Preparation of Palladium/Polyelectrolyte Hollow Nanospheres and Their Catalytic Activity in 4-Nitrophenol Reduction

doi:10.11944/j.issn.1000-0518.2015.03.140204

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (3): 310-316.DOI: 10.11944/j.issn.1000-0518.2015.03.140204

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Preparation of Palladium/Polyelectrolyte Hollow Nanospheres and Their Catalytic Activity in 4-Nitrophenol Reduction

HE Xiaoyan^*, LIU Zhirong, FAN Fuhong, QIANG Shenglu, CHENG Li

Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu Province,College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070,China

Received:2014-06-11 Accepted:2014-10-30 Published:2015-03-02 Online:2015-03-02
Contact: Xiaoyan HE
Supported by:
Supported by the National Natural Science Foundation of China(No.21164010), the Natural Science Foundation of Gansu Province(No.1107RJZA149)

Abstract

Abstract:

Pd/polyelectrolyte hollow nanospheres were prepared by a facile method that combined the surface-initiated atom transfer radical polymerization(SI-ATRP) and in situ growth of metal nanoparticles. Transmission electron microscopy(TEM), Fourier transform infrared spectra(FTIR), energy-dispersive X-ray(EDX) and thermogravimetric analysis(TGA) were used to characterize the morphology and structure of air@PMETAI@Pd(PMETAI:poly{[2-(methacryloyloxy)ethyl] trimethylammonium iodide}) nanospheres. The result shows that Pd nanoparticles with diameter of (1.5±0.2) nm are homogeneously embedded inside the polyelectrolyte layer. Catalytic activity of the Pd/polyelectrolyte hollow nanospheres was investigated by the reduction of 4-nitrophenol with NaBH₄ as a model reaction. It is found that they displayed excellent catalytic properties and good reusability.

Key words: Pd nanoparticles, polyelectrolyte hollow nanospheres, catalyst, nitrophenol

CLC Number:

HE Xiaoyan, LIU Zhirong, FAN Fuhong, QIANG Shenglu, CHENG Li. Preparation of Palladium/Polyelectrolyte Hollow Nanospheres and Their Catalytic Activity in 4-Nitrophenol Reduction[J]. Chinese Journal of Applied Chemistry, 2015, 32(3): 310-316.

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Preparation of Palladium/Polyelectrolyte Hollow Nanospheres and Their Catalytic Activity in 4-Nitrophenol Reduction

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