Synthesis, Crystal Structure and Luminescent Properties of a Europium Complex from Imidazole Dicarboxylate

doi:10.11944/j.issn.1000-0518.2018.01.170336

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (1): 82-88.DOI: 10.11944/j.issn.1000-0518.2018.01.170336

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Synthesis, Crystal Structure and Luminescent Properties of a Europium Complex from Imidazole Dicarboxylate

LIN Xiaoyi^a,ZHU Yongchao^b,MENG Xiangru^b^*()

^aNo.1 Middle School of Nanyang,Nanyang,He'nan 473009,China
^bCollege of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450001,China

Received:2017-09-14 Accepted:2017-12-12 Published:2018-01-03 Online:2018-01-03
Contact: MENG Xiangru
Supported by:
Supported by the National Natural Science Foundation of China(No.J1210060), the He'nan Science and Technology Project(No.172102210128)

Abstract

Abstract:

By solvothermal reaction of Eu(NO₃)₃ 6H₂O with 2-(2-bromophenyl)-1H-imidazole-4,5-dicarboxylic acid (o-BrPhH₃IDC) in the presence of terephthalic acid, a three-dimensional supramolecular complex (H₃O)[Eu(o-BrPhH₂IDC)₄](1) was prepared. The crystal structure of complex 1 was determined by single crystal X-ray diffraction. The results show that complex 1 crystallizes in the cubic system, I-43d space group, and the central europium ion is in a eight-coordinate system. The solid-state fluorescence of complex 1 reveals that complex 1 exhibits a characteristic europium emission spectra at the excitation wavelength of 395 nm which implies that the organic ligand has a good antenna effect and a good sensitization effect on europium ion.

Key words: Eu-complex, imidazole dicarboxylate, crystal structure, fluorescence properties

LIN Xiaoyi, ZHU Yongchao, MENG Xiangru. Synthesis, Crystal Structure and Luminescent Properties of a Europium Complex from Imidazole Dicarboxylate[J]. Chinese Journal of Applied Chemistry, 2018, 35(1): 82-88.

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Synthesis, Crystal Structure and Luminescent Properties of a Europium Complex from Imidazole Dicarboxylate

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