
Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (2): 245-251.DOI: 10.19894/j.issn.1000-0518.220185
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Jin-Jian LIU1,2(), Na LIU1, Feng-Yi YANG1
Received:
2022-05-19
Accepted:
2022-11-15
Published:
2023-02-01
Online:
2023-02-27
Contact:
Jin-Jian LIU
About author:
liujj@sxnu.edu.cnSupported by:
CLC Number:
Jin-Jian LIU, Na LIU, Feng-Yi YANG. Synthesis and Photochromic Properties of Two Isostructural Viologen Coordination Polymers[J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 245-251.
Compound | 1 | 2 |
---|---|---|
CCDC code | 1997701 | 1974986 |
Empirical formula | C26H22Cl2MnN2O5 | C26H28 Cl2CdN2O8 |
Formula mass | 568.29 | 679.82 |
Crystal size/mm | 0.3×0.3×0.2 | 0.2×0.2×0.2 |
Crystal system | Monoclinic | Monoclinic |
Space group | P21/n | P21/n |
a/nm | 1.629 25(18) | 1.612 49(14) |
b/nm | 0.952 47(10) | 0.986 10(9) |
c/nm | 1.901 5(2) | 1.878 61(16) |
α/(°) | 90 | 90 |
β/(°) | 113.454(2) | 114.672(2) |
γ/(°) | 90 | 90 |
Volume/nm3 | 2.707 0(5) | 2.714 4(4) |
Z | 4 | 4 |
Dc/(g·cm-3) | 1.394 | 1.644 |
F(000) | 0.723 | 1.053 |
μ/mm-1 | 1 164 | 1 344 |
R1/wR2, [I≥2σ(I)] a,b | 0.125 0, 0.403 0 | 0.057 3, 0.182 7 |
R1/wR2, (all data) | 0.134 7, 0.418 1 | 0.073 2, 0.199 6 |
Table 1 Crystal data and structure refinement for compounds 1 and 2
Compound | 1 | 2 |
---|---|---|
CCDC code | 1997701 | 1974986 |
Empirical formula | C26H22Cl2MnN2O5 | C26H28 Cl2CdN2O8 |
Formula mass | 568.29 | 679.82 |
Crystal size/mm | 0.3×0.3×0.2 | 0.2×0.2×0.2 |
Crystal system | Monoclinic | Monoclinic |
Space group | P21/n | P21/n |
a/nm | 1.629 25(18) | 1.612 49(14) |
b/nm | 0.952 47(10) | 0.986 10(9) |
c/nm | 1.901 5(2) | 1.878 61(16) |
α/(°) | 90 | 90 |
β/(°) | 113.454(2) | 114.672(2) |
γ/(°) | 90 | 90 |
Volume/nm3 | 2.707 0(5) | 2.714 4(4) |
Z | 4 | 4 |
Dc/(g·cm-3) | 1.394 | 1.644 |
F(000) | 0.723 | 1.053 |
μ/mm-1 | 1 164 | 1 344 |
R1/wR2, [I≥2σ(I)] a,b | 0.125 0, 0.403 0 | 0.057 3, 0.182 7 |
R1/wR2, (all data) | 0.134 7, 0.418 1 | 0.073 2, 0.199 6 |
Fig.4 UV-Vis spectra before and after irradiation for compounds 1 (A) and 2 (C) ; EPR spectra before and after irradiation for compounds 1 (B) and 2 (D)
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