Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni2+ in Aqueous Solution

doi:10.11944/j.issn.1000-0518.2017.12.170294

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (12): 1468-1473.DOI: 10.11944/j.issn.1000-0518.2017.12.170294

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Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution

HUANG Qi^a^b^c,SONG Haohan^c,WANG Xiao^c,PANG Lanfang^c,ZHOU Yanmei^c^*()

^aState Key Laboratory of Marine Environmental Science of China, Xiamen University,Xiamen,Fujian 361102,China
^bCollege of the Environment and Ecology,Xiamen University,Xiamen,Fujian 361102,China
^cInstitute of Environmental and Analytical Sciences,College of Chemistry and Chemical Engineering,He'nan University,Kaifeng,He'nan 475004,China

Received:2017-08-21 Accepted:2017-10-17 Published:2017-12-04 Online:2017-12-04
Contact: ZHOU Yanmei
Supported by:
Supported by the National Natural Science Foundation of China(No.21576071, No.21776061), the Open Foundation of State Key Laboratory of Fine Chemicals(No.KF1514)

Abstract

Abstract:

Molecular spectroscopy has the advantages of high sensitivity and simple operation. Therefore, it is significant to develop a probe with high selectivity for nickel ions(Ni²⁺). In this paper, a novel molecular probe was designed and synthesized from rhodamine B, hydrazine hydrate and 2-acetylpyrazine for the detection of Ni²⁺ with excellent selectivity in aqueous media. Simultaneously, the probe rhodamine B amide derivative(RWZ) can achieve “naked eye” recognition of Ni²⁺ in aqueous solution. Furthermore, the probe shows high sensitivity to Ni²⁺ with low limit of detection(0.5 μmol/L), indicating that the probe can be used for detection of Ni²⁺ in aqueous solution.

Key words: molecular probe, rhodamine B, nickel ion, “naked-eye&rdquo, identification

HUANG Qi, SONG Haohan, WANG Xiao, PANG Lanfang, ZHOU Yanmei. Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution[J]. Chinese Journal of Applied Chemistry, 2017, 34(12): 1468-1473.

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Synthesis of a New Rhodamine-Based Probe for Selective Detection of Ni²⁺ in Aqueous Solution

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