Synthesis and Photochromic Properties of Two Isostructural Viologen Coordination Polymers

doi:10.19894/j.issn.1000-0518.220185

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (2): 245-251.DOI: 10.19894/j.issn.1000-0518.220185

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Synthesis and Photochromic Properties of Two Isostructural Viologen Coordination Polymers

Jin-Jian LIU¹^,²(), Na LIU¹, Feng-Yi YANG¹

^1.School of Chemistry and Material Science，Shanxi Normal University，Taiyuan 030031，China
^2.Modern College of Humanities and Science，Shanxi Normal University，Linfen 041000，China

Received:2022-05-19 Accepted:2022-11-15 Published:2023-02-01 Online:2023-02-27
Contact: Jin-Jian LIU
About author:liujj@sxnu.edu.cn
Supported by:
the Natural Science Foundation of Shanxi Province(20210302124260);the Graduate Education Innovation Project of Shanxi Normal University(2021XSY039)

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Abstract

Abstract:

As a new type of smart material， chromic materials have great applications in the fields of optical storage information and optical devices. Self-assembly of transition metal ions Mn²⁺ and Cd²⁺with a viologen ligand， 1，1′-bis（4-carboxybenzyl）-4，4′-bipyridinium dichloride （H₂BpybcCl₂） with flexible backbone， forms two novel isostructural coordination polymers，［Mn（Bpybc）Cl₂·H₂O］ _n （1） and ［Cd（Bpybc）Cl₂·4H₂O］ _n （2）. X-ray single-crystal diffraction shows that two compounds are one-dimensional chain structures. Both compounds exhibit obvious photochromic behaviors under UV irradiation， which is caused by photo-induced electron transfer to generate viologen free radicals.

Key words: Viologens, Coordination polymers, Crystal structure, Photochromism, Electron transfer

CLC Number:

O614

Jin-Jian LIU, Na LIU, Feng-Yi YANG. Synthesis and Photochromic Properties of Two Isostructural Viologen Coordination Polymers[J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 245-251.

Figures/Tables 5

References 28

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Compound	1	2
CCDC code	1997701	1974986
Empirical formula	C₂₆H₂₂Cl₂MnN₂O₅	C₂₆H₂₈ Cl₂CdN₂O₈
Formula mass	568.29	679.82
Crystal size/mm	0.3×0.3×0.2	0.2×0.2×0.2
Crystal system	Monoclinic	Monoclinic
Space group	P2₁/n	P2₁/n
a/nm	1.629 25（18）	1.612 49（14）
b/nm	0.952 47（10）	0.986 10（9）
c/nm	1.901 5（2）	1.878 61（16）
α/（°）	90	90
β/（°）	113.454（2）	114.672（2）
γ/（°）	90	90
Volume/nm³	2.707 0（5）	2.714 4（4）
Z	4	4
D_c/（g·cm^-3）	1.394	1.644
F（000）	0.723	1.053
μ/mm^-1	1 164	1 344
R₁/wR₂，［I≥2σ（I）］ ^a^，^b	0.125 0， 0.403 0	0.057 3， 0.182 7
R₁/wR₂，（all data）	0.134 7， 0.418 1	0.073 2， 0.199 6

Compound	1	2
CCDC code	1997701	1974986
Empirical formula	C₂₆H₂₂Cl₂MnN₂O₅	C₂₆H₂₈ Cl₂CdN₂O₈
Formula mass	568.29	679.82
Crystal size/mm	0.3×0.3×0.2	0.2×0.2×0.2
Crystal system	Monoclinic	Monoclinic
Space group	P2₁/n	P2₁/n
a/nm	1.629 25（18）	1.612 49（14）
b/nm	0.952 47（10）	0.986 10（9）
c/nm	1.901 5（2）	1.878 61（16）
α/（°）	90	90
β/（°）	113.454（2）	114.672（2）
γ/（°）	90	90
Volume/nm³	2.707 0（5）	2.714 4（4）
Z	4	4
D_c/（g·cm^-3）	1.394	1.644
F（000）	0.723	1.053
μ/mm^-1	1 164	1 344
R₁/wR₂，［I≥2σ（I）］ ^a^，^b	0.125 0， 0.403 0	0.057 3， 0.182 7
R₁/wR₂，（all data）	0.134 7， 0.418 1	0.073 2， 0.199 6

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Synthesis and Photochromic Properties of Two Isostructural Viologen Coordination Polymers

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