Preparation and Electrochemical Characteristics of Manganese Dioxide/graphene Composite Paper Electrode

doi:10.11944/j.issn.1000-0518.2015.07.140404

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (7): 843-848.DOI: 10.11944/j.issn.1000-0518.2015.07.140404

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Preparation and Electrochemical Characteristics of Manganese Dioxide/graphene Composite Paper Electrode

LIU Yaliu, YUAN Zhongzhi^*, LIU Liling

School of Chemistry and Environment,South China Normal University,Guangzhou 51006,China

Received:2014-11-19 Accepted:2015-04-01 Published:2015-06-30 Online:2015-06-30
Contact: Zhongzhi YUAN
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Abstract

Abstract:

The flexible MnO₂/graphene composite paper electrode for lithium batteries was prepared by electro-deposition of MnO₂, via the oxidation of Mn²⁺ solution, on the graphene film. The paper electrode structure, appearance and electrochemical performances were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), cyclic voltammetry (CV) and galvanostatic discharging. The results show that spherical MnO₂ particles are homogeneously deposited on the graphene flakes to form a MnO₂/graphene composite paper electrode with the thickness of 45 μm. The crystal structure of MnO₂ in the composite changes from γ-MnO₂ to a mixed structure of γ/β-MnO₂ after calcination at 380 ℃. The discharge capacity of MnO₂ in the composite can reach 269 mA·h/g at 0.1C at room temperature. The structure of graphene is not damaged at the high calcination temperature. The good flexibility, low impendence and excellent electrochemical performance of the MnO₂/graphene paper electrode are profitable for flexible Li/MnO₂ batteries.

Key words: lithium battery, graphene, manganese dioxide, flexible electrode

CLC Number:

LIU Yaliu, YUAN Zhongzhi, LIU Liling. Preparation and Electrochemical Characteristics of Manganese Dioxide/graphene Composite Paper Electrode[J]. Chinese Journal of Applied Chemistry, 2015, 32(7): 843-848.

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Preparation and Electrochemical Characteristics of Manganese Dioxide/graphene Composite Paper Electrode

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