Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites

doi:10.19894/j.issn.1000-0518.210120

Chinese Journal of Applied Chemistry ›› 2021, Vol. 38 ›› Issue (12): 1588-1598.DOI: 10.19894/j.issn.1000-0518.210120

• Full Papers • Previous Articles Next Articles

Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites

WU Qiu-Ping^1,2, CAI Kun-Ting³, WANG Yuan-Kang⁴, SUN Kai^1,2, YANG Jin-Bo⁴, HAN Song-Bai^5*, LIU Yun-Tao ^1,2*

¹(Department of Nuclear Physics, China Institute of Atomic Energy, Beijing 102413, China)
²(National Key Laboratory for Metrology and Calibration Techniques, China Institute of Atomic Energy, Beijing 102413, China )
³(Department of Material Science and Engineering, Peking University, Beijing 100871, China)
⁴(College of Physics, Peking University, Beijing 100871, China)
⁵(Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen 518055, China)

Received:2021-03-17 Revised:2021-06-26 Published:2021-12-01 Online:2022-02-01
Supported by:
National Key R&D Program of China (No.2017YFA0403701)

Abstract

Abstract: In this paper, a Co/C carbon-based composite material with excellent microwave absorption properties was successfully prepared by pyrolyzing metal-organic framework ZIF-67. The sample with a mass fraction of 35% of absorbent obtained at a pyrolysis temperature of 600 ℃ has a minimum reflection loss of -54.30 dB and its thickness is only 1.75 mm. By analyzing the microwave absorption characteristics of the sample′s loss capability and impedance matching, it is found that the skeleton structure in the composite material has a great influence on its impedance matching performance. And the uniformly dispersed Co/C-polyurethane (PU) phase change composite material was prepared by in-situ composite method, and its microwave-thermal conversion performance was preliminarily studied. The amount of added microwave absorbent has a significant effect on its microwave-heat conversion performance, and the heating efficiency increases exponentially with the added amount. The Co/C-PU phase change composite material studied in this paper has great application potential in electromagnetic shielding, radar and infrared compatible stealth. In addition, solid-solid phase change materials combined with the rapid and high-efficiency characteristics of microwave heating effects have unique advantages when used for energy storage or other thermal applications.

Key words: Microwave absorption materials, Phase change materials, Metal-organic frameworks, Polyurethane, Microwave-heat transportation

CLC Number:

O642

WU Qiu-Ping, CAI Kun-Ting, WANG Yuan-Kang, SUN Kai, YANG Jin-Bo, HAN Song-Bai, LIU Yun-Tao. Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites[J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1588-1598.

References

[1] LIU W, SHAO Q, JI G, et al. Metal organic-frameworks derived porous carbon-wrapped Ni composites with optimized impedance matching as excellent lightweight electromagnetic wave absorber[J]. Chem Eng J, 2017, 313: 734-744.
[2] LIU T, PANG Y, XIE X B, et al. Co/C nanoparticles with low graphitization degree: a high performance microwave-absorbing material[J]. J Mater Chem C , 2016, 4(8): 1727-1735.
[3] CHEN D, WANG G S, HE S, et al. Controllable fabrication of mono-dispersed RGO-hematite nanocomposites and their enhanced wave absorption properties[J]. J Mater Chem A, 2013, 1(19): 5996-6003.
[4] ZHAO H B, CHENG J B, ZHU J Y, et al. Ultralight CoNi/rGO aerogels toward excellent microwave absorption at ultrathin thickness[J]. J Mater Chem C, 2019, 7(2): 441-448.
[5] KIM T, LEE J, LEE K, et al. Magnetic and dispersible FeCoNi-graphene film produced without heat treatment for electromagnetic wave absorption[J]. Chem Eng J, 2019, 361: 1182-1189.
[6] WEN B, CAO M S, HOU Z L, et al. Temperature dependent microwave attenuation behavior for carbon-nanotube/silica composites[J]. Carbon, 2013, 65: 124-139.
[7] WANGL, BAI X Y, WEN B, et al. Honeycomb-like Co/C composites derived from hierarchically nanoporous ZIF-67 as a lightweight and highly efficient microwave absorber[J]. Compos B Eng, 2019, 166: 464-471.
[8] LI H, LIANG X, CHENG Y, et al. Coin-like α-Fe₂O₃@CoFe₂O₄ core-shell composites with excellent electromagnetic absorption performance[J]. ACS Appl Mater Interfaces, 2015, 7(8): 4744-4750.
[9] LI Z, HAN X, MA Y, et al. MOFs-derived hollow Co/C microspheres with enhanced microwave absorption performance[J]. ACS Sustainable Chem Eng, 2018, 6(7): 8904-8913.
[10] LIANG X H, QUAN B, CHEN J, et al. Nano bimetallic@carbon layer on porous carbon nanofibers with multiple interfaces for microwave absorption applications[J]. ACS Appl Nano Mater, 2018, 1(10): 5712-5721.
[11] LIU Q, ZHANG D, FAN T. Electromagnetic wave absorption properties of porous carbon/Co nanocomposites[J]. Appl Phys Lett, 2008, 93(1): 401.
[12] MA J N, ZHANG X M, LIU W, et al. Direct synthesis of MOF-derived nanoporous CuO/carbon composites for high impedance matching and advanced microwave absorption[J]. J Mater Chem C, 2016, 4(48): 11419-11426.
[13] SHARMA A, TYAGI V V, CHEN C R, et al. Review on thermal energy storage with phase change materials and applications[J]. Renew Sustainable Energy Rev, 2009, 13(2): 318-345.
[14] LIU C, LI F, MA L P, et al. Advanced materials for energy storage[J]. Adv Mater, 2010, 22(8): E28-E62.
[15] SAN, AHME T. Thermal energy storage characteristics of bentonite-based composite PCMs with enhanced thermal conductivity as novel thermal storage building materials[J]. Energy Convers Manage, 2016, 117: 132-141.
[16] CHEN R, YAO R, XIA W, et al. Electro/photo to heat conversion system based on polyurethane embedded graphite foam[J]. Appl Energy, 2015, 152: 183-188.
[17] BHATTACHARYA P, DHIBAR S, HATUI G, et al. Graphene decorated with hexagonal shaped M-type ferrite and polyaniline wrapper: a potential candidate for electromagnetic wave absorbing and energy storage device applications[J]. RSC Adv, 2014, 4(33): 17039-17053.
[18] WANG Y, DU Y C, GUO D, et al. Precursor-directed synthesis of porous cobalt assemblies with tunable close-packed hexagonal and face-centered cubic phases for the effective enhancement in microwave absorption[J]. J Mater Sci, 2017, 52(8): 4399-4411.
[19] DINEGA D P, BAWENDI M G. A solution-phase chemical approach to a new crystal structure of cobalt[J]. Angew Chem Int Ed, 1999, 38(12): 1788-1791.
[20] KIM S S, JO S B, GUEON K I, et al. Complex permeability and permittivity and microwave absorption of ferrite-rubber composite at X-band frequencies[J]. IEEE Trans Magn, 1991, 27(6): 5462-5464.
[21] ZHANG X M, GUANG B J, LIU W, et al. Thermal conversion of an Fe₃O₄@metal-organic framework: a new method for an efficient Fe-Co/nanoporous carbon microwave absorbing material[J]. Nanoscale, 2015, 7(30): 12932-12942.
[22] ZHOU X, WANG B, JIA Z, et al. Dielectric behavior of Fe₃N@C composites with green synthesis and their remarkable electromagnetic wave absorption performance[J]. J Colloid Interface Sci, 2020, 582: 515-525.
[23] XIONG Y, XU L, YANG C, et al. Implanting FeCo/C nanocages with tunable electromagnetic parameters in anisotropic wood carbon aerogels for efficient microwave absorption[J]. J Mater Chem A. 2020, 8(36): 18863-18871.
[24] ZHANG Y, YAO M, LIU C, et al. Reduced graphene oxide-CoFe₂O₄/FeCo nanoparticle composites for electromagnetic wave absorption[J]. ACS Appl Nano Mater, 2020, 3(9): 8939-8948.
[25] WANG X Y, LU Y K, ZHU T, et al. CoFe₂O₄/N-doped reduced graphene oxide aerogels for high-performance microwave absorption[J]. Chem Eng J, 2020, 388: 124317.
[26] ZHANG Y C, GAO S, XING H L, et al. In situ carbon nanotubes encapsulated metal nickle as high-performance microwave absorber from Ni-Zn metal-organic framework derivative[J]. J Alloys Compd, 2019, 801: 609-618.
[27] ZHANG Z L, LV Y Y, CHEN X Q, et al. Porous flower-like Ni/C composites derived from MOFs toward high-performance electromagnetic wave absorption[J]. J Magn Magn Mater, 2019, 487: 165334-165334.
[28] CAO M S, SONG W L, HOU Z L, et al. The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites[J]. Carbon, 2009, 48(3): 788.
[29] LI J, LU S Q, HUANG H L, et al. ZIF-67 as continuous self-sacrifice template derived NiCo₂O₄/CoN-CNTs nanocages as efficient bifunctional electrocatalysts for rechargeable Zn-Air batteries[J]. ACS Sustainable Chem Eng, 2018, 6: 10021-10029.
[30] HONG W, KITTA M, XU Q. Bimetallic MOF-derived FeCo-P/C nanocomposites as efficient catalysts for oxygen evolution reaction[J]. Small Methods, 2018, 2(12): 1800214.
[31] WANG L, GUAN Y, QIU X, et al. Efficient ferrite/Co/porous carbon microwave absorbing material based on ferrite@metal-organic framework[J]. Chem Eng J, 2017, 326: 945-955.
[32] YAN J, HUANG Y, YAN Y, et al. The high-performance electromagnetic wave absorbers based on two kinds of nickel-based MOFs-derived Ni@C microspheres[J]. ACS Appl Mater Interfaces, 2019, 11(43): 40781-40792.
[33] GREEN M, LIU Z, XIANG P, et al. Ferric metal-organic framework for microwave absorption[J]. Mater Today Chem, 2018, 9: 140-148.
[34] WU C, CHEN Z, WANG M, et al. Microwaveabsorption: confining tiny MoO₂ clusters into reduced graphene oxide for highly efficient low frequency microwave absorption[J]. Small, 2020, 16(30): 2001686.
[35] CHE R C, PENG L M, DUAN X F, et al. Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes[J]. Adv Mater, 2004, 16(5): 401-405.
[36] XIANG J, LI J L, ZHANG X H, et al. Magnetic carbon nanofibers containing uniformly dispersed Fe/Co/Ni nanoparticles as stable and high-performance electromagnetic wave absorbers[J]. J Mater Chem A, 2014: 16905-16914.
[37] FU M, JIAO Q, ZHAO Y, et al. Vapor diffusion synthesis of CoFe₂O₄ hollow sphere/graphene composites as absorbing materials[J]. J Mater Chem A, 2013, 2(3): 735-744.
[38] GANDHI N, SINGH K, OHLAN A, et al. Thermal, dielectric and microwave absorption properties of polyaniline-CoFe₂O₄ nanocomposites[J]. Compos Sci Technol, 2011, 71(15): 1754-1760.
[39] WANG W, TANG B, JU B, et al. Fe₃O₄-functionalized graphene nanosheet embedded phase change material composites: efficient magnetic- and sunlight-driven energy conversion and storage[J]. J Mater Chem A, 2017, 5: 958-968.
[40] GUYOMAR D, MATEI D F, GUIFFARD B, et al. Magnetoelectricity in polyurethane films loaded with different magnetic particles[J]. Mater Lett, 2009, 63(6/7): 611-613.
[41] WU W H, HUANG X Y, YAO R M, et al. Synthesis and properties of polyurethane/coal-derived carbon foam phase change composites for thermal energy storage[J]. Acta Phys-Chim Sin, 2017, 33(1): 255-261.
[42] YIN Y, LIU X, WEI X, et al. Magneticallyaligned Co-C/MWCNTs composite derived from MWCNTs interconnected zeolitic imidazolate frameworks for lightweight and highly efficient electromagnetic wave absorber[J]. ACS Appl Mater Interfaces, 2017: 30850.
[43] LIN H, ZHU H, GUO H, et al. Microwave-absorbing properties of Co-filled carbon nanotubes[J]. Mater Res Bull, 2008, 43(10): 2697-2702.
[44] QIANG R, DU Y C, CHEN D T, et al. Electromagnetic functionalized Co/C composites by in situ pyrolysis of metal-organic frameworks (ZIF-67)[J]. J Alloys Compd, 2016, 681: 384-393.

Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Xue-Bo LEI, Hui-Jing LIU, He-Yu DING, Guo-Dong SHEN, Run-Jun SUN. Research Progress on Photocatalysts for Degradation of Organic Pollutants in Printing and Dyeing Wastewater [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 681-696.
[2]	Yu-Zhu CHEN, Si-Si LIU, Meng-Meng ZHANG, Xiang-De LIN, Dong-Dong ZENG. Polyurethane Dressing Based on Antibacterial Chitosan/Carboxymethyl Cellulose Composite Drug Coating [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 252-260.
[3]	Bi-Ru SHI, Hao-Hao WU, Hao-Pu XIE, Xin-Xin TIAN, Ying-Lu SUN, Xiang-Dong LIU, Yu-Ming YANG. Preparation and Properties of Self-healing Polyurethane Adhesives with Diels-Alder Bonds [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 277-287.
[4]	Dan ZHANG, Fang LIU, Xue YANG, Dong-Hua XU, Tong-Fei SHI. Relationship Between Hardness and Impact Properties of Thermoplastic Polyurethane Blends [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1216-1223.
[5]	Zhong XU, Jun LI, En-Hui WU, Yan JIANG. Influence of Vanadium Tailings on the Thermal Stability and Electrical Conductivity of Expanded Graphite/ Paraffin Composite Phase Change Materials [J]. Chinese Journal of Applied Chemistry, 2022, 39(3): 461-469.
[6]	ZHANG Ming-Shan, LI Teng-Ya, LEI Yu, WU Yan, HE Shu-Hai. Determination of Two Sulfonamides in Environmental Water Based on Dispersivesolid-Phase Extraction with MIL-101(Cr) Metal-Organic Framework [J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 236-244.
[7]	WU Qiu-Ping, CAI Kun-Ting, WANG Yuan-Kang, SUN Kai, YANG Jin-Bo, HAN Song-Bai, LIU Yun-Tao. Microwave Absorption Properties of Co/C and Microwave-Heat Conversion Properties of Co/C-Polyurethane Phase Change Composites [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 0-0.
[8]	PAN Ge, LIU Fang, FU Zhilei, LI Shuangshuang, XU Donghua, XU Zhaohua, SHI Tongfei, WANG Xiaowei, MA Rui. Effect of Mass Fraction of Color Paste in Waterborne Polyurethane Coatings on Low Temperature Blasting Properties of Polyvinyl Chloride Skin [J]. Chinese Journal of Applied Chemistry, 2020, 37(2): 182-189.
[9]	AN Pinping, LUO Fubin, HUANG Baoquan, XIAO Liren, QIAN Qingrong, LI Hongzhou, CHEN Qinghua. Properties of Thermal Conductivity Enhanced Polyethylene Glycol-Based Phase Change Composites [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 46-53.
[10]	GUO Xiaoyan, CHENG Xiaoqi, ZHANG Liangliang, HUANG Yiping, XU Gewen, BAO Junjie. Preparation and Properties of Sulfonic Waterborne Polyurethane Hydrogels with Sodium N,N-Bis (2-hydroxyethyl)-2-aminoethane Sulfonate as Chain Extender [J]. Chinese Journal of Applied Chemistry, 2019, 36(6): 631-640.
[11]	CHEN Guangmei,WANG Zhikun,WU Lixia,HUANG Yiping. Preparation and Properties of Polyurethane Modified by Acrylate/Nano-SiO₂ Composites [J]. Chinese Journal of Applied Chemistry, 2019, 36(5): 532-538.
[12]	XIAO Fan,CUI Yuanjing,QIAN Guodong. Metal-Organic Frameworks for Fluorescence Detection Applications [J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1113-1125.
[13]	TIAN Yumeng, LI Xuemin, LI Xiaoxiao, HUAN Yan, YE Feng, YANG Xiaoniu. Effect of Molecular Cross-linking Degrees on the Morphology and Tribological Properties of 1,4-Phenylene Diisocyanate-Based Polyurethane Elastomers [J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1148-1154.
[14]	YUAN Ting,MENG Ting,LI Shuhua,FAN Louzhen. Recent Development of Electroluminescent Diodes Based on Phosphorescent Materials [J]. Chinese Journal of Applied Chemistry, 2018, 35(8): 871-880.
[15]	YUAN Ning,DU Bingjie,JIA Xiaoxia,YANG Jiangfeng,LI Jinping. Research Progress in Preparation Technology and Application of Bimetal Metal-Organic Frameworks Materials [J]. Chinese Journal of Applied Chemistry, 2018, 35(5): 500-510.