[J]. Chem Rev,2012,112(2):869-932.
[2]	Duan J,Higuchi M,Krishna R,et al. High CO2/N2/O2/CO Separation in a Chemically Robust Porous Coordination Polymer with Low Binding Energy[J]. Chem Sci,2014,5:660-666.
[3]	Coronado E,Espallargas G M.Dynamic Magnetic MOFs[J]. Chem Soc Rev,2013,42:1525-1539.
[4]	Zou J Y,Shi W,Xu N,et al. A Homospin Cobalt(Ⅱ) Topological Ferrimagnet[J]. Chem Commun,2013,49:8226-8228.
[5]	Jia X X,Yao R X,Zhang F Q,et al. A Fluorescent Anionic MOF with Zn4(trz)2 Chain for Highly Selective Visual Sensing of Contaminants:Cr(Ⅲ) Ion and TNP[J]. Inorg Chem,2017,56(5):2690-2696.
[6]	Zou J Y,Shi W,Gao H L,et al. Spin Canting and Metamagnetism in 3D Pillared-Layer Homospin Cobalt(Ⅱ) Molecular Magnetic Materials Constructed via a Mixed Ligands Approach[J]. Inorg Chem Front,2014,1:242-248.
[7]	Yin Z,Zhou Y L,Zeng M H,et al. The Concept of Mixed Organic Ligands in Metal-Organic Frameworks:Design, Tuning and Functions[J]. Dalton Trans,2015,44:5258-5275.
[8]	Zhao X,Bu X H,Zhai Q G,et al. Pore Space Partition by Symmetry-Matching Regulated Ligand Insertion and Dramatic Tuning on Carbon Dioxide Uptake[J]. J Am Chem Soc,2015,137(4):1396-1399.
[9]	Feng Y Y,Liu X Y,Duan L Q,et al. In-Situ Synthesized 3D Heterometallic Metal-Organic Framework(MOF) as High-Energy-Density Materials Shows High Heat of Detonation, Good Thermostability and Insensitivity[J]. Dalton Trans,2015,44:2333-2339.
[10]	Liu G C,Yu H X,Lin H Y,et al. Spacers-Induced Structural Diversity of Cobalt Coordination Polymers Based on “V”-type Dipyridylamide and Dicarboxylic Ligands:Fluorescent, Magnetic and Photocatalytic Properties[J]. Polyhedron,2017,126:205-213.
[11]	Hsu Y F,Lin C H,Chen J D,et al. A Novel Interpenetrating Diamondoid Network from Self-assembly of N,N'-Di(4-pyridyl)adipoamide and Copper Sulfate:An Unusual 12-Fold, [6+6] Mode[J]. Cryst Growth Des,2008,8(4):1094-1096.
[12]	Cheng P C,Kuo P T,Liao Y H,et al. Ligand-Isomerism Controlled Structural Diversity of Zn(Ⅱ) and Cd(Ⅱ) Coordination Polymers from Mixed Dipyridyladipoamide and Benzenedicarboxylate Ligands[J]. Cryst Growth Des,2013,13(2):623-632.
[13]	Wang X L,Luan J,Sui F F,et al. Structural Diversities, Fluorescent and Photocatalytic Properties of a Series of CuⅡ Coordination Polymers Constructed from Flexible Bis-pyridyl-Bis-amide Ligands with Different Spacer Length and Different Aromatic Carboxylates[J]. Cryst Growth Des,2013,13(8):3561-3576.
[14]	Wang X L,Sui F F,Lin H Y,et al. Aromatic Polycarboxylate-Tuned Assembly of Three New 2D Copper(Ⅱ) Complexes Derived from a Flexible Bis(pyridylamide) Ligand[J]. Aust J Chem,2013,66(1):67-74.
[15]	Wang X L,Xiong Y,Sha X T,et al. Various Polycarboxylate-Directed Cd(Ⅱ) Coordination Polymers Based on a Semirigid Bis-pyridyl-Bis-amide Ligand: Construction and Fluorescent and Photocatalytic Properties[J]. Cryst Growth Des,2017,17(2):483-496.
[16]	Dybtsev D N,Chun H,Kim K.Rigid and Flexible:A Highly Porous Metal Organic Framework with Unusual Guest-Dependent Dynamic Behavior[J]. Angew Chem Int Ed,2004,43(38):5033-5036.
[17]	Liu W,Peng Y Y,Wu S G,et al. Guest-Switchable Multi-Step Spin Transitions in an Amine-Functionalized Metal-Organic Framework[J]. Angew Chem Int Ed,2017,129(47):15178-15182.
[18]	Shi L,Shao D,Wei H Y,et al. Two Interpenetrated Cobalt(Ⅱ) Metal-Organic Frameworks with Guest-Dependent Structures and Field-Induced Single-Ion Magnet Behaviors[J]. Cryst Growth Des,2018,18(9):5270-5278.
[19]	Wang Y L,Chen L,Liu C M,et al. Field-Induced Slow Magnetic Relaxation and Gas Adsorption Properties of a Bifunctional Cobalt(Ⅱ) Compound[J]. Inorg Chem,2015,54(23):11362-11368.
[20]	Vallejo J,Fortea-Pérez F R,Pardo E,et al. Guest-Dependent Single-Ion Magnet Behaviour in a Cobalt(Ⅱ) Metal Organic Framework[J]. Chem Sci,2016,7:2286-2293.
[21]	Gupta K,Dadwal A,Rana S,et al. Metamagnetism in Nanosheets of CoⅡ-MOF with TN at 26 K and a Giant Hysteretic Effect at 5 K[J]. Inorg Chem,2018,57(24):15044-15047.
[22]	Lim K S,Lee W R,Lee H G,et al. Control of Interchain Antiferromagnetic Coupling in Porous Co(Ⅱ)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length:How Far Does Magnetic Interaction Propagate?[J]. Inorg Chem,2017,56(13):7443-7448.
[23]	Tian C B,Han Y H,He Z Z,et al. Magnetic Tuning of an Anionic CoⅡ-MOF through Deionization of the Framework:Spin-Canting, Spin-Flop, and Easy-Plane Magnetic Anisotropy[J]. Chem Eur J,2017,23(4):767-772.
[24]	Qin Z,Jennings M C,Puddephatt R J.Self-assembly in Palladium(Ⅱ) and Platinum(Ⅱ) Chemistry:The Biomimetic Approach[J]. Inorg Chem,2003,42(6):1956-1965.
[25]	Wang X L,Luan J,Lin H Y,et al. The Various Architectures and Properties of a Series of Coordination Polymers Tuned by the Central Metals[J]. Dalton Trans,2014,43:8072-8082.
[26]	Sheldrick G M.SHELXS-97,Program for Crystal Structure Solution[CP]. University of Gö ttingen. Germany,1997.
[27]	Sheldrick G M.SHELXL-97,Program for the Refinement of Crystal Structures[CP]. University of Göttingen. Germany,1997.
[28]	Li M X,Zhang Y F,He X,et al. Diverse Structures and Ferro-/Ferri-/Antiferromagnetic Interactions of Pyridyltetrazole Coordination Polymers with Polycarboxylate Auxiliary Ligands[J]. Cryst Growth Des,2016,16(5):2912-2922.
[29]	Wang X L,Mu B,Lin H Y,et al. Substituent Groups from Aromatic Dicarboxylates Modulated Structural Diversification in the Assembly of Co(Ⅱ) Complexes Based on the Bis-pyridyl-Bis-amide Ligands[J]. Sci China Chem,2013,56(5):557-566.
[30]	Gangu K K,Maddila S,Mukkamala S B,et al. A 3D Supramolecular Assembly of Co(Ⅱ) MOF Constructed with 2,5-Pyridinedicarboxylate Strut and Its Catalytic Activity towards Synthesis of Tetrahydrobiphenylene-1,3-Dicarbonitriles[J]. Inorg Chim Acta,2018,482:830-837.
[31]	YUN Jixing,HU Zhili,LI Yumeng,et al. Synthesis. Synthesis, Structure and Photoelectric Property of a Series of Ni(Ⅱ) Complexes Constructed Through Aromatic Carboxylic Ligands[J]. Chem J Chinese Univ,2018,39(10):2161-2169(in Chinese). 贠吉星,胡志莉,李禹蒙,等. 由芳香羧酸构筑的系列配合物的合成、结构及光电性能[J]. 高等学校化学学报,2018,39(10):2161-2169.
[32]	Deacon G B,Phillips R J.Relationships Between the Carbon-Oxygen Stretching Frequencies of Carboxylato Complexes and the Type of Carboxylate Coordination[J]. Coord Chem Rev,1980,33(3):227-250.
[33]	Yang G P,Wang Y Y,Ma L F,et al. Hydrothermal Syntheses and Characterizations of Three Coordination Polymers Based on Mixed Organic Ligands[J]. Eur J Inorg Chem,2007,24:3892-3898.
[34]	Wang R,Zhang J,Li L.Conformation Preference of a Flexible Cyclohexanetetracarboxylate Ligand in Three New Metal-Organic Frameworks:Structures, Magnetic and Luminescent Properties[J]. Inorg Chem,2009,48(15):7194-7200.
[35]	Zeng M H,Tan Y X,He Y P,et al. A Porous 4Fold-Interpenetrated Chiral Framework Exhibiting Vapochromism, Single-Crystal-to-Single-Crystal Solvent Exchange, Gas Sorption, and a Poisoning Effect[J]. Inorg Chem,2013,52(5):2353-2360.
[36]	Wang X L,Wu X M,Liu G C,et al. Four Thiophene-Pyridyl-Amide-Based ZnⅡ/CdⅡ Coordination Polymers:Assembly, Structures, Photocatalytic Properties and Fluorescent Recognition for Fe3+[J]. J Solid State Chem,2017,249:51-57.
[37]	Batool S S,Gilani S R,Tahir M N,et al. Synthesis, and Structural Characterization of Mixed Ligand Copper(Ⅱ) Complexes of N,N,N',N'-Tetramethylethylenediamine Incorporating Carboxylates[J]. J Mol Struct,2017,1148:7-14.
[38]	Yang C,Wang Q L,Tang G T,et al. Synthesis, Crystal Structure, Spectroscopy and Magnetism of a Mixed Valence Co(Ⅲ)-Co(Ⅱ)-Co(Ⅲ) Complex Stabilized by N-(2-Hydroxybenzyl)salicylaldimine[J]. J Coord Chem,2010,63(3):505-514.
[39]	Fabelo O,Pasán J,Canadillas-Delgado L,et al. Cobalt(Ⅱ) Sheet-Like Systems Based on Diacetic Ligands:From Subtle Structural Variances to Different Magnetic Behaviors[J]. Inorg Chem,2009,48(13):6086-6095.
[40]	Jia H P,Li W,Ju Z F,et al. Synthesis, Structure and Magnetism of Metal-Organic Framework Materials with Doubly Pillared Layers[J]. Eur J Inorg Chem,2006,21:4264-4270.
[41]	Rueff J M,Masciocchi N,Rabu P,et al. Synthesis, Structure and Magnetism of Homologous Series of Polycrystalline Cobalt Alkane Mono- and Dicarboxylate Soaps[J]. Chem Eur J,2002,8(8):1813-1820.
[42]	Li L,Zou J Y,You S Y,et al. Assembly of a New (3,6)-Connected Cobalt(Ⅱ) Metal-Organic Framework via a Mixed Ligands Approach[J]. Polyhedron,2018,141:262-266.
[43]	Fabelo O,Canñadillas-Delgado L,Pasán J,et al. Study of the Influence of the Bridge on the Magnetic Coupling in Cobalt(Ⅱ) Complexes[J]. Inorg Chem,2009,48(23):11342-11351.
[44]	Masuhara N,Hayami S,Motokawa N,et al. Crystal Structure and Magnetic Property of Two Novel 1-D Cobalt(Ⅱ) Assemblies[J]. Chem Lett,2007,36(1):90-91.

Syntheses, Crystal Structures and Magnetic Properties of a 2D Cobalt(Ⅱ) Metal-Organic Framework Based on N,N'-Bis-(3-Pyridyl) Terephthalamide and 1,3,5-Benzenetricarboxylic Acid

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