Synthesis, Structure and Photocatalytic Activity of Triazine-Pyrazole Ruthenium Complexes

doi:10.11944/j.issn.1000-0518.2018.02.170084

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (2): 206-215.DOI: 10.11944/j.issn.1000-0518.2018.02.170084

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Synthesis, Structure and Photocatalytic Activity of Triazine-Pyrazole Ruthenium Complexes

GU Zhimeng,WANG Ying,ZHAO Min,HAO Qiuhua,SHANG Di,BAI Fengying(),XING Yongheng

College of Chemical Engineering,Liaoning Normal University,Dalian,Liaoning 116029,China

Received:2017-03-27 Accepted:2017-06-22 Published:2018-02-01 Online:2018-01-29
Contact: BAI Fengying
Supported by:
Supported by the National Natural Science Foundation of China(No.21571091), the Liaoning Province Students Innovation and Entrepreneurship Projects(No.201610165047)

Abstract

Abstract:

As the photocatalytic reaction has the advantages of non-pollution, safe and efficient, so it has become a research hotspot of environmental protecting field. Therefore, this work choose 2,4-two (3,5-two methyl pyrazole)-6-two ethyl amine-1,3,5-three triazine(L₁) and 2,6-di[3-(5-methylpyrazolyl)] pyridine(L₂) as the ligands, RuCl₃ as the metal source to synthesize three kinds of complexes, [Ru(L₁)Cl₃](1), [Ru(L₂)₂]·Cl₃(2), and [Ru(L₂)₂]·(H₂BTC)·(HBTC)·H₂O(3). At the same time, the complexes were characterized by infrared(IR) spectrometry, ultraviolet-visible(UV-Vis), themogravimetry(TG) and X-ray diffraction, and the photocatalytic degradation of RhB was explored. The results show that the complexes 13 have a certain degree of photodegradation effect, the degradation efficiency is 46.8%, 44.7% and 40.4%, respectively. Under the same conditions, the degradation effects of the complexes are better than those corresponding only with metal salts, ligands and H₂O₂, respectively.

Key words: triazine-pyrazole derivatives, ruthenium complexes, crystal structure, photocatalytic performance

GU Zhimeng,WANG Ying,ZHAO Min,HAO Qiuhua,SHANG Di,BAI Fengying,XING Yongheng. Synthesis, Structure and Photocatalytic Activity of Triazine-Pyrazole Ruthenium Complexes[J]. Chinese Journal of Applied Chemistry, 2018, 35(2): 206-215.

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Synthesis, Structure and Photocatalytic Activity of Triazine-Pyrazole Ruthenium Complexes

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